Synthesis, structure and coordination properties of three cyclam-based ligands bearing one scorpionate arm

The synthesis and the properties of three new cyclam-based macrocycles bearing one N-tosylamide pendant arm have been described in this paper. These ligands show original acid–base behavior. Several complexes with transition metals have been synthesized and characterized by using various methods, in...

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Bibliographic Details
Published in:	Inorganica Chimica Acta Vol. 373; no. 1; pp. 150 - 158
Main Authors:	Kannappan, Ramu, Rousselin, Yoann, Jabri, Rim Zaari, Goze, Christine, Brandès, Stéphane, Guilard, Roger, Zrineh, Abdellah, Denat, Franck
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 15-07-2011
Subjects:	Cyclam EPR Metal complexes N-Sulfonylacetamide X-ray studies X-ray studies N-Sulfonylacetamide Metal complexes EPR Cyclam
Online Access:	Get full text
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Summary:	The synthesis and the properties of three new cyclam-based macrocycles bearing one N-tosylamide pendant arm have been described in this paper. These ligands show original acid–base behavior. Several complexes with transition metals have been synthesized and characterized by using various methods, including UV–Vis, EPR, infrared, as well as X-ray crystallography. [Display omitted] ► We report the synthesis and the properties of three new cyclam-based macrocycles bearing one N-tosylamide pendant arm. ► These ligands show original zwiterrionic behavior. ► Several complexes with transition metals have been synthesized and characterized by using various methods, including UV–Vis, EPR, infrared, as well as X-ray crystallography. In this work, three new cyclam-based ligands L 1 , L 2 and L 3 bearing N-sulfonylacetamide pendant arm and their Cu(II), Zn(II), Cd(II) and Pb(II) complexes were synthesized and characterized by mass spectrometry, NMR, infrared and UV–Vis spectroscopies. The ligands present an original zwitterionic form in which the nitrogen atom of the sulfonylacetamide is deprotonated and one nitrogen of the macrocycle is protonated. This observation was confirmed by X-ray crystallography. The infrared spectra of the ligands revealed very low CO vibrational band values which can be explained by the fact that the oxygen atom is involved in some hydrogen bonds. The amidate form of the sulfonylacetamide arm is maintained upon complexation. Infrared data revealed a probable different coordination mode for Pb(II) than for the other three cations. Some additional studies by UV–Vis and EPR spectroscopies were performed for the Cu(II) complexes. Finally, the geometry coordination of the Cu(II) L 3 , Zn(II) L 3 and Cd(II) L 3 complexes in the solid state was studied by X-ray crystallography.
ISSN:	0020-1693 1873-3255
DOI:	10.1016/j.ica.2011.04.013