Search Results - "Izarova, Natalya V."
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Noble Metals in Polyoxometalates
Published in Angewandte Chemie International Edition (17-09-2012)“…Polyoxometalates containing noble metal ions, such as ruthenium, osmium, rhodium, palladium, platinum, silver and gold, are a structurally diverse class of…”
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Organoarsonate Functionalization of Heteropolyoxotungstates
Published in Inorganic chemistry (20-11-2017)“…Functionalization of the {P8W48} polyoxotungstate (POT) archetype with aromatic organoarsonates results in the first homometallic {P8W48} derivatives, with the…”
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Sequential Isomerization of a Macrocyclic Polyoxometalate Archetype
Published in Inorganic chemistry (15-07-2019)“…Controlled isomerization of individual {α-P2W12O48} polyoxotungstate building blocks under the constricted conditions of the macrocyclic [P8W48O184]40–…”
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Noble Metals in Polyoxometalate Chemistry: Palladium-Containing Derivatives of the Monolacunary Keggin and Wells–Dawson Tungstophosphates
Published in Inorganic chemistry (17-10-2011)“…We have prepared the three novel PdII-containing tungstophosphates [Pd2(α-PW11O39H0.5)2]9– and two structural isomers of [Pd2(α2-P2W17O61H n )2](16–2n)– via…”
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Classical/Non-classical Polyoxometalate Hybrids
Published in Chemistry : a European journal (02-11-2016)“…Two polyanions [SeI V2PdII4WVI14O56H]11− and [SeI V4PdII4WVI28O108H12]12− are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and…”
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Polyoxopalladates Encapsulating 8‑Coordinated Metal Ions, [MO8PdII 12L8] n− (M = Sc3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Lu3+; L = PhAsO3 2–, PhPO3 2–, SeO3 2–)
Published in Inorganic chemistry (17-12-2012)“…A total of 16 discrete polyoxopalladates(II) [MO8PdII 12L8] n−, with a metal ion M encapsulated in a cuboid-shaped {Pd12O8L8} cage, have been synthesized: the…”
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Polyoxopalladates Encapsulating Yttrium and Lanthanide Ions, [XIIIPdII12(AsPh)8O32]5− (X=Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)
Published in Chemistry : a European journal (09-08-2010)“…A series of novel yttrium‐ and lanthanide‐containing heteropolyoxopalladates have been prepared and isolated as hydrated sodium salts,…”
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Synthesis and Biological Activity of Organoantimony(III)-Containing Heteropolytungstates
Published in Inorganic chemistry (05-11-2012)“…Three discrete organoantimony(III)-containing heteropolytungstates [(PhSbIII)4(A-α-GeIVW9O34)2]12– (1), [(PhSbIII)4(A-α-PVW9O34)2]10– (2), and…”
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Tetrapalladium-Containing Polyoxotungstate [PdII 4(α‑P2W15O56)2]16–: A Comparative Study
Published in Inorganic chemistry (03-11-2014)“…The novel tetrapalladium(II)-containing polyoxometalate [PdII 4(α-P2W15O56)2]16– has been prepared in aqueous medium and characterized as its hydrated sodium…”
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Platinum-Containing Polyoxometalates: syn- and anti-[PtII2(α-PW11O39)2]10− and Formation of the Metal-Metal-Bonded di-PtIII Derivatives
Published in Chemistry : a European journal (11-04-2016)“…The first examples of dimeric, di‐PtII‐containing heteropolytungstates are reported. The two isomeric di‐platinum(II)‐containing 22‐tungsto‐2‐phosphates…”
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Organoarsonates Enable Single-Site Condensation of Hexalacunary {P2W12} Polyoxotungstates
Published in Inorganic chemistry (08-01-2024)“…A systematic study of the condensation reactions of arylarsonic-functionalized [α-P2W12O48]14– units in acidic aqueous media identified that the specific…”
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Conductive Self-Assembled Monolayers of Paramagnetic {Co II Co 4 III } and { Co 4 II Co 2 III } Coordination Clusters on Gold Surfaces
Published in Frontiers in chemistry (05-11-2019)“…Two polynuclear cobalt(II,III) complexes, [Co (N ) ( - -bda) (bza·SMe) ] ( ) and [Co (N ) ( - -bda) (bza·SMe) (MeOH) ]Cl ( ), where Hbza·SMe =…”
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Polyoxotungstate Archetype {P4W27} and its 3d Derivatives
Published in Chemistry : a European journal (10-06-2021)“…The propensity of the new, phenylphosphonate‐stabilized polyoxotungstate [(C6H5PVO)2P4W24O92]16− to act as a precursor for new 3d metal‐functionalized…”
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Trigonal Prismatic Coordination of Discrete Rare Earth Ions, Enforced by the Polyoxotungstate [P4W27O99(H2O)]16
Published in Chemistry : a European journal (20-09-2021)“…A family of solution‐stable polyanions [Na⊂{LnIII(H2O)}{WVIO(H2O)}PV4WVI26O98]12− (Ln=Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and Y) represent the first…”
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Expansion of Zirconium Oxide Clusters by 3d/4f Ions
Published in Inorganic chemistry (02-08-2021)“…Two series of charge-neutral coordination clusters featuring quasi-isostructural metal oxide cores, isolated as [Zr6Fe2Ln2O8(ib)14(bda)2(NO3)2]·xMeCN (Ln = La…”
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Controlled Hydrolysis of Phosphate Esters: A Route to Calixarene‐Supported Rare‐Earth Clusters
Published in Chemistry : a European journal (01-03-2023)“…Phosphate ester bonds are widely present in nature (e. g. DNA/RNA) and can be extremely stable against hydrolysis without the help of catalysts. Previously, we…”
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Polyoxometalates Made of Gold: The Polyoxoaurate [AuIII ₄AsV ₄O₂₀]
Published in Angewandte Chemie (International ed.) (01-01-2010)Get full text
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Platinum-Containing Polyoxometalates: syn- and anti-[Pt(II)2(α-PW11O39)2](10-) and Formation of the Metal-Metal-Bonded di-Pt(III) Derivatives
Published in Chemistry : a European journal (11-04-2016)“…The first examples of dimeric, di-Pt(II) -containing heteropolytungstates are reported. The two isomeric di-platinum(II)-containing 22-tungsto-2-phosphates…”
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Probing Frontier Orbital Energies of {Co9(P2W15)3} Polyoxometalate Clusters at Molecule–Metal and Molecule–Water Interfaces
Published in Journal of the American Chemical Society (18-10-2017)“…Functionalization of polyoxotungstates with organoarsonate coligands enabling surface decoration was explored for the triangular cluster architectures of the…”
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Sensing alterations of the local environment of 3d, 4d, and 4f central ions in polyoxopalladates with soft X-ray magnetic dichroisms
Published in Journal of magnetism and magnetic materials (15-11-2020)“…•Tuneable molecular magnets characterized by x-ray absorption spectroscopy.•4f states of some trivalent lanthanide ions are sensitive to axial distortions.•How…”
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