Search Results - "Ito, Kohzo"
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Novel entropic elasticity of polymeric materials: why is slide-ring gel so soft?
Published in Polymer journal (01-01-2012)“…We have recently developed a slide-ring gel that is different from physical and chemical gels by crosslinking polyrotaxane, a necklace-like supramolecule…”
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Slide-Ring Materials Using Cyclodextrin
Published in Chemical & pharmaceutical bulletin (2017)“…We have recently synthesized slide-ring materials using cyclodextrin by cross-linking polyrotaxanes, a typical supramolecule. The slide-ring materials have…”
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From topological gels to slide-ring materials
Published in Journal of applied polymer science (05-08-2014)“…ABSTRACT A novel type of gel, called a topological gel, has been recently developed with a supramolecular architecture with topological characteristics. In the…”
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Mechanical Properties of Ultrathin Polystyrene‑b‑Polybutadiene‑b‑Polystyrene Block Copolymer Films: Film Thickness-Dependent Young’s Modulus
Published in Macromolecules (28-09-2021)“…This study investigated the mechanical properties of ultrathin polystyrene-b-polybutadiene-b-polystyrene (SBS) block copolymer films with thicknesses ranging…”
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Thermally Healable and Reprocessable Bis(hindered amino)disulfide-Cross-Linked Polymethacrylate Networks
Published in ACS macro letters (21-11-2017)“…A facile approach to polymethacrylate networks that contain thermally exchangeable bis(2,2,6,6-tetramethylpiperidin-1-yl)disulfide (BiTEMPS) cross-linkers is…”
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Structure and dynamics of polyrotaxane and slide-ring materials
Published in Polymer (Guilford) (15-02-2010)“…Polyrotaxane (PR), in which cyclic molecules are threaded into a linear polymer chain, has generated great interest because the sliding and rotation of the…”
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Prolonged Glass Transition due to Topological Constraints in Polyrotaxanes
Published in Journal of the American Chemical Society (14-08-2019)“…Topological constraints in polyrotaxanes significantly affected their glass transition dynamics. The effects of the constraints were systematically studied…”
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Stress-strain measurement of ultra-thin polystyrene films: Film thickness and molecular weight dependence of crazing stress
Published in Polymer (Guilford) (11-08-2017)“…In general, self-standing polymer ultra-thin films are difficult to be handled, and therefore their mechanical properties have been poorly understood. We…”
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Effects of Ring Size on the Dynamics of Polyrotaxane Glass
Published in Macromolecules (27-10-2020)“…The dynamics of two polyrotaxanes with different ring component sizes were compared through viscoelastic measurements. An improved polyrotaxane synthesis was…”
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Direct enhancement of intercomponent interactions in polyrotaxane and its pronounced effects on glass state properties
Published in Chemical communications (Cambridge, England) (23-11-2021)“…Strong interactions between the host cyclodextrin and the threading guest polymer were introduced by selective modifications to the polymer of a…”
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Anisotropic Amorphous X‑ray Diffraction Attributed to the Orientation of Cyclodextrin
Published in The journal of physical chemistry letters (06-08-2020)“…The beauty of cyclic molecules is reflected in their host–guest complexation reactions, as well as their unique X-ray diffraction patterns. Cyclodextrins, the…”
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Molecular Dynamics of Polyrotaxane in Solution Investigated by Quasi-Elastic Neutron Scattering and Molecular Dynamics Simulation: Sliding Motion of Rings on Polymer
Published in Journal of the American Chemical Society (19-06-2019)“…In this study, we investigated the molecular dynamics of polyrotaxane (PR), composed of α-cyclodextrins (CDs) and a poly(ethylene glycol) (PEG) axial chain,…”
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Crack velocity dependent toughness of polyrotaxane networks: The sliding dynamics of rings on polymer under stretching
Published in Mechanics of materials (01-05-2021)“…We investigate the fracture toughness of slide-ring (SR) gels, in which polymer chains are cross-linked by ring molecules, at various strain rates to evaluate…”
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Mechanical properties of supramolecular elastomers prepared from polymer-grafted polyrotaxane
Published in Polymer (Guilford) (16-10-2017)“…Supramolecular slide-ring (SR) elastomers without solvent were fabricated by cross-linking of polymer-grafted polyrotaxane in which α-cyclodextrins (CDs) with…”
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Sliding Dynamics of Ring on Polymer in Rotaxane: A Coarse-Grained Molecular Dynamics Simulation Study
Published in Macromolecules (28-05-2019)“…Rotaxane is a topological supramolecule in which a ring molecule is threaded onto an axial chain. A unique feature of rotaxane is that the ring can slide along…”
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Negative interfacial energies of dynamic polymer brush interfaces: a discussion of the free energy balance
Published in Polymer journal (01-08-2023)“…Interfacial energy is an important physical parameter for describing interfacial properties. However, quantifying the interfacial energy of a polymer–liquid…”
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One-Pot Synthesis and Characterization of Polyrotaxane–Silica Hybrid Aerogel
Published in ACS macro letters (21-03-2017)“…A novel kind of polyrotaxane–silica hybrid aerogel is successfully prepared via one-pot sol–gel synthesis in this work. The polyrotaxane can chemically…”
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Mechanical Properties and Swelling Behaviors of Ultrathin Chemically Cross-Linked Polybutadiene Films
Published in Macromolecules (13-06-2023)“…With the advancement of nanoscience and nanotechnology, understanding the unique mechanical properties of ultrathin polymer films is becoming increasingly…”
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Ductile Glass of Polyrotaxane Toughened by Stretch-Induced Intramolecular Phase Separation
Published in ACS applied materials & interfaces (27-09-2017)“…A new class of ductile glasses is created from a thermoplastic polyrotaxane. The hard glass, which has a Young’s modulus of 1 GPa, shows crazing, necking, and…”
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