Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex

A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn(IV)=O adduct is capable of activating C-H bonds by a H-atom transfer mechanism and is more reactive in this regard than most Mn(IV)=O species.

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Bibliographic Details
Published in:	Chemical communications (Cambridge, England) Vol. 49; no. 47; p. 5378
Main Authors:	Leto, Domenick F, Ingram, Rena, Day, Victor W, Jackson, Timothy A
Format:	Journal Article
Language:	English
Published:	England 01-01-2013
Subjects:	Coordination Complexes - chemistry Manganese - chemistry Oxygen - chemistry Spectrum Analysis X-Ray Diffraction
Online Access:	Get more information
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Description
Summary:	A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn(IV)=O adduct is capable of activating C-H bonds by a H-atom transfer mechanism and is more reactive in this regard than most Mn(IV)=O species.
ISSN:	1364-548X
DOI:	10.1039/c3cc00244f