Search Results - "Hutchinson, Robin A"
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Synthesis and Utilization of Low Dispersity Acrylic Macromonomer as Dispersant for Nonaqueous Dispersion Polymerization
Published in Macromolecules (28-08-2018)“…The effect of dispersity on the stabilization performance of poly(butyl methacrylate) (P(BMA)) ω-unsaturated macromonomer used as a reactive dispersant in…”
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Measurement and Modeling of Semi-Batch Solution Radical Copolymerization of N-tert -Butyl Acrylamide with Methyl Acrylate in Ethanol/Water
Published in Polymers (31-12-2022)“…The synthetic polymer industry is transitioning from the use of organic solvents to aqueous media in order to reduce environmental impact. However, with…”
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Determination of Intramolecular Chain Transfer and Midchain Radical Propagation Rate Coefficients for Butyl Acrylate by Pulsed Laser Polymerization
Published in Macromolecules (27-11-2007)“…A novel method to extract individual free-radical polymerization rate coefficients for butyl acrylate intramolecular chain transfer (backbiting), k bb, and for…”
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4
comprehensive kinetic model for high-temperature free radical production of styrene/methacrylate/acrylate resins
Published in AIChE journal (01-01-2011)“…n-Butyl methacrylate/styrene/n-butyl acrylate (BMA/ST/BA) high-temperature starved-feed solution semibatch copolymerization and terpolymerization experiments…”
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Solvent Effects on Radical Copolymerization Kinetics of 2-Hydroxyethyl Methacrylate and Butyl Methacrylate
Published in Polymers (13-03-2019)“…2-Hydroxyethyl methacrylate (HEMA) is an important component of many acrylic resins used in coatings formulations, as the functionality ensures that the chains…”
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6
Continuous Controlled Radical Polymerization of Methyl Acrylate in a Copper Tubular Reactor
Published in Macromolecular rapid communications. (04-04-2011)“…The use of copper tubing as both the reactor and as a catalyst source is demonstrated for continuous controlled radical polymerization of methyl acrylate at…”
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The Effect of Hydrogen Bonding on Intramolecular Chain Transfer in Polymerization of Acrylates
Published in Macromolecular rapid communications. (15-07-2011)“…Propagation rate coefficients (kp) for 2‐hydroxyethyl acrylate (HEA) have been determined by pulsed‐laser polymerization (PLP) combined with size‐exclusion…”
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Investigation of Free-Radical Copolymerization Propagation Kinetics of Vinyl Acetate and Methyl Methacrylate
Published in The journal of physical chemistry. B (01-04-2010)“…The free-radical copolymerization propagation kinetics of vinyl acetate (VAc) and methyl methacrylate (MMA) at 50 °C were investigated through an experimental…”
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Radical Propagation Kinetics of N-Vinylpyrrolidone in Organic Solvents Studied by Pulsed-Laser Polymerization-Size-Exclusion Chromatography (PLP-SEC)
Published in Macromolecular chemistry and physics (01-12-2014)“…Pulsed‐laser polymerization with subsequent analysis of the polymer molar mass distribution by size‐exclusion chromatography, PLP–SEC, is used to measure the…”
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10
Continuous ARGET ATRP of Methyl Methacrylate and Butyl Acrylate in a Stirred Tank Reactor
Published in Industrial & engineering chemistry research (28-08-2013)“…Activator regenerated by electron transfer atom-transfer radical polymerization of butyl acrylate and methyl methacrylate was successfully adapted from a batch…”
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11
Quantitative analyses to estimate the bioaccessibility of a hydrolytically degradable cationic flocculant
Published in Heliyon (01-12-2021)“…Poly(lactic acid) choline iodide ester methacrylate, poly(PLA4ChMA), is a cationic degradable polymer that can flocculate particles and dewater oil sands from…”
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12
Secondary Reactions in the High-Temperature Free Radical Polymerization of Butyl Acrylate
Published in Macromolecules (10-08-2004)“…Secondary reactions have a marked effect on butyl acrylate polymerization rate and polymer structure under the high-temperature free radical reaction…”
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13
Innovative process for facile dextran-bovine serum albumin conjugate synthesis: Mechanism, kinetics, and characterization
Published in Carbohydrate polymers (01-11-2022)“…Three process variations are developed to synthesize dextran-bovine serum albumin (BSA) model conjugate through the Maillard reaction and a Schiff base-Amadori…”
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Deterministic Approach to Estimate Functionality of Chains Produced by Radical Copolymerization in the Presence of Secondary Reactions
Published in Macromolecules (28-07-2020)“…Functional acrylic resins for the coatings and adhesives industry are often synthesized by radical solution copolymerization at high temperatures (>120 °C)…”
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15
Modeling the Distribution of Functional Groups in Semibatch Radical Copolymerization: An Accelerated Stochastic Approach
Published in Industrial & engineering chemistry research (25-07-2018)“…While Kinetic Monte Carlo (KMC) techniques provide a powerful means to model polymer microstructure, the associated computational cost has been a barrier to…”
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The Effect of Hydrogen Bonding on Radical Semi-Batch Copolymerization of Butyl Acrylate and 2-Hydroxyethyl Acrylate
Published in Polymers (17-08-2017)“…The radical copolymerization of butyl acrylate (BA) and 2-hydroxyethyl acrylate (HEA) was investigated under batch and semi-batch operations, with a focus on…”
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Free-Radical Propagation Kinetics of N-Vinyl Formamide in Aqueous Solution Studied by PLP-SEC
Published in Macromolecular chemistry and physics (01-03-2010)“…The propagation rate coefficients, kp, were determined for free‐radical polymerization of N‐vinyl formamide (NVF) in aqueous solution by pulsed‐laser‐initiated…”
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The effect of hydrogen bonding on the copolymerization kinetics of 2‐methoxyethyl acrylate with 2‐hydroxyethyl methacrylate in alcohol and aqueous solutions
Published in Canadian journal of chemical engineering (01-04-2022)“…The influence of alcohol and alcohol/water solutions on the radical copolymerization kinetics of 2‐hydroxyethyl methacrylate (HEMA) with 2‐methoxyethyl…”
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Estimating the bioaccessibility of flocculants in the presence of sediments in model wastewater
Published in Environmental pollution (1987) (15-12-2022)“…The cationic degradable polymer poly(lactic acid) choline iodide ester methacrylate, poly(PLA4ChMA), can be used to flocculate particles and dewater sediments…”
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The Use of High‐Temperature Semi‐Batch Radical Polymerization to Synthesize Acrylate Based Macromonomers and Structured Copolymers
Published in Macromolecular chemistry and physics (01-01-2024)“…A high‐temperature starved‐feed semi‐batch operating policy is developed to produce p(acrylates) with high macromonomer content, taking advantage of side…”
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