Search Results - "Humphries, Terry"
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Producing Alkali Metal Hydrides from Hydroxides
Published in Inorganic chemistry (12-02-2024)“…In this study, a novel method for producing different alkali metal hydrides (NaH, KH, RbH, and CsH) from their corresponding metal hydroxides (NaOH, KOH, RbOH,…”
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Future perspectives of thermal energy storage with metal hydrides
Published in International journal of hydrogen energy (22-03-2019)“…Thermochemical energy storage materials have advantage of much higher energy densities compared to latent or sensible heat storage materials. Metal hydrides…”
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Materials for hydrogen-based energy storage – past, recent progress and future outlook
Published in Journal of alloys and compounds (25-06-2020)“…Globally, the accelerating use of renewable energy sources, enabled by increased efficiencies and reduced costs, and driven by the need to mitigate the effects…”
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Thermodynamic destablization of SrH2 using Al for the next generation of high temperature thermal batteries
Published in Journal of alloys and compounds (15-02-2022)“…•The SrH2 and 2Al system was studied for thermochemical energy storage applications.•Thermodynamic destablization was observed compared to pure strontium…”
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Rare Earth Borohydrides—Crystal Structures and Thermal Properties
Published in Energies (Basel) (01-12-2017)“…Rare earth (RE) borohydrides have received considerable attention during the past ten years as possible hydrogen storage materials due to their relatively high…”
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Hydroxylated closo-Dodecaborates M2B12(OH)12 (M = Li, Na, K, and Cs); Structural Analysis, Thermal Properties, and Solid-State Ionic Conductivity
Published in Journal of physical chemistry. C (28-05-2020)“…Closo-borates and derivatives thereof have shown great potential as electrolyte materials for all-solid-state batteries owing to their exceptional ionic…”
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Exploring halide destabilised calcium hydride as a high-temperature thermal battery
Published in Journal of alloys and compounds (05-04-2020)“…CaH2 is a metal hydride with a high energy density that decomposes around 1100 °C at 1 bar of H2 pressure. Due to this high decomposition temperature, it is…”
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High-temperature thermochemical energy storage using metal hydrides: Destabilisation of calcium hydride with silicon
Published in Journal of alloys and compounds (25-03-2021)“…The thermochemical energy storage properties of calcium hydride (CaH2) destabilised with either silicon (Si) or CaxSiy compounds at various molar ratios, were…”
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Metallic and complex hydride-based electrochemical storage of energy
Published in Progress in energy and combustion science (01-07-2022)“…The development of efficient storage systems is one of the keys to the success of the energy transition. There are many ways to store energy, but among them,…”
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Hydrogen storage properties of eutectic metal borohydrides melt-infiltrated into porous Al scaffolds
Published in Journal of alloys and compounds (15-02-2019)“…Porous Al scaffolds were synthesised and melt-infiltrated with various eutectic metal borohydride mixtures (0.725LiBH4-0.275KBH4, 0.68NaBH4-0.32KBH4,…”
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Efficient Synthesis of an Aluminum Amidoborane Ammoniate
Published in Energies (Basel) (01-09-2015)“…A novel species of metal amidoborane ammoniate, [Al(NH2BH3)63-][Al(NH3)63+] has been successfully synthesized in up to 95% via the one-step reaction of…”
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Fluorine Substitution in Magnesium Hydride as a Tool for Thermodynamic Control
Published in Journal of physical chemistry. C (30-04-2020)“…Metal hydrides continue to vie for attention as materials in multiple technological applications including hydrogen storage media, thermal energy storage (TES)…”
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Physicochemical Characterization of a Na–H–F Thermal Battery Material
Published in Journal of physical chemistry. C (05-03-2020)“…Fluorine-substituted sodium hydride is investigated for application as a thermal energy storage material inside thermal batteries. A range of compositions of…”
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Synthesis of NaAlH4/Al composites and their applications in hydrogen storage
Published in International journal of hydrogen energy (06-09-2018)“…In solid-state hydrogen storage in light metal hydrides, nanoconfinement and the use of catalysts represent promising solutions to overcoming limitations such…”
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Reversible Hydrogenation Studies of NaBH4 Milled with Ni-Containing Additives
Published in Journal of physical chemistry. C (28-03-2013)“…NaBH4 has long been identified as a viable hydrogen-storage material due to a theoretical gravimetric H2 capacity of 10.6 wt %. Because of the high enthalpy of…”
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Enhanced tunability of thermodynamic stability of complex hydrides by the incorporation of H– anions
Published in Applied physics letters (19-05-2014)“…First-principles calculations were employed to investigate hypothetical complex hydrides (M,M′)4FeH8 (M = Na, Li; M′=Mg, Zn, Y, Al). Besides complex anion…”
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State-of-the-Art and Progress in Metal-Hydrogen Systems
Published in Inorganics (01-12-2023)“…Hydrogen is heralded as a future global energy carrier [...]…”
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Regeneration of LiAlH4 at sub-ambient temperatures studied by multinuclear NMR spectroscopy
Published in Journal of alloys and compounds (05-11-2017)“…Lithium aluminium hydride (LiAlH4) has long been identified as a viable hydrogen storage material, due to its high attainable theoretical gravimetric hydrogen…”
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Establishing ZIF‐8 as a reference material for hydrogen cryoadsorption: An interlaboratory study
Published in Chemphyschem (01-03-2024)“…Hydrogen storage by cryoadsorption on porous materials has the advantages of low material cost, safety, fast kinetics, and high cyclic stability. The further…”
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Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru
Published in Coordination chemistry reviews (01-07-2017)“…[Display omitted] •Complex Transition Metal Hydrides of Ni, Fe, Co and Ru have been explored.•All analogues of [NiH4]4−, [FeH6]4−, [CoH5]4− and [RuH6]4− anions…”
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