Search Results - "Huh, Daniel N."

Engineering electronic structure to prolong relaxation times in molecular qubits by minimising orbital angular momentum by Ariciu, Ana-Maria, Woen, David H., Huh, Daniel N., Nodaraki, Lydia E., Kostopoulos, Andreas K., Goodwin, Conrad A. P., Chilton, Nicholas F., McInnes, Eric J. L., Winpenny, Richard E. P., Evans, William J., Tuna, Floriana

“…The proposal that paramagnetic transition metal complexes could be used as qubits for quantum information processing (QIP) requires that the molecules retain…”
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Reassessment of N 2 activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N 2 adduct is actually an arene adduct by Huh, Daniel N, Koby, Ross F, Stuart, Zoe E, Dunscomb, Rachel J, Schley, Nathan D, Tonks, Ian A

“…The complex {(TMEDA) Li}{[Ti(N(TMS) ) ] (μ-η :η -N ) } (5-Li) is the only transition metal N complex ever reported with two side-on N adducts. In this report,…”
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Crystal structure of the [(THF)Cs(μ-η 5 :η 5 -Cp') 3 Yb] n oligomer by Huh, Daniel N, Ziller, Joseph W, Evans, William J

“…The green compound poly[(tetra-hydro-furan)-tris-[μ-η :η -1-(tri-methyl-sil-yl)cyclo-penta-dien-yl]caesium(I)ytterbium(II)], [CsYb(C H Si) (C H O)] or…”
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Multicomponent syntheses of 5- and 6-membered aromatic heterocycles using group 4-8 transition metal catalysts by Huh, Daniel N, Cheng, Yukun, Frye, Connor W, Egger, Dominic T, Tonks, Ian A

“…In this Perspective , we discuss recent syntheses of 5- and 6-membered aromatic heterocycles via multicomponent reactions (MCRs) that are catalyzed by group…”
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Synthesis of Ln(II)-in-Cryptand Complexes by Chemical Reduction of Ln(III)-in-Cryptand Precursors: Isolation of a Nd(II)-in-Cryptand Complex by Ciccone, Sierra R, Huh, Daniel N, Evans, William J, Roy, Saswata, Bekoe, Samuel, Furche, Filipp

“…Lanthanide triflates have been used to incorporate Nd(III) and Sm(III) ions into the 2.2.2-cryptand ligand (crypt) to explore their reductive chemistry.  The…”
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Facile Encapsulation of Ln(II) Ions into Cryptate Complexes from LnI2(THF)2 Precursors (Ln = Sm, Eu, Yb) by Huh, Daniel N, Ziller, Joseph W, Evans, William J

“…The reactivity of LnI2(THF)2 (Ln = Sm, Eu, Yb; THF = tetrahydrofuran) with 2.2.2-cryptand (crypt) was explored to see if these readily accessible precursors…”
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Ligand Effects on the Spin Relaxation Dynamics and Coherent Manipulation of Organometallic La(II) Potential Qu d its by Nodaraki, Lydia E, Ariciu, Ana-Maria, Huh, Daniel N, Liu, Jingjing, Martins, Daniel O T A, Ortu, Fabrizio, Winpenny, Richard E P, Chilton, Nicholas F, McInnes, Eric J L, Mills, David P, Evans, William J, Tuna, Floriana

“…We present pulsed electron paramagnetic resonance (EPR) studies on three La(II) complexes, [K(2.2.2-cryptand)][La(Cp') ] ( ), [K(2.2.2-cryptand)][La(Cp″) ] (…”
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Ligand Effects on the Spin Relaxation Dynamics and Coherent Manipulation of Organometallic La(II) Potential Qudits by Nodaraki, Lydia E., Ariciu, Ana-Maria, Huh, Daniel N., Liu, Jingjing, Martins, Daniel O. T. A., Ortu, Fabrizio, Winpenny, Richard E. P., Chilton, Nicholas F., McInnes, Eric J. L., Mills, David P., Evans, William J., Tuna, Floriana

“…We present pulsed electron paramagnetic resonance (EPR) studies on three La­(II) complexes, [K­(2.2.2-cryptand)]­[La­(Cp′)3] (1),…”
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Reassessment of N2 activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N2 adduct is actually an arene adduct by Huh, Daniel N, Koby, Ross F, Stuart, Zoe E, Dunscomb, Rachel J, Schley, Nathan D, Tonks, Ian A

“…The complex {(TMEDA)2Li}{[Ti(N(TMS)2)2]2(μ-η2:η2-N2)2} (5-Li) is the only transition metal N2 complex ever reported with two side-on N2 adducts. In this…”
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Facile Encapsulation of Ln(II) Ions into Cryptate Complexes from LnI 2 (THF) 2 Precursors (Ln = Sm, Eu, Yb) by Huh, Daniel N, Ziller, Joseph W, Evans, William J

“…The reactivity of LnI (THF) (Ln = Sm, Eu, Yb; THF = tetrahydrofuran) with 2.2.2-cryptand (crypt) was explored to see if these readily accessible precursors…”
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Stabilization of U(III) to Oxidation and Hydrolysis by Encapsulation Using 2.2.2-Cryptand by Huh, Daniel N, Barlow, Jeffrey M, Ciccone, Sierra R, Ziller, Joseph W, Yang, Jenny Y, Evans, William J

“…The electrochemical properties of U­(III)-in-crypt (crypt = 2.2.2-cryptand) were examined in dimethylformamide (DMF) and acetonitrile (MeCN) to determine the…”
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High-Resolution X-ray Photoelectron Spectroscopy of Organometallic (C 5 H 4 SiMe 3 ) 3 Ln III and [(C 5 H 4 SiMe 3 ) 3 Ln II ] 1- Complexes (Ln = Sm, Eu, Gd, Tb) by Huh, Daniel N, Bruce, Jared P, Ganesh Balasubramani, Sree, Ciccone, Sierra R, Furche, Filipp, Hemminger, John C, Evans, William J

“…The capacity of X-ray photoelectron spectroscopy (XPS) to provide information on the electronic structure of molecular organometallic complexes of Ln(II) ions…”
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A Single Small-Scale Plutonium Redox Reaction System Yields Three Crystallographically-Characterizable Organoplutonium Complexes by Windorff, Cory J, Sperling, Joseph M, Albrecht-Schönzart, Thomas E, Bai, Zhuanling, Evans, William J, Gaiser, Alyssa N, Gaunt, Andrew J, Goodwin, Conrad A. P, Hobart, David E, Huffman, Zachary K, Huh, Daniel N, Klamm, Bonnie E, Poe, Todd N, Warzecha, Evan

“…An approach to obtaining substantial amounts of data from a hazardous starting material that can only be obtained and handled in small quantities is…”
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Chelate-Free Synthesis of the U(II) Complex, [(C5H3(SiMe3)2)3U]1–, Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs by Huh, Daniel N., Ziller, Joseph W., Evans, William J.

“…To expand the range of synthetic options for generating complexes of the actinide metals in the +2 oxidation state, reduction of Cp″3U (Cp″ = C5H3(SiMe3)2) and…”
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Isolation of a Square-Planar Th(III) Complex: Synthesis and Structure of [Th(OC6H2 tBu2‑2,6-Me-4)4]1 by Huh, Daniel N, Roy, Saswata, Ziller, Joseph W, Furche, Filipp, Evans, William J

“…Reduction of Th­(OC6H2 tBu2-2,6-Me-4)4 using either KC8 or Li in THF forms a new example of a crystallographically characterizable Th­(III) complex in the…”
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Synthesis of LnII‐in‐Cryptand Complexes by Chemical Reduction of LnIII‐in‐Cryptand Precursors: Isolation of a NdII‐in‐Cryptand Complex by Huh, Daniel N., Ciccone, Sierra R., Bekoe, Samuel, Roy, Saswata, Ziller, Joseph W., Furche, Filipp, Evans, William J.

“…Lanthanide triflates have been used to incorporate NdIII and SmIII ions into the 2.2.2‐cryptand ligand (crypt) to explore their reductive chemistry. The…”
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Electronic structure analysis and reactivity of the bimetallic bis-titanocene vinylcarboxylate complex, [(Cp2Ti)2(O2C3TMS2)] by Huh, Daniel N., Maity, Asim, Van Trieste, Gerard P., Schley, Nathan D., Powers, David C., Tonks, Ian A.

“…The reactivity and redox behavior of the bimetallic TiIII/TiIII complex, [(Cp2Ti)2(O2C3TMS2)], has been examined using isocyanides, TMSCl, and MeI. The…”
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Synthesis of Ba(II) analogs of Ln(II)-in-(2.2.2-cryptand) and layered hexagonal net Ln(II) complexes, [(THF)Cs(µ–η5:η5–C5H4SiMe3)3LnII] by Huh, Daniel N., Ciccone, Sierra R., Moore, William N.G., Ziller, Joseph W., Evans, William J.

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4f-Orbital mixing increases the magnetic susceptibility of Cp′3Eu by Gunther, S Olivia, Qiao, Yusen, Smith, Patrick W, Ciccone, Sierra R, Ditter, Alexander S, Huh, Daniel N, Moreau, Liane M, Shuh, David K, Sun, Taoxiang, Arnold, Polly L, Booth, Corwin H, de Jong, Wibe A, Evans, William J, Lukens, Wayne W, Minasian, Stefan G

“…Traditional models of lanthanide electronic structure suggest that bonding is predominantly ionic, and that covalent orbital mixing is not an important factor…”
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4f-Orbital mixing increases the magnetic susceptibility of Cp' 3 Eu by Gunther, S Olivia, Qiao, Yusen, Smith, Patrick W, Ciccone, Sierra R, Ditter, Alexander S, Huh, Daniel N, Moreau, Liane M, Shuh, David K, Sun, Taoxiang, Arnold, Polly L, Booth, Corwin H, de Jong, Wibe A, Evans, William J, Lukens, Jr, Wayne W, Minasian, Stefan G

“…Traditional models of lanthanide electronic structure suggest that bonding is predominantly ionic, and that covalent orbital mixing is not an important factor…”
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