Search Results - "Hrib, Cristian G."
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1
Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair
Published in Angewandte Chemie (International ed.) (15-09-2008)“…Relief from frustration: The sterically demanding carbene 1,3‐di‐tert‐butylimidazolin‐2‐ylidene and B(C6F5)3, a “frustrated” Lewis pair, is a viable system for…”
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2
Efficient Room-Temperature Alkyne Metathesis with Well-Defined Imidazolin-2-iminato Tungsten Alkylidyne Complexes
Published in Angewandte Chemie (International ed.) (01-01-2007)“…It's a game of give and take: Following the successful design strategy for high‐oxidation‐state alkene metathesis catalysts of the Schrock type, one of the…”
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3
The First Linear, Homoleptic Triple-Decker Sandwich Complex of an f-Element: A Molecular Model for Organolanthanide Nanowires
Published in Organometallics (08-11-2010)“…The first structurally authenticated linear, homoleptic triple-decker sandwich complex of an f-element, (η8-COT′′)Nd(μ-η8:η8-COT′′)Nd(η8-COT′′) (2; COT′′ =…”
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4
Secondary Interactions in Phosphane‐Functionalized Group 4 Cycloheptatrienyl–Cyclopentadienyl Sandwich Complexes
Published in Chemistry : a European journal (01-01-2009)“…Twice as reactive: The coordination chemistry of phosphane‐functionalized Zr and Hf cycloheptatrienyl–cyclopentadienyl complexes gives rise to unusual…”
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5
Ruthenium-Catalyzed Functionalization of Pyrroles and Indoles with Propargyl Alcohols
Published in Chemistry : a European journal (14-05-2012)“…Several ruthenium‐catalyzed atom‐economic transformations of propargyl alcohols with pyrroles or indoles leading to alkylated, propargylated, or annulated…”
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6
New Lanthanide Alkynylamidinates and Diiminophosphinates
Published in Inorganics (01-12-2015)“…This contribution reports the synthesis and structural characterization of several new lithium and lanthanide alkynylamidinate complexes. Treatment of PhC≡CLi…”
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7
Structures and Energetic Properties of Two New Salts Comprising the 5,5'-Azotetrazolate Dianion
Published in Crystals (Basel) (01-09-2015)“…Two new potentially energetic salts comprising the 5,5'-azotetrazolate dianion have been prepared and structurally characterized. The new azotetrazolates are…”
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Quinine-Derived Imidazolidin-2-imine Ligands: Synthesis, Coordination Chemistry, and Application in Catalytic Transfer Hydrogenation
Published in ZAAC - Journal of Inorganic and General Chemistry (01-04-2010)“…Two new optically active bidentate N,N‐ligands, DMIQCI (3a) and DMIQCD (3b), containing a quinuclidine core and an imidazolidin‐2‐imine unit, were synthesized…”
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Crystallization and Structure Determination of Fac-Triammin-Aquo-Oxalato-Cobalt (III)-Nitrate Monohydrate
Published in Crystals (Basel) (01-12-2014)“…The title compound, fac-triammin-aquo-oxalato-cobalt(III)-nitrate monohydrate, fac-[Co(NH3)3(C2O4)(H2O)]NO3*H2O (2), was prepared according to an original…”
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10
4-Bromo-2-[5-methyl-2-(morpholin-4-yl)-1,3-thia-zol-4-yl]phenol
Published in Acta crystallographica. Section E, Structure reports online (01-07-2013)“…In the title compound, C14H15BrN2O2S, synthesized by the reaction of the corresponding phenacyl thio-cyanate with morpholine, the dihedral angle between the…”
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11
Bromidobis[3-(1H-pyrazol-1-yl-κN(2))propionamide-κO]copper(II) bromide methanol monosolvate
Published in Acta crystallographica. Section E, Structure reports online (01-10-2012)“…The title copper(II) N-pyrazolylpropanamide (PPA) complex, [CuBr(PPA)(2)]Br, was obtained in 78% yield by treatment of CuBr(2) with an excess of the ligand in…”
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12
Di-μ-oxido-bis-[bis-(diiso-propyl-aceta-midinato)-κN;κ(2) N,N'-germanium(IV)]
Published in Acta crystallographica. Section E, Structure reports online (01-12-2013)“…The title compound, [Ge2(C8H17N2)4O2], crystallizes with imposed twofold symmetry, which allows the monodentate amidinate ligands to be arranged in a cisoid…”
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13
Rare-Earth Metal Alkyl, Amido, and Cyclopentadienyl Complexes Supported by Imidazolin-2-iminato Ligands: Synthesis, Structural Characterization, and Catalytic Application
Published in Inorganic chemistry (01-03-2010)“…The rare earth metal dichlorides [(1)MCl2(THF)3] (2a, M = Sc; 2b, M = Y; 2c, M = Lu) and the gadolinium complex [(1)GdCl2(THF)2]·[LiCl(THF)2] (2d), containing…”
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14
Steric Effects in Lanthanide Sandwich Complexes Containing Bulky Cyclooctatetraenyl Ligands
Published in Organometallics (11-03-2013)“…This paper gives a full account of the complex reaction system LnCl3/(COT″)2– (COT″ = 1,4-bis(trimethylsilyl)cyclooctatetraenyl dianion). Four different series…”
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15
Molecular and Crystal Structure of a New High Energy Density Material: Aminoguanidinium-styphnate, [H2NNHC(NH2)2]2[C6HO2(NO2)3]
Published in Crystals (Basel) (04-01-2012)“…The title compound [H2NNHC(NH2)2]2[C6HO2(NO2)3] (2) was prepared in 85% yield by treatment of sodium styphnate with 2 equivalents of aminoguanidinium nitrate,…”
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16
Experimental and Theoretical Investigations of Catalytic Alkyne Cross-Metathesis with Imidazolin-2-iminato Tungsten Alkylidyne Complexes
Published in Organometallics (09-03-2009)“…The imidazolin-2-iminato tungsten alkylidyne complexes [Me3CC≡W(NImR)(OR′)2] (4a: R = tBu, R′ = CMe3; 4b: R = Dipp, R′ = CMe3; 5a: R = tBu, R′ = CMe(CF3)2; 5b:…”
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17
Carboranylamidinates
Published in Journal of the American Chemical Society (10-11-2010)“…Carboranylamidinate anions are readily accessible via addition of N,N′-dialkylcarbodiimides to lithio-ortho-carborane. They represent a novel difunctional…”
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18
Lanthanide(III) Sandwich and Half‐Sandwich Complexes with Bulky Cyclooctatetraenyl Ligands: Synthesis, Structures, and Magnetic Properties
Published in European journal of inorganic chemistry (09-11-2017)“…Five new lanthanide(III) sandwich and half‐sandwich complexes with bulky cyclooctatetraenyl ligands have been prepared and fully characterized, including…”
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19
Imidazolin-2-iminato Complexes of Rare Earth Metals with Very Short Metal−Nitrogen Bonds: Experimental and Theoretical Studies
Published in Inorganic chemistry (15-06-2009)“…The reactions of 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-imine (ImDippNH, 1-H) with trimethylsilylmethyl lithium (LiCH2SiMe3) and anhydrous rare earth metal…”
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20
Heterometallic Europium Disiloxanediolates: Synthesis, Structural Diversity, and Photoluminescence Properties
Published in Inorganic chemistry (03-11-2014)“…This contribution presents a full account of a structurally diverse class of heterometallic europium disiloxanediolates. The synthetic protocol involves in…”
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