Search Results - "House, Robert A."

Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes by House, Robert A., Maitra, Urmimala, Pérez-Osorio, Miguel A., Lozano, Juan G., Jin, Liyu, Somerville, James W., Duda, Laurent C., Nag, Abhishek, Walters, Andrew, Zhou, Ke-Jin, Roberts, Matthew R., Bruce, Peter G.

“…In conventional intercalation cathodes, alkali metal ions can move in and out of a layered material with the charge being compensated for by reversible…”
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Transition metal migration and O2 formation underpin voltage hysteresis in oxygen-redox disordered rocksalt cathodes by McColl, Kit, House, Robert A., Rees, Gregory J., Squires, Alexander G., Coles, Samuel W., Bruce, Peter G., Morgan, Benjamin J., Islam, M. Saiful

“…Lithium-rich disordered rocksalt cathodes display high capacities arising from redox chemistry on both transition-metal ions (TM-redox) and oxygen ions…”
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Redox Chemistry and the Role of Trapped Molecular O2 in Li-Rich Disordered Rocksalt Oxyfluoride Cathodes by Sharpe, Ryan, House, Robert A, Clarke, Matt J, Förstermann, Dominic, Marie, John-Joseph, Cibin, Giannantonio, Zhou, Ke-Jin, Playford, Helen Y, Bruce, Peter G, Islam, M. Saiful

“…In the search for high energy density cathodes for next-generation lithium-ion batteries, the disordered rocksalt oxyfluorides are receiving significant…”
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The Role of Ni and Co in Suppressing O‐Loss in Li‐Rich Layered Cathodes by Boivin, Edouard, Guerrini, Niccolo, House, Robert A., Lozano, Juan G., Jin, Liyu, Rees, Gregory J., Somerville, James W., Kuss, Christian, Roberts, Matthew R., Bruce, Peter G.

“…Lithium‐rich transition metal cathodes can deliver higher capacities than stoichiometric materials by exploiting redox reactions on oxygen. However, oxidation…”
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Covalency does not suppress O2 formation in 4d and 5d Li-rich O-redox cathodes by House, Robert A., Marie, John-Joseph, Park, Joohyuk, Rees, Gregory J., Agrestini, Stefano, Nag, Abhishek, Garcia-Fernandez, Mirian, Zhou, Ke-Jin, Bruce, Peter G.

“…Layered Li-rich transition metal oxides undergo O-redox, involving the oxidation of the O 2− ions charge compensated by extraction of Li + ions. Recent results…”
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The effect of volume change and stack pressure on solid‐state battery cathodes by Liu, Boyang, Pu, Shengda D., Doerrer, Christopher, Spencer Jolly, Dominic, House, Robert A., Melvin, Dominic L. R., Adamson, Paul, Grant, Patrick S., Gao, Xiangwen, Bruce, Peter G.

“…Abstract Solid‐state lithium batteries may provide increased energy density and improved safety compared with Li‐ion technology. However, in a solid‐state…”
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Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2 by Maitra, Urmimala, House, Robert A., Somerville, James W., Tapia-Ruiz, Nuria, Lozano, Juan G., Guerrini, Niccoló, Hao, Rong, Luo, Kun, Jin, Liyu, Pérez-Osorio, Miguel A., Massel, Felix, Pickup, David M., Ramos, Silvia, Lu, Xingye, McNally, Daniel E., Chadwick, Alan V., Giustino, Feliciano, Schmitt, Thorsten, Duda, Laurent C., Roberts, Matthew R., Bruce, Peter G.

“…The search for improved energy-storage materials has revealed Li- and Na-rich intercalation compounds as promising high-capacity cathodes. They exhibit…”
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The role of O2 in O-redox cathodes for Li-ion batteries by House, Robert A., Marie, John-Joseph, Pérez-Osorio, Miguel A., Rees, Gregory J., Boivin, Edouard, Bruce, Peter G.

“…The energy density of Li-ion batteries can be improved by storing charge at high voltages through the oxidation of oxide ions in the cathode material. However,…”
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Oxygen redox chemistry without excess alkali-metal ions in Na 2/3 [Mg 0.28 Mn 0.72 ]O 2 by Maitra, Urmimala, House, Robert A, Somerville, James W, Tapia-Ruiz, Nuria, Lozano, Juan G, Guerrini, Niccoló, Hao, Rong, Luo, Kun, Jin, Liyu, Pérez-Osorio, Miguel A, Massel, Felix, Pickup, David M, Ramos, Silvia, Lu, Xingye, McNally, Daniel E, Chadwick, Alan V, Giustino, Feliciano, Schmitt, Thorsten, Duda, Laurent C, Roberts, Matthew R, Bruce, Peter G

“…The search for improved energy-storage materials has revealed Li- and Na-rich intercalation compounds as promising high-capacity cathodes. They exhibit…”
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Controlling Iron Versus Oxygen Redox in the Layered Cathode Na0.67Fe0.5Mn0.5O2: Mitigating Voltage and Capacity Fade by Mg Substitution by Boivin, Edouard, House, Robert A., Marie, John‐Joseph, Bruce, Peter G.

“…Layered oxides for Na‐ion batteries containing Fe have attracted strong interest mainly due to their low cost. However, full oxidation of Fe3+ to Fe4+ is…”
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First-cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk by House, Robert A., Rees, Gregory J., Pérez-Osorio, Miguel A., Marie, John-Joseph, Boivin, Edouard, Robertson, Alex W., Nag, Abhishek, Garcia-Fernandez, Mirian, Zhou, Ke-Jin, Bruce, Peter G.

“…Li-rich cathode materials are potential candidates for next-generation Li-ion batteries. However, they exhibit a large voltage hysteresis on the first…”
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Trapped O2 and the origin of voltage fade in layered Li-rich cathodes by Marie, John-Joseph, House, Robert A., Rees, Gregory J., Robertson, Alex W., Jenkins, Max, Chen, Jun, Agrestini, Stefano, Garcia-Fernandez, Mirian, Zhou, Ke-Jin, Bruce, Peter G.

“…Oxygen redox cathodes, such as Li 1.2 Ni 0.13 Co 0.13 Mn 0.54 O 2 , deliver higher energy densities than those based on transition metal redox alone. However,…”
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Visualization of Tetrahedral Li in the Alkali Layers of Li-Rich Layered Metal Oxides by Song, Weixin, Pérez-Osorio, Miguel A., Chen, Jun, Ding, Zhiyuan, Marie, John-Joseph, Juelsholt, Mikkel, House, Robert A., Bruce, Peter G., Nellist, Peter D.

“…Understanding Li+ ion diffusion pathways in Li-rich layered transition metal (TM) oxides is crucial for understanding the sluggish kinetics in anionic O2–…”
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Reversible Electron–Holes on O in P2‐type Na0.67Li0.1Ni0.3Mn0.6O2 by Marie, John‐Joseph, Jenkins, Max, Chen, Jun, Rees, Gregory, Cellorio, Veronica, Choi, Jaewon, Agrestini, Stefano, Garcia‐Fernandez, Mirian, Zhou, Ke‐Jin, House, Robert A., Bruce, Peter G.

“…Achieving reversible O‐redox through the formation of electron–holes on O could hold the key to a new generation of high energy density Na‐ion cathodes…”
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Delocalized electron holes on oxygen in a battery cathode by House, Robert A., Rees, Gregory J., McColl, Kit, Marie, John-Joseph, Garcia-Fernandez, Mirian, Nag, Abhishek, Zhou, Ke-Jin, Cassidy, Simon, Morgan, Benjamin J., Saiful Islam, M., Bruce, Peter G.

“…Oxide ions in transition metal oxide cathodes can store charge at high voltage offering a route towards higher energy density batteries. However, upon charging…”
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Transition metal migration and O 2 formation underpin voltage hysteresis in oxygen-redox disordered rocksalt cathodes by McColl, Kit, House, Robert A, Rees, Gregory J, Squires, Alexander G, Coles, Samuel W, Bruce, Peter G, Morgan, Benjamin J, Islam, M Saiful

“…Lithium-rich disordered rocksalt cathodes display high capacities arising from redox chemistry on both transition-metal ions (TM-redox) and oxygen ions…”
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Current-Density-Dependent Electroplating in Ca Electrolytes: From Globules to Dendrites by Pu, Shengda D, Gong, Chen, Gao, Xiangwen, Ning, Ziyang, Yang, Sixie, Marie, John-Joseph, Liu, Boyang, House, Robert A, Hartley, Gareth O, Luo, Jun, Bruce, Peter G, Robertson, Alex W

“…Multivalent cation rechargeable batteries, including those based on Ca, Mg, Al, etc., have attracted considerable interest as candidates for beyond Li-ion…”
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What Triggers Oxygen Loss in Oxygen Redox Cathode Materials? by House, Robert A, Maitra, Urmimala, Jin, Liyu, Lozano, Juan G, Somerville, James W, Rees, Nicholas H, Naylor, Andrew J, Duda, Laurent C, Massel, Felix, Chadwick, Alan V, Ramos, Silvia, Pickup, David M, McNally, Daniel E, Lu, Xingye, Schmitt, Thorsten, Roberts, Matthew R, Bruce, Peter G

“…It is possible to increase the charge capacity of transition-metal (TM) oxide cathodes in alkali-ion batteries by invoking redox reactions on the oxygen…”
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Redox Chemistry and the Role of Trapped Molecular O 2 in Li-Rich Disordered Rocksalt Oxyfluoride Cathodes by Sharpe, Ryan, House, Robert A, Clarke, Matt J, Förstermann, Dominic, Marie, John-Joseph, Cibin, Giannantonio, Zhou, Ke-Jin, Playford, Helen Y, Bruce, Peter G, Islam, M Saiful

“…In the search for high energy density cathodes for next-generation lithium-ion batteries, the disordered rocksalt oxyfluorides are receiving significant…”
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Lightning fast conduction by House, Robert A., Bruce, Peter G.

“…In the intensive search for higher performance Li-ion cathode materials the spotlight is firmly fixed on Li-rich compounds. Now, a strategy utilizing a…”
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