Search Results - "Houck, Hannes A."
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Force–reversible chemical reaction at ambient temperature for designing toughened dynamic covalent polymer networks
Published in Nature communications (09-06-2022)“…Force-reversible C-N bonds, resulting from the click chemistry reaction between triazolinedione (TAD) and indole derivatives, offer exciting opportunities for…”
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2
Controlling thermal reactivity with different colors of light
Published in Nature communications (30-11-2017)“…The ability to switch between thermally and photochemically activated reaction channels with an external stimulus constitutes a key frontier within the realm…”
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Internal catalysis on the opposite side of the fence in non-isocyanate polyurethane covalent adaptable networks
Published in European polymer journal (05-04-2022)“…[Display omitted] •Design of non-isocyanate polyurethane dynamic networks in the absence of catalytic additives.•The location of the internal catalyst affects…”
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4
Design of a thermally controlled sequence of triazolinedione-based click and transclick reactions
Published in Chemical science (Cambridge) (01-04-2017)“…The reaction of triazolinediones (TADs) and indoles is of particular interest for polymer chemistry applications, as it is a very fast and irreversible…”
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5
From Sequence‐Defined Macromolecules to Macromolecular Pin Codes
Published in Advanced science (01-04-2020)“…Dynamic sequence‐defined oligomers carrying a chemically written pin code are obtained through a strategy combining multicomponent reactions with the…”
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Polymers without Petrochemicals: Sustainable Routes to Conventional Monomers
Published in Chemical reviews (08-03-2023)“…Access to a wide range of plastic materials has been rationalized by the increased demand from growing populations and the development of high-throughput…”
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Light-Stabilized Dynamic Materials
Published in Journal of the American Chemical Society (07-08-2019)“…The light-responsive adaptation of polymer materials typically requires different wavelengths or additional heat to induce reversible covalent bond formation…”
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Triazolinediones as Highly Enabling Synthetic Tools
Published in Chemical reviews (23-03-2016)“…Triazolinediones (TADs) are unique reagents in organic synthesis that have also found wide applications in different research disciplines, in spite of their…”
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Introducing Dynamic Bonds in Light‐based 3D Printing
Published in Advanced functional materials (01-05-2024)“…Light‐based 3D printing has received significant attention due to several advantages including high printing speed and resolution. Along with the development…”
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10
Aggregation-Induced Emission Poly(meth)acrylates for Photopatterning via Wavelength-Dependent Visible-Light-Regulated Controlled Radical Polymerization in Batch and Flow Conditions
Published in Macromolecules (22-11-2022)“…A robust wavelength-dependent visible-light-regulated reversible-deactivation radical polymerization protocol is first reported for the batch preparation of…”
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Thermoreversible [2 + 2] Photodimers of Monothiomaleimides and Intrinsically Recyclable Covalent Networks Thereof
Published in Journal of the American Chemical Society (17-07-2024)“…The development of intrinsically recyclable cross-linked materials remains challenged by the inherently unfavorable chemical equilibrium that dictates the…”
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Reversible Transformations of Polymer Topologies through Visible Light and Darkness
Published in Journal of the American Chemical Society (20-04-2022)“…A fundamentally important characteristic of a macromolecule is its shape. Herein, visible light and darkness are used as the only stimuli to reversibly alter…”
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Photocrosslinking of Polyacrylamides Using [2 + 2] Photodimerisation of Monothiomaleimides
Published in Macromolecules (11-10-2022)“…The [2 + 2] photocycloaddition of monothiomaleimides (MTMs) has been exploited for the photocrosslinking of polyacrylamides. Polymer scaffolds composed of…”
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14
Visible Light Conjugation with Triazolinediones as a Route to Degradable Poly(ethylene glycol)–Lipids for mRNA Lipid Nanoparticle Formulation
Published in Angewandte Chemie International Edition (05-06-2023)“…Polyethylene glycol (PEG) is considered as the gold standard for colloidal stabilization of nanomedicines, yet PEG is non‐degradable and lacks functionality on…”
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Two Functions from a Single Photoresist: Tuning Microstructure Degradability from Light‐Stabilized Dynamic Materials
Published in Advanced materials (Weinheim) (01-06-2023)“…A photoresist—based on a light‐stabilized dynamic material driven by an out‐of‐equilibrium photo‐Diels–Alder reaction of triazolinediones with…”
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3D Printed Microstructures Erasable by Darkness
Published in Advanced functional materials (01-09-2023)“…To advance the applications of direct laser writing (DLW), adaptability of the printed structure is critical, prompting a shift toward printing structures that…”
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Shining Light on Poly(ethylene glycol): From Polymer Modification to 3D Laser Printing of Water Erasable Microstructures
Published in Advanced materials (Weinheim) (01-08-2020)“…The implementation of stimuli‐responsive bonds into 3D network assemblies is a key concept to design adaptive materials that can reshape and degrade. Here, a…”
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Light-fueled dynamic covalent crosslinking of single polymer chains in non-equilibrium states
Published in Chemical science (Cambridge) (17-11-2020)“…While polymer synthesis proceeds predominantly towards the thermodynamic minimum, living systems operate on the reverse principle - consuming fuel to maintain…”
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The Power of Action Plots: Unveiling Reaction Selectivity of Light‐Stabilized Dynamic Covalent Chemistry
Published in Angewandte Chemie International Edition (02-10-2023)“…Exploiting the optimum wavelength of reactivity for efficient photochemical reactions has been well‐established based on the development of photochemical…”
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Tunable Blocking Agents for Temperature-Controlled Triazolinedione-Based Cross-Linking Reactions
Published in Macromolecules (24-04-2018)“…The remarkable reactivity of triazolinediones (TADs) toward olefin-type substrates marks them as highly attractive click reagents, in particular for polymer…”
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