Search Results - "Hope, Eric G."

Bis-Cyclometalation of Fluorinated N-Aryl NHCs by Harding, Duncan A. J, Hope, Eric G, Singh, Kuldip, Solan, Gregory A

“…The new imidazolium salts N,N′-bisfluoroarylimidazolium chloride (fluoroaryl = 4-fluorophenyl (1), 2,4-difluorophenyl (2), 2,4,6-trifluorophenyl (3)) have been…”
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Intramolecular Fluorocyclizations of Unsaturated Carboxylic Acids with a Stable Hypervalent Fluoroiodane Reagent by Geary, Gemma C., Hope, Eric G., Stuart, Alison M.

“…A new class of fluorinated lactones was prepared by the intramolecular fluorocyclizations of unsaturated carboxylic acids by using the stable fluoroiodane…”
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Effect of Electrolyte Concentration on the Viscosity and Voltammetry of Supercritical Solutions by Abbott, Andrew P, Hope, Eric G, Palmer, Donna J

“…The viscosity of a supercritical electrolyte solution is measured for the first time using a modified quartz crystal microbalance, and it is shown that ionic…”
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Complexes of molybdenum(VI) oxide tetrafluoride and molybdenum(VI) dioxide difluoride with neutral N- and O-donor ligands by Levason, William, Monzittu, Francesco M., Reid, Gillian, Zhang, Wenjian, Hope, Eric G.

“…[Display omitted] •First examples of MoOF4 complexes with neutral ligands.•X-ray structure of [MoOF4(Ph3PO)].•Comparisons of [MoOF4(L)] and [MoO2F2(L)2]…”
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Synthesis of fluoroalkyl-derivatised BINAP ligands by Birdsall, David J, Hope, Eric G, Stuart, Alison M, Chen, Weiping, Hu, Yulai, Xiao, Jianliang

“…Fluoroalkyl-derivatised R-BINAP ligands have been prepared, characterised and applied in the ruthenium-catalysed asymmetric hydrogenation of dimethyl…”
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Active O,Npy,N-Titanium(IV) Fluoride Precatalysts for Ethylene Polymerization: Exploring “Fluoride Effects” on Polymer Properties and Catalytic Performance by Wright, Luka A, Hope, Eric G, Solan, Gregory A, Cross, Warren B, Singh, Kuldip

“…Three examples of discrete six-coordinate O,Npy,N-bearing titanium­(IV) trifluoride complexes, [{2-(C5H4N)-6-(CMe2O)­C5H3N}­TiF3] (1),…”
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A recyclable perfluoroalkylated PCP pincer palladium complex by Duncan, Daniel, Hope, Eric G, Singh, Kuldip, Stuart, Alison M

“…A new fluorous PCP pincer ligand has been coordinated to Ni(II), Pd(II) and Pt(II). The air stable palladium complex, which promotes Heck reactions between…”
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Insoluble Perfluoroalkylated Polymers: New Solid Supports for Supported Fluorous Phase Catalysis by Audic, Nicolas, Dyer, Philip W., Hope, Eric G., Stuart, Alison M., Suhard, Samuel

“…New perfluoroalkylated polystyrene resins have been prepared by the suspension polymerisation of 4‐(perfluoro‐n‐octyl)styrene. The evaluation of these highly…”
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Fluorous biphase catalysis by Hope, Eric G, Stuart, Alison M

“…The evolution and future prospects for the fluorous biphase approach to homogeneous catalysis are discussed…”
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Supported Fluorous Phase Catalysis on PTFE, Fluoroalkylated Micro- and Meso-porous Silica by Hope, Eric G., Sherrington, James, Stuart, Alison M.

“…New perfluoroalkylated micro‐ and mesoporous silica, along with powdered Teflon, have been evaluated as solid supports for supported fluorous phase catalysis…”
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Intramolecular Fluorocyclizations of Unsaturated Carboxylic Acids with a Stable Hypervalent Fluoroiodane Reagent by Geary, Gemma C., Hope, Eric G., Stuart, Alison M.

“…A new class of fluorinated lactones was prepared by the intramolecular fluorocyclizations of unsaturated carboxylic acids by using the stable fluoroiodane…”
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Effect of Solutes on the Viscosity of Supercritical Solutions by Abbott, Andrew P, Hope, Eric G, Palmer, Donna J

“…This study shows that solutes can impart significant structure to supercritical solutions, resulting in unexpectedly high solution viscosity at pressures close…”
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Probing Solute Clustering in Supercritical Solutions Using Solvatochromic Parameters by Abbott, Andrew P, Hope, Eric G, Palmer, Donna J

“…Kamlet and Taft polarity parameters are presented for three supercritical solutions containing solutes of different polarities at two concentrations. It is…”
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Synthesis, properties, and multinuclear NMR (125Te{1H}, 13C{1H}, 1H) studies in di- and polytelluroether ligands by Hope, Eric G, Kemmitt, Tim, Levason, William

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Hydroformylation in perfluorinated solvents; improved selectivity, catalyst retention and product separation by Foster, Douglas F, Gudmunsen, David, Adams, Dave J, Stuart, Alison M, Hope, Eric G, Cole-Hamilton, David J, Schwarz, Gary P, Pogorzelec, Peter

“…The hydroformylation of linear terminal alkenes using rhodium based catalysts under fluorous biphasic conditions in the presence and absence of toluene is…”
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Coordination chemistry of the noble gases and noble gas fluorides by Hope, Eric G.

“…► The first combined survey of metal-noble gas and metal-noble gas fluoride complexes. ► Recent developments in organometallic noble gas complexes in an…”
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Ruthenium-catalysed asymmetric hydrogenation with fluoroalkylated BINAP ligands in supercritical CO2 by YULAI HU, BIRDSALL, David J, STUART, Alison M, HOPE, Eric G, JIANLIANG XIAO

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Hydroformylation in fluorous solvents by Adams, Dave J, Cole-Hamilton, David J, Hope, Eric G, Pogorzelec, Peter J, Stuart, Alison M

“…The hydroformylation of long chain alkenes under fluorous biphase conditions and in neat perfluorocarbon solvents is reviewed, with emphasis on the steric and…”
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Polymer modification using difluoromethane (HFC 32) and carbon dioxide by Abbott, Andrew P., Brooks, Nick, Eltringham, Wayne, Hillman, A. Robert, Hope, Eric G.

“…The infusion of difluoromethane (HFC 32) and CO2 into polystyrene and polyethylene has been characterized using a quartz crystal microbalance technique over a…”
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Towards the synthesis of perfluoroalkylated derivatives of Xantphos by Adams, Dave J., Cole-Hamilton, David J., Harding, Duncan A.J., Hope, Eric G., Pogorzelec, Peter, Stuart, Alison M.

“…An analogue of Xantphos incorporating four perfluoroalkyl groups has been prepared and successfully used as a ligand in the rhodium-catalysed hydroformylation…”
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