Search Results - "Hooper, Reagan X."
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Cobalt–Carbon Bonding in a Salen-Supported Cobalt(IV) Alkyl Complex Postulated in Oxidative MHAT Catalysis
Published in Journal of the American Chemical Society (15-06-2022)“…The catalytic hydrofunctionalization of alkenes through radical-polar crossover metal hydrogen atom transfer (MHAT) offers a mild pathway for the introduction…”
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2
Desulfurization and N2 Binding at an Iron Complex Derived from the C–S Activation of Benzothiophene
Published in Organometallics (14-08-2023)“…Metal insertion into the C–S bonds of thiophenes is a facile route to interesting polydentate ligand scaffolds with C and S donors. Here, we describe…”
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3
Mechanism of Nitrogen-Carbon Bond Formation from Iron(IV) Disilylhydrazido Intermediates during N2 Reduction
Published in Journal of the American Chemical Society (01-03-2023)“…We recently reported a reaction sequence that activates C–H bonds in simple arenes as well as the N–N triple bond in N2, delivering the aryl group to N2 to…”
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4
Desulfurization and N 2 Binding at an Iron Complex Derived from the C-S Activation of Benzothiophene
Published in Organometallics (14-08-2023)“…Metal insertion into the C-S bonds of thiophenes is a facile route to interesting polydentate ligand scaffolds with C and S donors. Here, we describe…”
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5
Evaluating Diazene to N2 Interconversion at Iron‐Sulfur Complexes
Published in Chemistry : a European journal (25-04-2024)“…Biological N2 reduction occurs at sulfur‐rich multiiron sites, and an interesting potential pathway is concerted double reduction/ protonation of bridging N2…”
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6
Evaluating Diazene to N 2 Interconversion at Iron-Sulfur Complexes
Published in Chemistry : a European journal (25-04-2024)“…Biological N reduction occurs at sulfur-rich multiiron sites, and an interesting potential pathway is concerted double reduction/ protonation of bridging N…”
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7
Mechanism of Nitrogen-Carbon Bond Formation from Iron(IV) Disilylhydrazido Intermediates during N 2 Reduction
Published in Journal of the American Chemical Society (01-03-2023)“…We recently reported a reaction sequence that activates C-H bonds in simple arenes as well as the N-N triple bond in N , delivering the aryl group to N to form…”
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8
Iron(iv) alkyl complexes: electronic structure contributions to Fe–C bond homolysis and migration reactions that form N–C bonds from N2
Published in Chemical science (Cambridge) (24-01-2024)“…High-valent iron alkyl complexes are rare, as they are prone to Fe–C bond homolysis. Here, we describe an unusual way to access formally iron(iv) alkyl…”
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9
Mixed Valence {Ni2+Ni1+} Clusters as Models of Acetyl Coenzyme A Synthase Intermediates
Published in Journal of the American Chemical Society (31-07-2024)“…Acetyl coenzyme A synthase (ACS) catalyzes the formation and deconstruction of the key biological metabolite, acetyl coenzyme A (acetyl-CoA). The active site…”
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10
Iron(iv) alkyl complexes: electronic structure contributions to Fe-C bond homolysis and migration reactions that form N-C bonds from N 2
Published in Chemical science (Cambridge) (06-03-2024)“…High-valent iron alkyl complexes are rare, as they are prone to Fe-C bond homolysis. Here, we describe an unusual way to access formally iron(iv) alkyl…”
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11
Iron Complexes of a Proton-Responsive SCS Pincer Ligand with a Sensitive Electronic Structure
Published in Inorganic chemistry (24-01-2022)“…Sulfur/carbon/sulfur pincer ligands have an interesting combination of strong-field and weak-field donors, a coordination environment that is also present in…”
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12
Iron() alkyl complexes: electronic structure contributions to Fe-C bond homolysis and migration reactions that form N-C bonds from N
Published in Chemical science (Cambridge) (06-03-2024)“…High-valent iron alkyl complexes are rare, as they are prone to Fe-C bond homolysis. Here, we describe an unusual way to access formally iron( iv ) alkyl…”
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13
Iron Complexes of a Proton-Responsive SCS Pincer Ligand with a Sensitive Electronic Structure
Published in Inorganic chemistry (24-01-2022)“…Not provided…”
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