Search Results - "Holschumacher, Dirk"

Sulfur and SeleniumActivation by Frustrated NHC/B(C6F5)3 Lewis Pairs; Conformational Flexibility of Products by Holschumacher, Dirk, Daniliuc, Constantin G., Jones, Peter G., Tamm, Matthias

“…Frustrated Lewis pairs consisting of N-heterocyclic carbenes (NHC) and the borane B(C react with elemental sulfur or selenium to give products of the type…”
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Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair by Holschumacher, Dirk, Bannenberg, Thomas, Hrib, Cristian G, Jones, Peter G, Tamm, Matthias

“…Relief from frustration: The sterically demanding carbene 1,3‐di‐tert‐butylimidazolin‐2‐ylidene and B(C6F5)3, a “frustrated” Lewis pair, is a viable system for…”
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Dihydrogen Activation by Frustrated Carbene-Borane Lewis Pairs: An Experimental and Theoretical Study of Carbene Variation by Kronig, Sabrina, Theuergarten, Eileen, Holschumacher, Dirk, Bannenberg, Thomas, Daniliuc, Constantin G, Jones, Peter G, Tamm, Matthias

“…A variety of Lewis acid–base pairs consisting of tris(pentafluorophenyl)borane, B(C6F5)3, in combination with sterically demanding five- and six-membered…”
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Cover Picture: Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair / Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3 (Angew. Chem. Int. Ed. 39/2008) by Holschumacher, Dirk, Bannenberg, Thomas, Hrib, Cristian G., Jones, Peter G., Tamm, Matthias, Chase, Preston A., Stephan, Douglas W.

“…Forcing a square peg into a round hole: tBu2ImC: and B(C6F5)3 form a frustrated Lewis pair (FLP), allowing the synergistic activation of H2. On page 7428 ff.,…”
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Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair by Holschumacher, Dirk, Bannenberg, Thomas, Hrib, Cristian G., Jones, Peter G., Tamm, Matthias

“…Ein Weg aus der Frustration: Das „frustrierte“ Lewis‐Paar aus dem sterisch anspruchsvollen Carben 1,3‐Di‐tert‐butylimidazolin‐2‐yliden und B(C6F5)3 eignet sich…”
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Titelbild: Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair / Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3 (Angew. Chem. 39/2008) by Holschumacher, Dirk, Bannenberg, Thomas, Hrib, Cristian G., Jones, Peter G., Tamm, Matthias, Chase, Preston A., Stephan, Douglas W.

“…Das Eckige ins Runde zwingen: tBu2ImC: und B(C6F5)3 bilden ein frustriertes Lewis‐Paar (FLP), das die synergistische Aktivierung von H2 ermöglicht. Auf S. 7538…”
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Heterolytic Dihydrogen Activation by a Frustrated Carbene–Borane Lewis Pair by Holschumacher, Dirk, Bannenberg, Thomas, Hrib, Cristian G., Jones, Peter G., Tamm, Matthias

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