Search Results - "Holle, Sigrid"

Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs by Alcarazo, Manuel, Gomez, Catherine, Holle, Sigrid, Goddard, Richard

“…Twice frustrated: The unusual electronic distribution around the central carbon(0) atom in carbodiphosphoranes makes this center so basic that, even after a…”
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Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes by Inés, Blanca, Palomas, David, Holle, Sigrid, Steinberg, Sebastian, Nicasio, Juan A., Alcarazo, Manuel

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Synthesis, Structure, and Reactivity of Carbene-Stabilized Phosphorus(III)-Centered Trications [L3P]3 by Petuškova, Jekaterina, Patil, Mahendra, Holle, Sigrid, Lehmann, Christian W, Thiel, Walter, Alcarazo, Manuel

“…Carbene-stabilized [L3P]+3 cations have been synthesized for the first time by a reaction between 1-chloro-2,3-bis(dialkylamino)cyclopropenium salts and…”
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Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair by Inés, Blanca, Holle, Sigrid, Goddard, Richard, Alcarazo, Manuel

“…Boranes were getting borin': Owing to the Lewis acidic character of the central carbon atom, a bisfluorenyl‐substituted allene 1 could be used instead of…”
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Efficient Asymmetric Hydrogenation of Pyridines by Glorius, Frank, Spielkamp, Nick, Holle, Sigrid, Goddard, Richard, Lehmann, Christian W.

“…Up to four stereocenters can be created efficiently in a single step by the asymmetric hydrogenation of oxazolidinone‐substituted pyridines (see scheme)…”
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On the Reactivity of Tetrakis(trifluoromethyl)cyclopentadienone towards Carbon-Based Lewis Bases by Holle, Sigrid, Escudero, Daniel, Inés, Blanca, Rust, Jörg, Thiel, Walter, Alcarazo, Manuel

“…The reactivitiy of tetrakis(trifluoromethyl)cyclopentadienone towards different C‐based Lewis bases, such as N‐heterocyclic carbenes (NHC), ylides and…”
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Frontispiece: On the Reactivity of Tetrakis(trifluoromethyl)cyclopentadienone towards Carbon-Based Lewis Bases by Holle, Sigrid, Escudero, Daniel, Inés, Blanca, Rust, Jörg, Thiel, Walter, Alcarazo, Manuel

“…Organic Lewis Acids Tetrakis(trifluoromethyl)cyclopentenedione has been described to form Lewis adducts with phosphines through the oxygen atom. This…”
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Metal‐Free Hydrogenation of Electron‐Poor Allenes and Alkenes by Inés, Blanca, Palomas, David, Holle, Sigrid, Steinberg, Sebastian, Nicasio, Juan A., Alcarazo, Manuel

“…The poorer, the better: A metal‐free catalytic procedure for the reduction of electron‐poor allenes and alkenes has been developed. The method employs a…”
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Corrigendum: Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs by Alcarazo, Manuel, Gomez, Catherine, Holle, Sigrid, Goddard, Richard

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Metallfreie Hydrierung von elektronenarmen Allenen und Alkenen by Inés, Blanca, Palomas, David, Holle, Sigrid, Steinberg, Sebastian, Nicasio, Juan A., Alcarazo, Manuel

“…Je ärmer, desto besser: Ein metallfreies katalytisches Verfahren für die Reduktion von elektronenarmen Allenen und Alkenen mit frustrierten Lewis‐Paaren als…”
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Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair by Inés, Blanca, Holle, Sigrid, Goddard, Richard, Alcarazo, Manuel

“…Borane sind nicht alles: Das Bisfluorenylallen 1 mit einem Lewis‐sauren zentralen Kohlenstoffatom kann B(C6F5)3 bei der Bildung frustrierter Lewis‐Paare…”
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Berichtigung: Exploring the Reactivity of Carbon(0)/Borane‐Based Frustrated Lewis Pairs by Alcarazo, Manuel, Gomez, Catherine, Holle, Sigrid, Goddard, Richard

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Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs by Alcarazo, Manuel, Gomez, Catherine, Holle, Sigrid, Goddard, Richard

“…Doppelt frustriert: Die ungewöhnliche elektronische Verteilung um das zentrale Kohlenstoff(0)‐Atom in Carbodiphosphoranen macht dieses Zentrum so basisch, dass…”
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Cover Picture: Efficient Asymmetric Hydrogenation of Pyridines (Angew. Chem. Int. Ed. 21/2004) by Glorius, Frank, Spielkamp, Nick, Holle, Sigrid, Goddard, Richard, Lehmann, Christian W.

“…The stereoselective hydrogenation of oxazolidinone‐substituted pyridines shown in the cover picture gives piperidines containing up to four new stereocenters…”
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Metallfreie Hydrierung von elektronenarmen Allenen und Alkenen by Inés, Blanca, Palomas, David, Holle, Sigrid, Steinberg, Sebastian, Nicasio, Juan A., Alcarazo, Manuel

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Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair by Inés, Blanca, Holle, Sigrid, Goddard, Richard, Alcarazo, Manuel

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Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair by Ines, Blanca, Holle, Sigrid, Goddard, Richard, Alcarazo, Manuel

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Exploring the Reactivity of Carbon(0)/Borane‐Based Frustrated Lewis Pairs by Alcarazo, Manuel, Gomez, Catherine, Holle, Sigrid, Goddard, Richard

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Berichtigung: Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs by Alcarazo, Manuel, Gomez, Catherine, Holle, Sigrid, Goddard, Richard

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Amino-substituted cyclopentadienyl cobalt complexes by Holle, Sigrid, Jolly, Peter W

“…Reduction of the (η 1,η 5-R 2NC 2H 4C 5Me 4)CoCl complexes (R=Me, R 2=cyclo-C 4H 8), prepared by treating CoCl 2 with 2-dimethylaminoethyl- or…”
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