Search Results - "Hoffmann, Erik H."
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Direct sulfuric acid formation from the gas-phase oxidation of reduced-sulfur compounds
Published in Nature communications (10-08-2023)“…Sulfuric acid represents a fundamental precursor for new nanometre-sized atmospheric aerosol particles. These particles, after subsequent growth, may influence…”
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Particle-Phase Photoreactions of HULIS and TMIs Establish a Strong Source of H2O2 and Particulate Sulfate in the Winter North China Plain
Published in Environmental science & technology (15-06-2021)“…During haze periods in the North China Plain, extremely high NO concentrations have been observed, commonly exceeding 1 ppbv, preventing the classical…”
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An improved multiphase chemistry mechanism for methylamines: significant dimethylamine cloud production
Published in NPJ climate and atmospheric science (04-06-2024)“…Monomethylamine (MMA), dimethylamine (DMA), and trimethylamine (TMA) are important compounds for atmospheric key processes, e.g., new particle formation (NPF)…”
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Gas‐Phase Formation of Sulfurous Acid (H2SO3) in the Atmosphere
Published in Angewandte Chemie International Edition (22-07-2024)“…Sulfurous acid (H2SO3) is known to be thermodynamically instable decomposing into SO2 and H2O. All attempts to detect this elusive acid in solution failed up…”
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Kinetics and Mechanisms of Aqueous-Phase Reactions of Triplet-State Imidazole-2-carboxaldehyde and 3,4-Dimethoxybenzaldehyde with α,β-Unsaturated Carbonyl Compounds
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (24-11-2022)“…Reactions in the atmospheric aqueous phase are an important source of secondary organic aerosols (SOA). Within the present study, the reactions of…”
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Enhanced Chlorine and Bromine Atom Activation by Hydrolysis of Halogen Nitrates from Marine Aerosols at Polluted Coastal Areas
Published in Environmental science & technology (15-01-2019)“…Detailed multiphase chemistry box model studies are carried out, investigating halogen radical activation at polluted coastal areas. Simulations are performed…”
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Daytime Atmospheric Halogen Cycling through Aqueous-Phase Oxygen Atom Chemistry
Published in Journal of the American Chemical Society (26-07-2023)“…Halogen atoms are important atmospheric oxidants that have unidentified daytime sources from photochemical halide oxidation in sea salt aerosols. Here, we show…”
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Temperature-Dependent Oxidation of Hydroxylated Aldehydes by •OH, SO4 •–, and NO3 • Radicals in the Atmospheric Aqueous Phase
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (10-08-2023)“…T-dependent aqueous-phase rate constants were determined for the oxidation of the hydroxy aldehydes, glyceraldehyde, glycolaldehyde, and lactaldehyde, by the…”
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Temperature-Dependent Oxidation of Hydroxylated Aldehydes by • OH, SO 4 •- , and NO 3 • Radicals in the Atmospheric Aqueous Phase
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (10-08-2023)“…-dependent aqueous-phase rate constants were determined for the oxidation of the hydroxy aldehydes, glyceraldehyde, glycolaldehyde, and lactaldehyde, by the…”
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Hydrotrioxide (ROOOH) formation in the atmosphere
Published in Science (American Association for the Advancement of Science) (27-05-2022)“…Organic hydrotrioxides (ROOOH) are known to be strong oxidants used in organic synthesis. Previously, it has been speculated that they are formed in the…”
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Opinion: The germicidal effect of ambient air (open-air factor) revisited
Published in Atmospheric chemistry and physics (02-09-2021)“…The term open-air factor (OAF) was coined following microbiological research in the 1960s and 1970s which established that rural air had powerful germicidal…”
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Near-Explicit Multiphase Modeling of Halogen Chemistry in a Mixed Urban and Maritime Coastal Area
Published in ACS earth and space chemistry (21-11-2019)“…In the present study, detailed air-parcel model simulations have been carried out that focus on multiphase halogen chemistry and its impact on the air quality…”
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CAPRAM reduction towards an operational multiphase halogen and dimethyl sulfide chemistry treatment in the chemistry transport model COSMO-MUSCAT(5.04e)
Published in Geoscientific Model Development (04-06-2020)“…A condensed multiphase halogen and dimethyl sulfide (DMS) chemistry mechanism for application in chemistry transport models is developed by reducing the CAPRAM…”
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Rapid growth of Aitken-mode particles during Arctic summer by fog chemical processing and its implication
Published in PNAS nexus (01-05-2023)“…In the Arctic, new particle formation (NPF) and subsequent growth processes are the keys to produce Aitken-mode particles, which under certain conditions can…”
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Urban Grime Photochemistry and Its Interaction with Air Pollutants NO, NO2, and O3: A Source for HONO and NO2 Impacting OH in Urban Areas
Published in ACS earth and space chemistry (16-11-2023)“…The interaction of air pollutants with urban grime surface films (e.g., windows, building walls, etc.) are potentially impacting urban air quality due to…”
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Gasphasenbildung von Schwefliger Säure (H2SO3) in der Atmosphäre
Published in Angewandte Chemie (22-07-2024)“…Schweflige Säure (H2SO3) ist dafür bekannt, dass sie thermodynamisch instabil ist und in SO2 und H2O zerfällt. Alle Versuche, diese schwer zugängliche Säure in…”
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A CAPRAM Modeling Study on the Role of Heterogeneous Reactions on Dust in Tropospheric Chemistry
Published in ACS earth and space chemistry (17-10-2024)“…A heterogeneous dust chemistry module was developed and coupled toward the near-explicit mechanism MCM. Model simulations were performed for different dust…”
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Insights Into NO x and HONO Chemistry in the Tropical Marine Boundary Layer at Cape Verde During the MarParCloud Campaign
Published in Journal of geophysical research. Atmospheres (27-08-2023)“…Abstract Chemical processing of reactive nitrogen species, especially of NO x (= NO + NO 2 ) and nitrous acid (HONO), determines the photochemical ozone…”
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