Search Results - "Hobbs, Christopher E."
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Recent Advances in Bio-Based Flame Retardant Additives for Synthetic Polymeric Materials
Published in Polymers (31-01-2019)“…It would be difficult to imagine how modern life across the globe would operate in the absence of synthetic polymers. Although these materials (mostly in the…”
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Polyisobutylene-Supported Phosphines as Recyclable and Regenerable Catalysts and Reagents
Published in Journal of organic chemistry (19-08-2011)“…Phosphines are important as catalysts or reagents in synthesis but must be separated from products after a reaction. This report shows that polyisobutylene…”
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Ring Opening Metathesis Polymerization of a New Monomer Derived from a Nitroso Diels–Alder Reaction
Published in Macromolecular chemistry and physics (01-07-2021)“…A nitroso Diels–Alder (NDA) reaction between cyclopentadiene and an in situ generated nitroso compound leads to a new heterocyclic monomer for ring opening…”
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Post‐Polymerization Thiol Substitutions Facilitated by Mechanochemistry
Published in Macromolecular chemistry and physics (01-11-2019)“…The use of mechanical force to facilitate post‐polymerization, solvent‐free thiol substitution reactions is described. These reactions are amenable to…”
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Combining ATRP and ROMP with Thio‐Bromo, Copper‐Catalyzed, and Strain‐Promoted Click Reactions for Brush Copolymer Synthesis Starting from a Single Initiator/Monomer/Click Partner
Published in Macromolecular chemistry and physics (01-04-2019)“…The preparation of functionalized graft copolymers utilizing a combination of ATRP, ROMP, thio‐bromo, and Huisgen‐type click chemistries is described. The…”
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Phase-selectively soluble, polymer-supported salen catalyst prepared using atom transfer radical polymerization (ATRP)
Published in Polymer (Guilford) (17-01-2018)“…This communication describes the use of atom transfer radical polymerization (ATRP) to prepare a new phase-selectively soluble, polymer-supported CrIII salen…”
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Corrigendum to Phase-selectively soluble, polymer-supported salen catalyst prepared using atom transfer radical polymerization (ATRP)
Published in Polymer (Guilford) (28-03-2018)Get full text
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Toward the (nearly) complete elimination of solvent waste in Ring Opening Metathesis Polymerization (ROMP) reactions
Published in Polymer (Guilford) (02-12-2015)“…This short communication describes current efforts geared toward the development of solvent-free, Ring Opening Metathesis Polymerization (ROMP) processes. It…”
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Post-Polymerization Modification of Ring Opening Metathesis Polymerization (ROMP)-Derived Materials Using Wittig Reactions
Published in Polymers (29-05-2020)“…This communication describes our recent efforts to utilize Wittig olefination reactions for the post-polymerization modification of polynorbornene derivatives…”
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Postpolymerization modification of a sulfonyl fluoride‐decorated polynorbornene using the sulfur‐fluoride exchange click reaction
Published in Journal of polymer science (2020) (01-01-2023)“…This contribution describes the ring opening metathesis polymerization of a sulfonyl fluoride decorated polynorbornene and its postsynthetic modification using…”
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Polyethylene as a Cosolvent and Catalyst Support in Ring-Opening Metathesis Polymerization
Published in Macromolecules (25-08-2015)“…Polyethylene oligomers (PEOlig) can be used as cosolvents and sometimes soluble catalyst supports in ring-opening metathesis polymerization (ROMP) reactions…”
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Norbornene derivatives from a metal‐free, strain‐promoted cycloaddition reaction: New building blocks for ring‐opening metathesis polymerization reactions
Published in Journal of polymer science. Part A, Polymer chemistry (15-10-2015)“…The preparation of new ring opening metathesis polymerization (ROMP) monomers using a 1,3‐dipolar cycloaddition between aryl azides and norbornadiene is…”
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Ring opening metathesis polymerization (ROMP) and thio‐bromo “click” chemistry approach toward the preparation of flame‐retardant polymers
Published in Journal of polymer science. Part A, Polymer chemistry (15-03-2018)“…ABSTRACT This contribution describes our recent efforts geared toward the use of a general, thio‐bromo “click” reaction as a post‐polymerization method for the…”
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Thio‐bromo “Click,” post‐polymerization strategy for functionalizing ring opening metathesis polymerization (ROMP)‐derived materials
Published in Journal of polymer science. Part A, Polymer chemistry (01-01-2016)“…The use of a thio‐bromo click strategy as an efficient postpolymerization tool is described. Norbornene derivatives bearing an α‐bromo ester could be…”
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Use of an isotactic-propylene/hexene copolymer as a new, versatile, soluble support
Published in Journal of polymer science. Part A, Polymer chemistry (01-03-2014)“…ABSTRACT The use of isotactic‐poly(propylene‐co‐hexene) (iPPH) as new polymeric scaffold for synthesis as well as a phase‐selective, soluble polymer support…”
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Ring Opening Metathesis Polymerization of a New Monomer Derived from a Nitroso Diels–Alder Reaction
Published in Macromolecular chemistry and physics (01-07-2021)“…Front Cover: In article number 2100098, Christopher E. Hobbs and co‐workers describe the use of a Nitroso–Diels–Alder reaction as an effective route toward the…”
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Protective encapsulation of acid-sensitive catalysts using polyethylene ligands
Published in Journal of polymer science. Part A, Polymer chemistry (01-12-2012)“…The stability of polyethylene oligomer (PEOlig)‐entrapped salen‐metal complexes toward acidolysis is described. These complexes dissolve in hot toluene and…”
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Terminal functionalization of atactic polypropylene: a new soluble polymer support
Published in Tetrahedron letters (20-02-2013)“…The preparation of terminally functionalized atactic polypropylenes is described. Using standard organic transformations, an olefin terminated polypropylene…”
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