Search Results - "Höger, Sigurd"
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Shape-Persistent Macrocycles: From Molecules to Materials
Published in Chemistry : a European journal (19-03-2004)“…Shape‐persistent macrocycles with an interior in the nanometer regime allow the attachment of (functional) side groups at defined positions at the ring. These…”
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From π‑Conjugated Rods to Shape-Persistent Rings, Wheels, and Ladders: The Question of Rigidity
Published in Accounts of chemical research (03-09-2024)“…Conspectus Rigid-rod oligomers and polymers are mostly based on (hetero)aromatic rings connected with each other, either directly or via ethynylene or…”
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Switching between H- and J-type electronic coupling in single conjugated polymer aggregates
Published in Nature communications (21-11-2017)“…The aggregation of conjugated polymers and electronic coupling of chromophores play a central role in the fundamental understanding of light and charge…”
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Vibrations Responsible for Luminescence from HJ-Aggregates of Conjugated Polymers Identified by Cryogenic Spectroscopy of Single Nanoparticles
Published in ACS nano (26-04-2022)“…A single polymer chain can be thought of as a covalently bound J-aggregate, where the microscopic transition-dipole moments line up to emit in phase. Packing…”
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Time-Resolved Electron Paramagnetic Resonance and Theoretical Investigations of Metal-Free Room-Temperature Triplet Emitters
Published in Journal of the American Chemical Society (20-09-2017)“…Utilization of triplets is important for preparing organic light-emitting diodes with high efficiency. Very recently, both electrophosphorescence and…”
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6
Metal-Free OLED Triplet Emitters by Side-Stepping Kasha's Rule
Published in Angewandte Chemie International Edition (09-12-2013)“…Keeping it light: Most organic fluorophores do not show useful emission from the triplet excited state. A new class of materials is presented for organic…”
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Picosecond time-resolved photon antibunching measures nanoscale exciton motion and the true number of chromophores
Published in Nature communications (26-02-2021)“…The particle-like nature of light becomes evident in the photon statistics of fluorescence from single quantum systems as photon antibunching. In…”
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8
Shape-persistent rings and wheels
Published in Pure and applied chemistry (08-03-2010)“…Shape-persistent macrocycles based on the arylene-ethynylene backbone are synthetically challenging targets that can be obtained in good to high yields either…”
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Homo-FRET in π‑Conjugated Polygons: Intermediate-Strength Dipole–Dipole Coupling Makes Energy Transfer Reversible
Published in Nano letters (14-08-2019)“…The concept of homo-FRET is often used to describe energy transfer between like chromophores of molecular aggregates such as in π-conjugated polymers…”
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Effect of Conjugation Pathway in Metal-Free Room-Temperature Dual Singlet–Triplet Emitters for Organic Light-Emitting Diodes
Published in The journal of physical chemistry letters (17-11-2016)“…Metal-free dual singlet–triplet organic light-emitting diode (OLED) emitters can provide direct insight into spin statistics, spin correlations and spin…”
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A Liquid-Crystalline Phenylene-Based Shape-Persistent Molecular Spoked Wheel
Published in Journal of the American Chemical Society (29-03-2017)“…Molecular spoked wheels with an all-phenylene backbone and different alkoxy side chain substitution patterns were synthesized using a cobalt-catalyzed [2 + 2 +…”
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A Giant Molecular Spoked Wheel
Published in Journal of the American Chemical Society (03-12-2014)“…The modular synthesis of a defined, rigid molecular spoked wheel structure with the sum formula C1878H2682 and a diameter of about 12 nm is described. The…”
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Flexible Phenanthracene Nanotubes for Explosive Detection
Published in Journal of the American Chemical Society (07-02-2024)“…Phenanthracene nanotubes with arylene-ethynylene-butadiynylene rims and phenanthracene walls are synthesized in a modular bottom-up approach. One of the rims…”
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14
Exciton Localization in Extended π‑Electron Systems: Comparison of Linear and Cyclic Structures
Published in The journal of physical chemistry. B (30-07-2015)“…We employ five π-conjugated model materials of different molecular shapeoligomers and cyclic structuresto investigate the extent of exciton self-trapping and…”
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15
Excitation Energy Transfer between bodipy Dyes in a Symmetric Molecular Excitonic Seesaw
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (30-09-2021)“…We examine the redistribution of energy between electronic and vibrational degrees of freedom that takes place between a π-conjugated oligomer, a…”
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Mesoscopic quantum emitters from deterministic aggregates of conjugated polymers
Published in Proceedings of the National Academy of Sciences - PNAS (13-10-2015)“…An appealing definition of the term “molecule” arises from consideration of the nature of fluorescence, with discrete molecular entities emitting a stream of…”
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Synthesis and Arm Dissociation in Molecular Stars with a Spoked Wheel Core and Bottlebrush Arms
Published in Journal of the American Chemical Society (10-09-2014)“…Unique star-like polymeric architectures composed of bottlebrush arms and a molecular spoked wheel (MSW) core were prepared by atom transfer radical…”
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H‑Aggregation Effects between π‑Conjugated Chromophores in Cofacial Dimers and Trimers: Comparison of Theory and Single-Molecule Experiment
Published in The journal of physical chemistry. B (21-06-2018)“…Excited-state interchromophoric couplings in π-conjugated polymers present a daunting challenge to study as their spectroscopic signatures are difficult to…”
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