Search Results - "Hiskey, Michael A"
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Synthesis of an Energetic Nitrate Ester
Published in Angewandte Chemie (International ed.) (13-10-2008)“…Going out with a bang! A high‐energy‐density nitrate ester 1 with unique properties was synthesized in good yield in a three‐step process. Destructive stimuli…”
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2
Green Primaries: Environmentally Friendly Energetic Complexes
Published in Proceedings of the National Academy of Sciences - PNAS (04-04-2006)“…Primary explosives are used in small quantities to generate a detonation wave when subjected to a flame, heat, impact, electric spark, or friction. Detonation…”
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3
2,4,5-Trinitroimidazole-Based Energetic Salts
Published in Chemistry : a European journal (01-01-2007)“…2,4,5‐Trinitroimidazolate (TNI) salts with “high‐nitrogen” cations tend to be highly hydrogen bonded and have heats of formation ranging up to 616 kJ mol−1…”
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Tetrazine Explosives
Published in Propellants, explosives, pyrotechnics (01-08-2004)“…The synthesis and properties of various 1,2,4,5‐tetrazine explosives and energetic materials are described. These are the nitrate and perchlorate salts of…”
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Preparation of Nitrogen-Rich Nanolayered, Nanoclustered, and Nanodendritic Carbon Nitrides
Published in Angewandte Chemie International Edition (21-01-2005)“…Only C and N atoms are present in the high‐nitrogen compound 4,4′,6,6′‐tetra(azido)azo‐1,3,5‐triazine (TAAT), which is thus an ideal precursor for carbon…”
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Corrigendum: 2,4,5‐Trinitroimidazole‐Based Energetic Salts
Published in Chemistry : a European journal (26-04-2021)Get full text
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Synthesis, Characterization, and Energetic Properties of Diazido Heteroaromatic High-Nitrogen C−N Compound
Published in Journal of the American Chemical Society (14-09-2005)“…The synthesis, characterization, and energetic properties of diazido heteroaromatic high-nitrogen C−N compound, 3,6-diazido-1,2,4,5-tetrazine (DiAT), are…”
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Polyazido High-Nitrogen Compounds: Hydrazo- and Azo-1,3,5-triazine
Published in Angewandte Chemie International Edition (20-09-2004)“…20 nitrogens and six carbons: The compounds 1 and 2, demonstrate that hydrazo and azo linkages can be used to desensitize polyazido high‐nitrogen compounds and…”
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Azidoformamidinium and Guanidinium 5,5‘-Azotetrazolate Salts
Published in Chemistry of materials (12-07-2005)“…Energetic salts of the 5,5‘-azotetrazolate anion with different guandidinium cations were investigated, including bis(guanidinium) 5,5‘-azotetrazolate (GZT),…”
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10
Novel High-Nitrogen Materials Based on Nitroguanyl-Substituted Tetrazines
Published in Organic letters (19-08-2004)“…The synthesis and properties of several novel high-nitrogen materials based on nitroguanyl-substituted tetrazines are described. An optimized procedure…”
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3,6-Di(azido)-1,2,4,5-Tetrazine: A Precursor for the Preparation of Carbon Nanospheres and Nitrogen-Rich Carbon Nitrides
Published in Angewandte Chemie International Edition (25-10-2004)“…A high‐nitrogen compound, 3,6‐di(azido)‐1,2,4,5‐tetrazine, was used as precursor for the preparation of carbon nanospheres (see SEM picture) and nitrogen‐rich…”
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12
Perchlorate-Free Pyrotechnic Formulations Utilizing Energetic Chlorine Donors: 1-CDN, 11-CDN, 13-CDN
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (01-04-2013)“…Several novel materials were investigated as energetic chlorine donors, specifically for the preparation of perchlorate‐free pyrotechnic formulations with…”
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Tetraazapentalene Chemistry: Unexpected Intramolecular Electron Rearrangement Induced by Highly Reactive ψ-Dinitroso Substituents
Published in Angewandte Chemie International Edition (04-11-2005)“…Off with a bang: The thermally stable high‐energy 1 was prepared in a more efficient synthetic route. An unexpected ring scission of the tetraazapentalene…”
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14
New High-Nitrogen Materials Based on Nitroguanyl-Tetrazines: Explosive Properties, Thermal Decomposition and Combustion Studies
Published in Propellants, explosives, pyrotechnics (01-12-2005)“…This paper describes the explosive sensitivity and performance properties of two novel high‐nitrogen materials, 3,6‐bis‐nitroguanyl‐1,2,4,5‐tetrazine (1,…”
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Os(II)−Nitrosyl and Os(II)−Dinitrogen Complexes from Reactions between Os(VI)−Nitrido and Hydroxylamines and Methoxylamines
Published in Journal of the American Chemical Society (24-03-2004)“…Reactions between the Os(VI)−nitrido salts (e.g., trans-[OsVI(tpy)(Cl)2(N)]PF6 (tpy = 2,2‘:6‘,2”-terpyridine), cis-[OsVI(tpy)(Cl)2(N)]PF6, and…”
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Synthesis, Characterization, and Explosive Properties of the Nitrogen-Rich Borazine [H3N3B3(N3)3]
Published in Inorganic chemistry (09-08-1999)“…The azidoborazines [Me3N3B2(Me)2B(N3)] and [H3N3B3(N3)3] were prepared from the combination of Me3SiN3 and the chloroborazines [Me3N3B2(Me)2BCl] and…”
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15N Chemical Shift Tensors of β-HMX
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (04-07-2002)“…The 15N principal values and orientations of the chemical shift tensors of β-HMX are obtained by means of a FIREMAT experiment. A fitting routine using…”
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Synthesis and characterization of bis bipyridyl ruthenium(II) and osmium(II) complexes with 5,5′-bis-tetrazolate and N,N-bis(tetrazol-5-yl)-amine
Published in Inorganica Chimica Acta (01-09-2016)“…New mixed ligand bis-bipyridyl Ru(II) and Os(II) bound with the five membered di-anionic ligands 5,5′-bis-tetrazolate (bt) and N,N-bis(tetrazol-5-yl)-amine…”
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3,3′-Azobis(6-amino-1,2,4,5-tetrazine): A Novel High-Nitrogen Energetic Material
Published in Angewandte Chemie International Edition (15-05-2000)“…A very high heat of formation is displayed by the title compound 1, the first azo‐1,2,4,5‐tetrazine to be synthesized and likely the most dense C,H,N molecule…”
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Synthesis, Characterization, and Explosive Properties of the Nitrogen-Rich Borazine [H3N3B3(N3)3]
Published in Inorganic chemistry (18-10-1999)Get full text
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