Search Results - "Hirayama, Lacie C"
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Indium-Mediated Asymmetric Barbier-Type Allylations: Additions to Aldehydes and Ketones and Mechanistic Investigation of the Organoindium Reagents
Published in Journal of organic chemistry (05-02-2010)“…We report a simple, efficient, and general method for the indium-mediated enantioselective allylation of aromatic and aliphatic aldehydes and ketones under…”
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Journal Article -
2
Indium-Mediated Asymmetric Barbier-Type Propargylations: Additions to Aldehydes and Ketones and Mechanistic Investigation of the Organoindium Reagents
Published in Journal of organic chemistry (20-01-2012)“…We report a simple, efficient, and general method for the indium-mediated enantioselective propargylation of aromatic and aliphatic aldehydes under…”
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Journal Article -
3
Direct Synthesis of B-Allyl and B-Allenyldiisopinocampheylborane Reagents Using Allyl or Propargyl Halides and Indium Metal Under Barbier-Type Conditions
Published in Journal of organic chemistry (04-05-2012)“…We report the first one-pot process for the asymmetric addition of allyl, methallyl, and propargyl groups to aldehydes and ketones using…”
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Journal Article -
4
Boronic Acid-Based Bipyridinium Salts as Tunable Receptors for Monosaccharides and α-Hydroxycarboxylates
Published in Journal of the American Chemical Society (07-02-2007)“…Several novel diboronic acid-substituted bipyridinium salts were prepared and, using a fluorescent reporter dye, were tested for their ability to selectively…”
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5
Asymmetric indium-mediated synthesis of homopropargylic alcohols
Published in Tetrahedron letters (17-07-2006)“…A method for the enantioselective synthesis of homopropargylic alcohols using indium under Barbier-like conditions is reported herein. Both aromatic and…”
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6
Enantioselective alkynylations of aromatic and aliphatic aldehydes catalyzed by terpene derived chiral amino alcohols
Published in Tetrahedron: asymmetry (23-05-2005)“…[Display omitted] Enantioselective alkynyl zinc additions to aromatic and aliphatic aldehydes have been studied using terpene derived chiral amino alcohol…”
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Journal Article -
7
Asymmetric indium-mediated Barbier-type allylation reactions with ketones to form homoallylic alcohol products
Published in Tetrahedron letters (14-01-2008)“…We report a general method for the enantioselective allylation of both aromatic and aliphatic ketones under indium-mediated Barbier-type conditions. Using 2…”
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Journal Article -
8
Indium-mediated Barbier-type allylation of aldehydes as a convenient method for the highly enantioselective synthesis of homoallylic alcohols
Published in Tetrahedron letters (28-03-2005)“…[Display omitted] We report a general method for the indium-mediated Barbier-type enantioselective allylation of both aromatic and aliphatic aldehydes using…”
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Journal Article -
9
Novel reactions of organoindium compounds: The synthesis of chiral alcohols, allylboron reagents and identification of the reactive intermediates
Published 01-01-2007“…The stereocontrolled synthesis of small chiral molecules is a requirement for the synthesis of many complex natural or unnatural molecules. Enantiomerically…”
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Dissertation