Search Results - "Hillmyer, Marc"
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The promise of plastics from plants
Published in Science (American Association for the Advancement of Science) (17-11-2017)“…Plant-derived feedstocks are increasingly competitive in plastics production Polymers protect us from the elements, increase the fuel efficiency of cars,…”
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50th Anniversary Perspective: There Is a Great Future in Sustainable Polymers
Published in Macromolecules (23-05-2017)“…It is likely that a half-century ago even enthusiastic and optimistic proponents of the synthetic polymer industry (Mr. McGuire included) could not have…”
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Aliphatic Polyester Block Polymers: Renewable, Degradable, and Sustainable
Published in Accounts of chemical research (19-08-2014)“…Conspectus Nearly all polymers are derived from nonrenewable fossil resources, and their disposal at their end of use presents significant environmental…”
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Enhanced Mechanical Properties of Aliphatic Polyester Thermoplastic Elastomers through Star Block Architectures
Published in Macromolecules (26-10-2021)“…A series of sustainable aliphatic polyester thermoplastic elastomers (APTPEs) consisting of multi-arm star polymers with arms of…”
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Reticulated Nanoporous Polymers by Controlled Polymerization-Induced Microphase Separation
Published in Science (American Association for the Advancement of Science) (15-06-2012)“…Materials with percolating mesopores are attractive for applications such as catalysis, nanotemplating, and separations. Polymeric frameworks are particularly…”
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Solvent Vapor Annealing of Block Polymer Thin Films
Published in Macromolecules (23-07-2013)“…This Perspective provides a critical analysis of the current knowledge concerning solvent vapor annealing (SVA) of block polymer thin films. Herein, we…”
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7
Aliphatic Polyester Block Polymer Design
Published in Macromolecules (12-04-2016)“…Aliphatic polyester block polymers constitute a highly useful and amazingly versatile class of self-assembled materials. Analogous to styrenic block polymers…”
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Sub‑5 nm Domains in Ordered Poly(cyclohexylethylene)-block-poly(methyl methacrylate) Block Polymers for Lithography
Published in Macromolecules (25-02-2014)“…A series of poly(cyclohexylethylene)-block-poly(methyl methacrylate) (PCHE–PMMA) diblock copolymers with varying molar mass (4.9 kg/mol ≤ M n ≤ 30.6 kg/mol)…”
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High χ–Low N Block Polymers: How Far Can We Go?
Published in ACS macro letters (15-09-2015)“…Block polymers incorporating highly incompatible segments are termed “high χ” polymers, where χ is the Flory–Huggins interaction parameter. These materials…”
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Aliphatic Polyester Thermoplastic Elastomers Containing Hydrogen-Bonding Ureidopyrimidinone Endgroups
Published in Biomacromolecules (08-07-2019)“…Polylactide-block-poly(γ-methyl-ε-caprolactone)-block-polylactide (LML) is a sustainable thermoplastic elastomer (TPE) candidate that exhibits competitive…”
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Enhanced Polyester Degradation through Transesterification with Salicylates
Published in Journal of the American Chemical Society (29-09-2021)“…Polyesters constitute nearly 10% of the global plastic market, but most are essentially non-degradable under ambient conditions or in engineered environments…”
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12
Nanoporous Membranes Derived from Block Copolymers: From Drug Delivery to Water Filtration
Published in ACS nano (27-07-2010)“…With nanoscale pores, high porosity, narrow pore size distributions, and tunable chemical and mechanical properties, block copolymers hold tremendous potential…”
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Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers
Published in Journal of the American Chemical Society (11-11-2015)“…Vitrimers are polymer networks whose cross-links undergo associative exchange processes at elevated temperature, usually in the presence of an embedded…”
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Next-Generation Ultrafiltration Membranes Enabled by Block Polymers
Published in ACS nano (22-12-2020)“…Reliable and equitable access to safe drinking water is a major and growing challenge worldwide. Membrane separations represent one of the most promising…”
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Linear Rheology of Polyolefin-Based Bottlebrush Polymers
Published in Macromolecules (14-07-2015)“…Two series of polyolefin-based bottlebrush polymers were synthesized using ring-opening metathesis polymerization of norbornenyl-functionalized macromonomers…”
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Multicompartment Block Polymer Micelles
Published in Macromolecules (10-01-2012)“…Multicompartment micelles are an intriguing class of self-assembled aggregates with subdivided solvophobic cores. They have been subject to extensive research…”
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High-Modulus, High-Conductivity Nanostructured Polymer Electrolyte Membranes via Polymerization-Induced Phase Separation
Published in Nano letters (08-01-2014)“…The primary challenge in solid-state polymer electrolyte membranes (PEMs) is to enhance properties, such as modulus, toughness, and high temperature stability,…”
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Reprocessable Acid-Degradable Polycarbonate Vitrimers
Published in Macromolecules (23-01-2018)“…Vitrimers are cross-linked polymer networks containing linkages that undergo thermally activated, associative exchange reactions, such that the cross-link…”
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Thermal processing of diblock copolymer melts mimics metallurgy
Published in Science (American Association for the Advancement of Science) (05-05-2017)“…Small-angle x-ray scattering experiments conducted with compositionally asymmetric low molar mass poly(isoprene)-b-poly(lactide) diblock copolymers reveal an…”
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Polylactide Vitrimers
Published in ACS macro letters (15-07-2014)“…While much research has been aimed at new approaches to the healing of cross-linked polymers, there is a dearth of effort in the healing of renewable…”
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