Search Results - "Hightower, Sean E."
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1
Electronic and Molecular Structures of trans-Dioxotechnetium(V) Polypyridyl Complexes in the Solid State
Published in Inorganic chemistry (20-06-2011)“…The structures of novel Tc(V) complexes trans-[TcO2(py)4]Cl·2H2O (1a), trans-[TcO2(pic)4]Cl·2H2O (2a), and trans-[TcO2(pic)4]BPh4 (2b) were determined by X-ray…”
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2
Highly Oxidizing Excited States of Re and Tc Complexes
Published in Journal of the American Chemical Society (27-12-2006)“…Like the Re analogue, the ligand-to-metal charge transfer (LMCT) excited-state of [Tc(dmpe)3]2+ (dmpe is bis-1,2-(dimethylphosphino)ethane) is luminescent in…”
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3
Unusual, Bifurcated Photoreactivity of a Rhenium(I) Carbonyl Complex of Triethynylphosphine
Published in Inorganic chemistry (26-12-2005)“…Preparations of the first metal complexes of triethynylphosphine (TEP) are described. They are of the type fac-Re(bpy)(CO)3(TEP)+ (1) and…”
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4
Luminescence from the trans-Dioxotechnetium(V) Chromophore
Published in Journal of the American Chemical Society (02-11-2005)“…The luminescence of trans-[TcO2(L)4]+ (L = pyridine (py) or picoline (pic)) and trans-[TcO2(CN)4]3- at room and low temperature is described and represents the…”
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5
Dye-Sensitized Solar-Cell Performance of a Cobalt(III/II) Redox Mediator with the 2,6-Bis(8-quinolinyl)pyridine Ligand
Published in European journal of inorganic chemistry (01-08-2015)“…Optical and electrochemical properties of the homoleptic cobalt(III/II) complexes mer,mer‐[Co(tpy‐κ3N,N′,N″)]n+ and mer,mer‐[Co(bqp‐κ3N,N′,N″)]n+ (n = 3+ or…”
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6
Synthesis, structure, and hydrogen evolution studies of a heteroleptic Co(III) complex
Published in Inorganica Chimica Acta (01-03-2021)“…The cobalt(III) complex, mer-[Co(tpy)(phen)Cl](PF6)2, was synthesized via a one-pot synthesis and fully characterised; then utilised to photocatalytically…”
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7
Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction
Published in Chemical communications (Cambridge, England) (21-01-2014)“…The reactivity of a rhenium complex containing an NAD(+) model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form…”
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8
Photophysics and luminescence spectroelectrochemistry of [Tc(dmpe)3](+/2+) (dmpe = 1,2-bis(dimethylphosphino)ethane)
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (05-12-2013)“…The ligand-to-metal charge transfer (LMCT) excited state luminescence of [Tc(dmpe)3](2+) (dmpe is 1,2-bis-(dimethylphosphino)ethane) has been measured in…”
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9
Experimental and Computational Studies of Nuclear Substituted 1,1‘-Dimethyl-2,2‘-Bipyridinium Tetrafluoroborates
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (27-12-2007)“…The synthesis and spectral properties of a new 2,2‘-bipyridinium ion, 1,1‘-dimethyl-4,4‘-(dimethylamino)-2,2‘-bipyridinium bis(tetrafluoroborate) are reported…”
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10
Photophysics and Luminescence Spectroelectrochemistry of [Tc(dmpe)3]+/2+ (dmpe = 1,2-bis(dimethylphosphino)ethane)
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (05-12-2013)“…The ligand-to-metal charge transfer (LMCT) excited state luminescence of [Tc(dmpe)3]2+ (dmpe is 1,2-bis-(dimethylphosphino)ethane) has been measured in…”
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11
Conformationally Induced Electrostatic Stabilization of Persulfoxides: A New Suggestion for Inhibition of Physical Quenching of Singlet Oxygen by Remote Functional Groups
Published in Journal of the American Chemical Society (24-08-2005)“…1,5-Dithiacyclooctane is shown to chemically react more efficiently and to remove singlet oxygen from solution more rapidly than either thiane or 1,4-dithiane…”
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12
Natural Bond Orbital Analyses of Persulfoxide Stabilization by Remote Functional Groups. The Conformationally Induced Electrostatic Stabilization Sulfide Photooxygenation Mechanism
Published in Journal of organic chemistry (03-02-2006)“…The conformationally induced electrostatic stabilization (CIES) sulfide photooxygenation mechanism was computationally examined using an ab initio model and…”
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13
Preparation and characterization of rhenium(I) dicarbonyl complexes based on the meridionally-coordinated terpyridine ligand
Published in Inorganic chemistry communications (01-10-2012)“…The synthesis and characterization for a series of meridionally-coordinated terpyridine rhenium(I) dicarbonyl complexes from mer,cis-Re(tpy-κ3N)(CO)2Cl, 2, are…”
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14
Synthesis, characterization, X-ray structure and DFT calculations of a bistridentate Co(III) complex based on the 2,6-bis(8′-quinolinyl)pyridine ligand
Published in Inorganic chemistry communications (01-12-2014)“…2,6-Bis(8′-quinolinyl)pyridine (bqp) reacts with cobalt (II) acetate tetrahydrate in methanol with subsequent oxidation to give mer-[Co(bqp-κ3N,N′,N″)2](Br3)3…”
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15
Synthesis, structural characterization and spectroscopic properties of cobalt complexes with the 2,6-bis(8′-quinolinyl)pyridine ligand
Published in Polyhedron (15-10-2014)“…Coordination of the 2,6-bis(8′-quinolinyl)pyridine (bqp) ligand to a cobalt (Co) core and its influence to electron spin and configuration on the structures…”
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16
Tricarbonyl rhenium complex of 2,6-bis(8′-quinolinyl)pyridine: Synthesis, spectroscopic characterization, X-ray structure and DFT calculations
Published in Inorganic chemistry communications (01-04-2013)“…2,6-Bis(8′-quinolinyl)pyridine (bqp) reacts with pentacarbonyl rhenium chloride in toluene to give fac,fac-[Re(bqp-κ3N)(CO)3](Cl). X-ray crystallographic data…”
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17
Photophysics and Luminescence Spectroelectrochemistry of [Tc(dmpe) sub(3)] super(+/2+) (dmpe = 1,2-bis(dimethylphosphino)ethane)
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (05-02-2013)“…The ligand-to-metal charge transfer (LMCT) excited state luminescence of [Tc(dmpe) sub(3)] super(2+) (dmpe is 1,2-bis-(dimethylphosphino)ethane) has been…”
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18
Preparative and computational studies of metal complexes containing molecular cages
Published 01-01-2007“…Metal based oligomeric complexes have many applications including artificial photosynthesis, catalysis, and molecular electronics. For these applications, it…”
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Dissertation