Search Results - "Hidalgo, Nereida"
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1
Metal‐Free Phosphorus‐Directed Borylation of C(sp2)−H Bonds
Published in Angewandte Chemie International Edition (03-01-2022)“…Spectacular progress has recently been achieved in transition metal‐catalyzed C−H borylation of phosphines as well as directed electrophilic C−H borylation. As…”
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2
Reversible Hydride Migration from C5Me5 to RhI Revealed by a Cooperative Bimetallic Approach
Published in Angewandte Chemie International Edition (16-11-2020)“…The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous, mostly due to their robust spectator role. Nonetheless, increasing…”
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3
Metal‐Free Phosphorus‐Directed Borylation of C(sp2)−H Bonds
Published in Angewandte Chemie (03-01-2022)“…Spectacular progress has recently been achieved in transition metal‐catalyzed C−H borylation of phosphines as well as directed electrophilic C−H borylation. As…”
Get full text
Journal Article -
4
Reversible Hydride Migration from C5Me5 to RhI Revealed by a Cooperative Bimetallic Approach
Published in Angewandte Chemie (16-11-2020)“…The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous, mostly due to their robust spectator role. Nonetheless, increasing…”
Get full text
Journal Article -
5
Chemo-selective Stille-type coupling of acyl-chlorides upon phosphine-borane Au() catalysis
Published in Chemical science (Cambridge) (03-04-2024)“…Phosphine-boranes do not promote oxidative addition of acyl chlorides to gold, but the phosphine-borane gold triflimide complex [ i Pr 2 P( o -C 6 H 4 )BCy 2…”
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6
Reversible Hydride Migration from C 5 Me 5 to Rh I Revealed by a Cooperative Bimetallic Approach
Published in Angewandte Chemie International Edition (16-11-2020)“…The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous, mostly due to their robust spectator role. Nonetheless, increasing…”
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Journal Article -
7
Reactivity of [Pt(P t Bu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity
Published in Organometallics (26-04-2021)“…Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi cross-coupling reactions. Zinc-based…”
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8
Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems
Published in Chemistry : a European journal (12-05-2020)“…A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) metal‐only frustrated Lewis pair (FLP)…”
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9
Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study
Published in Angewandte Chemie International Edition (26-08-2022)“…The organometallic chemistry of 4d and 5d transition metals has been vastly dominated by closed‐shell states. The reactivity of their metalloradical species is…”
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10
Front Cover: Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems (Chem. Eur. J. 27/2020)
Published in Chemistry : a European journal (12-05-2020)“…Introducing transition‐metal elements into frustrated Lewis pairs has emerged as a promising approach to develop new cooperative catalysts. Based on the…”
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11
Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs
Published in Organometallics (13-07-2020)“…Introducing transition metals into frustrated Lewis pair systems has attracted considerable attention in recent years. Here we report a selection of three…”
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12
Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems
Published in Chemistry : a European journal (12-05-2020)“…Invited for the cover of this issue is the group of Joaquín López‐Serrano and Jesús Campos at the Consejo Superior de Investigaciones Científicas and the…”
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13
Reversible Hydride Migration from C 5 Me 5 to Rh I Revealed by a Cooperative Bimetallic Approach
Published in Angewandte Chemie (16-11-2020)“…Abstract The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous, mostly due to their robust spectator role. Nonetheless,…”
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Journal Article -
14
Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study
Published in Angewandte Chemie (26-08-2022)“…The organometallic chemistry of 4d and 5d transition metals has been vastly dominated by closed‐shell states. The reactivity of their metalloradical species is…”
Get full text
Journal Article