Search Results - "Hickey, Anne K"
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Magnetization Slow Dynamics in Ferrocenium Complexes
Published in Chemistry : a European journal (09-08-2019)“…The single‐molecule magnet (SMM) properties of a series of ferrocenium complexes, [Fe(η5‐C5R5)2]+ (R=Me, Bn), are reported. In the presence of an applied dc…”
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Spectroscopic and Computational Studies of Spin States of Iron(IV) Nitrido and Imido Complexes
Published in Inorganic chemistry (17-04-2017)“…High-oxidation-state metal complexes with multiply bonded ligands are of great interest for both their reactivity as well as their fundamental bonding…”
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Evidence for the Existence of Terminal Scandium Imidos: Mechanistic Studies Involving Imido–Scandium Bond Formation and C–H Activation Reactions
Published in Journal of the American Chemical Society (12-12-2012)“…The anilide–methyl complex (PNP)Sc(NH[DIPP])(CH3) (1) [PNP– = bis(2-diisopropylphosphino-4-tolyl)amide, DIPP = 2,6-diisopropylphenyl] eliminates methane…”
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4
Sulfide Homeostasis and Nitroxyl Intersect via Formation of Reactive Sulfur Species in Staphylococcus aureus
Published in mSphere (01-05-2017)“…is a commensal human pathogen and a major cause of nosocomial infections. As gaseous signaling molecules, endogenous hydrogen sulfide (H S) and nitric oxide…”
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Abstraction of a Vinylic Hydrogen to Form Alkynes. Multinuclear and Multidimensional NMR Spectroscopy and Computational Studies Elucidating Structural Solution Behavior of Acetylene and Propyne Complexes of Titanium
Published in Organometallics (10-03-2014)“…The alkyne complexes [(PNP)Ti(η2-HCCH)(CH2 tBu)] (2) and [(PNP)Ti(η2-HCCMe)(CH2 tBu)] (3) have been prepared by treatment of [(PNP)TiCHtBu(OTf)] (1) with…”
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Two-State Reactivity in Iron-Catalyzed Alkene Isomerization Confers σ‑Base Resistance
Published in Journal of the American Chemical Society (09-09-2020)“…A low-coordinate, high spin (S = 3/2) organometallic iron(I) complex is a catalyst for the isomerization of alkenes. A combination of experimental and…”
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7
A Bidentate Carbene Ligand Stabilizes a Low-Coordinate Iron(0) Carbonyl Complex
Published in Organometallics (12-09-2016)“…The bulky bis(carbene)borate ligand Ph2B(tBuIm)2 – stabilizes low-coordinate and low-valent iron complexes. The four-coordinate iron(II) complex…”
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Low-Valent Iron Carbonyl Complexes with a Tripodal Carbene Ligand
Published in Organometallics (28-09-2015)“…A bulky tris(carbene)borate ligand allows several low-valent iron carbonyl complexes to be isolated. One-electron reduction of the cationic iron(II) complex…”
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Room Temperature Dehydrogenation of Ethane, Propane, Linear Alkanes C4–C8, and Some Cyclic Alkanes by Titanium–Carbon Multiple Bonds
Published in Journal of the American Chemical Society (02-10-2013)“…The transient titanium neopentylidyne, [(PNP)TiC t Bu] (A; PNP–N[2-P i Pr2-4-methylphenyl]2 –), dehydrogenates ethane to ethylene at room temperature over 24…”
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10
A Dimeric Hydride-Bridged Complex with Geometrically Distinct Iron Centers Giving Rise to an S = 3 Ground State
Published in Journal of the American Chemical Society (31-07-2019)“…Structural and spectroscopic characterization of the dimeric iron hydride complex [Ph2B(tBuIm)2FeH]2 reveals an unusual structure in which a tetrahedral…”
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Protonation Studies of Molybdenum(VI) Nitride Complexes That Contain the [2,6-(ArNCH2)2NC5H3]2– Ligand (Ar = 2,6-Diisopropylphenyl)
Published in Inorganic chemistry (18-03-2019)“…[Ar2N3]Mo(N)(O-t-Bu) (1), which contains the conformationally rigid pyridine-based diamido ligand [2,6-(ArNCH2)2NC5H3]2– (Ar = 2,6-diisopropylphenyl), is a…”
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12
Arrested α-hydride migration activates a phosphido ligand for C-H insertion
Published in Chemical communications (Cambridge, England) (2017)“…Bulky tris(carbene)borate ligands provide access to high spin iron(ii) phosphido complexes. The complex PhB(MesIm) FeP(H)Ph is thermally unstable, and [PPh]…”
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Correction to Spectroscopic and Computational Studies of Spin States of Iron(IV) Nitrido and Imido Complexes
Published in Inorganic chemistry (15-06-2020)Get full text
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Two-State Reactivity in Iron-Catalyzed Alkene Isomerization Confers σ-Base Resistance
Published in Journal of the American Chemical Society (12-08-2020)“…A low-coordinate, high spin (S = 3/2) organometallic iron(I) complex is a catalyst for the isomerization of alkenes. A combination of experimental and…”
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Mechanisms of C-H Activation by Iron Complexes Supported by Tris- and Bis(Carbene)Borate Ligands
Published 2017“…Catalytic processes such as olefin metathesis, cross-coupling, and C-H activation rely on making and breaking metal-carbon bonds. In organometallic complexes,…”
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Dissertation