Search Results - "Hertsen, Dietmar"

Reactivity of 3-Oxo-[beta]-lactams with Respect to Primary Amines--An Experimental and Computational Approach by Piens, Nicola, Goossens, Hannelore, Hertsen, Dietmar, Deketelaere, Sari, Crul, Lieselotte, Demeurisse, Lotte, DeMoor, Jelle, VandenBroeck, Elias, Mollet, Karen, VanHecke, Kristof, VanSpeybroeck, Veronique, D'hooghe, Matthias

“…The reactivity of 3-oxo-[beta]-lactams with respect to primary amines was investigated in depth. Depending on the specific azetidin-2-one C4 substituent, this…”
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Influence of Solvation and Dynamics on the Mechanism and Kinetics of Nucleophilic Aromatic Substitution Reactions in Liquid Ammonia by Moors, Samuel L. C, Brigou, Ben, Hertsen, Dietmar, Pinter, Balazs, Geerlings, Paul, Van Speybroeck, Veronique, Catak, Saron, De Proft, Frank

“…The role of the solvent and the influence of dynamics on the kinetics and mechanism of the SNAr reaction of several halonitrobenzenes in liquid ammonia, using…”
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Formation of Fluorinated Amido Esters through Unexpected C3-C4 Bond Fission in 4-Trifluoromethyl-3-oxo-[beta]-lactams by DaoThi, Hang, Goossens, Hannelore, Hertsen, Dietmar, Otte, Valerie, VanNguyen, Tuyen, VanSpeybroeck, Veronique, D'hooghe, Matthias

“…4-Trifluoromethyl-3-oxo-[beta]-lactams were unexpectedly transformed into 2-[(2,2-difluorovinyl)amino]-2-oxoacetates as major products, accompanied by minor…”
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Formation of Fluorinated Amido Esters through Unexpected C3−C4 Bond Fission in 4‐Trifluoromethyl‐3‐oxo‐β‐lactams by Dao Thi, Hang, Goossens, Hannelore, Hertsen, Dietmar, Otte, Valerie, Van Nguyen, Tuyen, Van Speybroeck, Veronique, D'hooghe, Matthias

“…4‐Trifluoromethyl‐3‐oxo‐β‐lactams were unexpectedly transformed into 2‐[(2,2‐difluorovinyl)amino]‐2‐oxoacetates as major products, accompanied by minor amounts…”
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Tandem Addition of Phosphite Nucleophiles Across Unsaturated Nitrogen-Containing Systems: Mechanistic Insights on Regioselectivity by Debrouwer, Wouter, Hertsen, Dietmar, Heugebaert, Thomas S. A, Boydas, Esma Birsen, Van Speybroeck, Veronique, Catak, Saron, Stevens, Christian V

“…The addition of phosphite nucleophiles across linear unsaturated imines is a powerful and atom-economical methodology for the synthesis of aminophosphonates…”
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Reactivity of 3‐Oxo‐β‐lactams with Respect to Primary Amines—An Experimental and Computational Approach by Piens, Nicola, Goossens, Hannelore, Hertsen, Dietmar, Deketelaere, Sari, Crul, Lieselotte, Demeurisse, Lotte, De Moor, Jelle, Van den Broeck, Elias, Mollet, Karen, Van Hecke, Kristof, Van Speybroeck, Veronique, D'hooghe, Matthias

“…The reactivity of 3‐oxo‐β‐lactams with respect to primary amines was investigated in depth. Depending on the specific azetidin‐2‐one C4 substituent, this…”
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Nucleophile-Dependent Regio- and Stereoselective Ring Opening of 1-Azoniabicyclo[3.1.0]hexane Tosylate by Ji, Mi-Kyung, Hertsen, Dietmar, Yoon, Doo-Ha, Eum, Heesung, Goossens, Hannelore, Waroquier, Michel, Van Speybroeck, Veronique, D'hooghe, Matthias, De Kimpe, Norbert, Ha, Hyun-Joon

“…1‐[(1R)‐(1‐Phenylethyl)]‐1‐azoniabicyclo[3.1.0]hexane tosylate was generated as a stable bicyclic aziridinium salt from the corresponding…”
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Synthesis of poly(2‐oxazoline)s with side chain methyl ester functionalities: Detailed understanding of living copolymerization behavior of methyl ester containing monomers with 2‐alkyl‐2‐oxazolines by Bouten, P. J. M, Hertsen, Dietmar, Vergaelen, Maarten, Monnery, Bryn D, Catak, Saron, van Hest, Jan C. M, Van Speybroeck, Veronique, Hoogenboom, Richard

“…Poly(2‐oxazoline)s with methyl ester functionalized side chains are interesting as they can undergo a direct amidation reaction or can be hydrolyzed to the…”
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