Search Results - "Hernando, Héctor"
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Assessing the changes in thermal and catalytic pyrolysis of lignocellulose when shifting from batch to continuous biomass feeding modes
Published in Catalysis today (15-01-2024)“…Lignocellulosic biomass pyrolysis has been earlier studied in a large variety of reaction systems. However, there is a lack of information on the effects of…”
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2
Insights on the acetic acid pretreatment of wheat straw: changes induced in the biomass properties and benefits for the bio-oil production by pyrolysis
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-02-2023)“…[Display omitted] •Wheat straw washing with acetic acid enhances pyrolysis bio-oil production.•Bio-oil is sharply enriched in levoglucosan for the acetic acid…”
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3
Selective Decarboxylation of Fatty Acids Catalyzed by Pd-Supported Hierarchical ZSM‑5 Zeolite
Published in Energy & fuels (04-11-2021)“…Decarboxylation of fatty acids is an interesting route for the production of renewable long-chain hydrocarbons that could replace fossil resources in the…”
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4
Autocatalytic properties of biochar during lignocellulose pyrolysis probed using a continuous reaction system
Published in Catalysis today (01-06-2023)“…The autocatalytic role of the biochar formed during the pyrolysis of oak woodchips has been in situ assessed using a continuous reaction system. To that end,…”
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5
Simultaneous removal of brominated and chlorinated species during the production of oils by e-waste plastics catalytic hydropyrolysis
Published in Journal of hazardous materials (05-03-2024)“…The production of added-value chemicals via pyrolysis of plastic wastes, such as those from electrical and electronic equipment (WEEE), needs addressing their…”
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6
Evaluating fractional pyrolysis for bio-oil speciation into holocellulose and lignin derived compounds
Published in Journal of analytical and applied pyrolysis (01-03-2021)“…[Display omitted] •Thermal fractional pyrolysis renders efficient segregation of bio-oil components.•Lower bio-oil yields and oxygen content in respect to…”
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Lamellar and pillared ZSM-5 zeolites modified with MgO and ZnO for catalytic fast-pyrolysis of eucalyptus woodchips
Published in Catalysis today (15-11-2016)“…[Display omitted] •2D ZSM-5 zeolites enable an efficient catalytic fast pyrolysis of lignocellulose.•ZnO and MgO have been uniformly dispersed onto the…”
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8
Aldol condensation of furfural and methyl isobutyl ketone over Zr-MOF-808/silica hybrid catalysts
Published in Fuel (Guildford) (01-05-2023)“…[Display omitted] •Preparation of Zr-MOF-808/silica hybrid catalysts.•Preservation of structure integrity and incorporation of metalorganic phase on mesoporous…”
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Utilisation of a basic K-grafted USY zeolite in catalytic pyrolysis of wheat straw to produce valuable oxygenated compounds
Published in Catalysis today (01-05-2022)“…The catalytic properties of K-grafted USY zeolite in fast pyrolysis of acid-washed wheat straw have been investigated using the parent USY sample as a…”
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10
Biomass catalytic fast pyrolysis over hierarchical ZSM-5 and Beta zeolites modified with Mg and Zn oxides
Published in Biomass conversion and biorefinery (01-09-2017)“…Hierarchical ZSM-5 and Beta zeolites, loaded with MgO and ZnO, have been explored for the catalytic fast-pyrolysis of eucalyptus woodchips. These materials…”
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11
Efficient Conversion of Glucose to Methyl Lactate with Sn-USY: Retro-aldol Activity Promotion by Controlled Ion Exchange
Published in ACS sustainable chemistry & engineering (11-07-2022)“…Sn-USY materials have been prepared through an optimized post-synthetic catalytic metalation procedure. These zeolites displayed, upon ion exchange with…”
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12
Catalytic Copyrolysis of Lignocellulose and Polyethylene Blends over HBeta Zeolite
Published in Industrial & engineering chemistry research (24-04-2019)“…Coprocessing of Eucalyptus woodchips (EU) and low-density polyethylene (LDPE) has been investigated using two HBeta zeolites as catalyst. The reactions were…”
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13
Bio-oil production by lignocellulose fast-pyrolysis: Isolating and comparing the effects of indigenous versus external catalysts
Published in Fuel processing technology (01-12-2017)“…The effect of both indigenous (mineral components) and external (HZSM-5 zeolite) catalysts on bio-oil production by biomass fast-pyrolysis has being isolated…”
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14
Deactivation and regeneration of solid acid and base catalyst bodies used in cascade for bio-oil synthesis and upgrading
Published in Journal of catalysis (01-01-2022)“…[Display omitted] •High bio-oil yield of low O content by cascade biomass catalytic fast pyrolysis (CFM).•Acid ZrO2/ZSM-5-attapulgite catalyzes CFP; base…”
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15
Performance of MCM-22 zeolite for the catalytic fast-pyrolysis of acid-washed wheat straw
Published in Catalysis today (15-04-2018)“…[Display omitted] •MCM-22 zeolites enable an efficient catalytic fast-pyrolysis of lignocellulosic biomass.•Low concentration acid sites zeolites promoted…”
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16
Enhanced bio-oil upgrading in biomass catalytic pyrolysis using KH-ZSM-5 zeolite with acid-base properties
Published in Biomass conversion and biorefinery (01-12-2021)“…Biomass catalytic pyrolysis has been investigated using wheat straw, previously subjected to acid washing to remove the mineral matter, as raw material with…”
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17
Effect of Mesoporosity, Acidity and Crystal Size of Zeolite ZSM‐5 on Catalytic Performance during the Ex‐situ Catalytic Fast Pyrolysis of Biomass
Published in ChemCatChem (18-02-2021)“…The catalytic performance of a set of technical, zeolite ZSM‐5 extruded materials have been studied in a bench scale unit for the ex‐situ Catalytic Fast…”
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Cascade Deoxygenation Process Integrating Acid and Base Catalysts for the Efficient Production of Second-Generation Biofuels
Published in ACS sustainable chemistry & engineering (04-11-2019)“…An innovative cascade deoxygenation concept coupling the thermal pyrolysis of lignocellulose with two consecutive (acidic and basic) catalytic beds in a single…”
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Scaling‐Up of Bio‐Oil Upgrading during Biomass Pyrolysis over ZrO2/ZSM‐5‐Attapulgite
Published in ChemSusChem (07-06-2019)“…Ex situ catalytic biomass pyrolysis was investigated at both laboratory and bench scale by using a zeolite ZSM‐5‐based catalyst for selectively upgrading the…”
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Upscaling Effects on Alkali Metal‐Grafted Ultrastable Y Zeolite Extrudates for Modeled Catalytic Deoxygenation of Bio‐oils
Published in ChemCatChem (21-04-2021)“…Developing efficient solid catalysts is necessary when for example moving from batch chemistry to continuous flow systems. In this work, scale‐up effects of…”
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