Search Results - "Helvetica chimica acta"
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Skeletal Editing: Interconversion of Arenes and Heteroarenes
Published in Helvetica chimica acta (01-03-2023)“…Skeletal editing involves making specific point‐changes to the core of a molecule through the selective insertion, deletion or exchange of atoms. It thus…”
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2
Perovskite: Name Puzzle and German‐Russian Odyssey of Discovery
Published in Helvetica chimica acta (01-06-2020)“…Today the term ‘perovskite’ is used to designate the crystalline structure of a wide variety of ABX3 ionic compounds. However, historically this name was used…”
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3
Radical Alliances: Solutions and Opportunities for Organic Synthesis
Published in Helvetica chimica acta (01-08-2019)“…The present account discusses in detail various mechanistic features of the degenerative radical addition‐transfer of xanthates and related thiocarbonylthio…”
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4
Pnictogen‐Bonding Catalysts, Compared to Tetrel‐Bonding Catalysts: More Than Just Weak Lewis Acids
Published in Helvetica chimica acta (01-12-2022)“…A hyperresponsive tool to assess supramolecular catalysis, the cyclization of di‐epoxides into cyclic ethers is used to elucidate the difference between…”
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5
Vinylbenziodoxol(on)es: Synthetic Methods and Applications
Published in Helvetica chimica acta (01-12-2020)“…Cyclic hypervalent iodine reagents are now frequently used in synthetic organic chemistry, either as oxidants or group‐transfer reagents…”
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6
Halogen‐Bonded Liquid Crystals
Published in Helvetica chimica acta (01-05-2023)“…While the halogen bond has been recognised and studied for over a hundred years, it is only in more recent times that chemists have begun to apply it and see…”
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7
Tuning the Halogen Bonding Strength of Cyclic Diaryliodonium Salts
Published in Helvetica chimica acta (01-02-2021)“…Diaryliodonium(III) salts have recently received increasing interest as a new class of strong halogen bonding noncovalent organocatalysts. Even though this…”
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8
The Journey of Ni(I) Chemistry
Published in Helvetica chimica acta (01-12-2021)“…In the last twenty years, nickel has successfully imprinted its role in the field of homogeneous catalysis as a valid and complementary alternative to…”
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9
Gram‐Scale Synthesis, Isolation and Characterisation of Sodium Organometallics: nBuNa and NaTMP
Published in Helvetica chimica acta (01-08-2022)“…Organolithium compounds represent one of the most widely utilised commodity reagents in synthetic chemistry. However, their analogues with the heavier…”
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10
Screening of Three Transition Metal‐Mediated Reactions Compatible with DNA‐Encoded Chemical Libraries
Published in Helvetica chimica acta (01-04-2019)“…The construction of DNA‐encoded chemical libraries (DECLs) crucially relies on the availability of chemical reactions, which are DNA‐compatible and which…”
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11
Suppressing Inversion of a Chiral Polycyclic Aromatic Aza Monkey Saddle by Molecular Editing
Published in Helvetica chimica acta (04-11-2024)“…The synthesis of chiral polycyclic aromatic hydrocarbons with monkey saddle topology are a fascinating class of negatively curved compounds. To make these…”
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12
A Chiral Propeller‐Shaped Triple Helicene Shows Multi‐Resonant Thermally Activated Delayed Fluorescence
Published in Helvetica chimica acta (01-11-2024)“…Multi‐resonant thermally activated delayed fluorescence (MR‐TADF) helicenes show great potential as chiral emitters due to their typically high…”
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13
Electronic Structures of Late versus Early Transition Metal Imido Complexes from 15N‐NMR Signatures
Published in Helvetica chimica acta (01-11-2024)“…Imido ligand is a ubiquitous motif in organometallic chemistry, serving roles spanning from ancillary ligands to reactive sites. The nature of M=N bond is…”
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14
Facile Synthesis of Phthalazinone/Isoindolinone Substituted Fluorescence Active Indolo[1,2‐a]quinoxaline Derivatives via ANRORC and Fluorescence Turn Off Sensing of Fe2
Published in Helvetica chimica acta (01-11-2024)“…Synthesis of a series of indolo[1,2‐a]quinoxaline derivatives substituted with phthalazinones/isoindolinones/carbonyl benzoylesters at C‐4 position have been…”
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15
Facile Synthesis of Phthalazinone/Isoindolinone Substituted Fluorescence Active Indoloquinoxaline Derivatives via ANRORC and Fluorescence Turn Off Sensing of Fe2
Published in Helvetica chimica acta (01-11-2024)“…Synthesis of a series of indolo[1,2‐a]quinoxaline derivatives substituted with phthalazinones/isoindolinones/carbonyl benzoylesters at C‐4 position have been…”
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16
Total Synthesis of Tagitinins, Goyazensolide and Related Furanoheliangolides and their Covalent Interaction with Importin‐5 (IPO5)
Published in Helvetica chimica acta (01-11-2024)“…Herein, we detail an extension of our research on the synthesis of a small library of furanoheliangolides and the characterization of the covalent interaction…”
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17
The pKa of Water and the Fundamental Laws Describing Solution Equilibria: An Appeal for a Consistent Thermodynamic Pedagogy
Published in Helvetica chimica acta (01-11-2024)“…A recurring misconception in some textbooks and research papers has led to an abandonment of fundamental physical laws when describing a subset of acid‐base…”
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Facile Synthesis of Phthalazinone/Isoindolinone Substituted Fluorescence Active Indolo[1,2‐ a ]quinoxaline Derivatives via ANRORC and Fluorescence Turn Off Sensing of Fe 2
Published in Helvetica chimica acta (31-10-2024)“…Abstract Synthesis of a series of indolo[1,2‐ a ]quinoxaline derivatives substituted with phthalazinones/isoindolinones/carbonyl benzoylesters at C‐4 position…”
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19
Reversible Grafting in Surface Organometallic Chemistry with a Late Transition‐Metal Amidinate Precursor
Published in Helvetica chimica acta (17-10-2024)“…Supported catalysts are central to industrial catalytic processes. While traditional synthesis methods often yield poorly defined materials, thus complicating…”
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An Overview of Recent Advances in the Synthesis of Organic Unsymmetrical Disulfides
Published in Helvetica chimica acta (01-08-2021)“…Organic unsymmetrical disulfides have been extensively applied in various academic and industrial fields including intermediates in organic synthesis,…”
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