Search Results - "Heinz, Ernst"
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Molecular chirality at surfaces
Published in physica status solidi (b) (01-11-2012)“…With the adsorption of larger molecules being increasingly tackled by surface scientists, the aspect of chirality often plays a role. This paper gives a…”
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Helicenes on Surfaces: Stereospecific On‐Surface Chemistry, Single Enantiomorphism, and Electron Spin Selectivity
Published in Chirality (New York, N.Y.) (01-08-2024)“…ABSTRACT Helicenes represent an important class of chiral organic material with promising optoelectronic properties. Hence, functionalization of surfaces with…”
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3
Spin‐Selective Electron Transport Through Single Chiral Molecules
Published in Small (Weinheim an der Bergstrasse, Germany) (01-05-2024)“…The interplay between chirality and magnetism is a source of fascination among scientists for over a century. In recent years, chirality‐induced spin…”
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Enantioselective Adsorption on Magnetic Surfaces
Published in Advanced materials (Weinheim) (01-04-2024)“…From the beginning of molecular theory, the interplay of chirality and magnetism has intrigued scientists. There is still the question if enantiospecific…”
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Disappearing Enantiomorphs: Single Handedness in Racemate Crystals
Published in Angewandte Chemie International Edition (23-11-2015)“…Although crystallization is the most important method for the separation of enantiomers of chiral molecules in the chemical industry, the chiral recognition…”
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Unbalanced 2D Chiral Crystallization of Pentahelicene Propellers and Their Planarization into Nanographenes
Published in Chemistry : a European journal (16-07-2021)“…The chiral self‐assembly of trispentahelicene propellers on a gold surface has been investigated in ultrahigh vacuum by means of scanning tunneling microscopy…”
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Highly Stereospecific On‐Surface Dimerization into Bishelicenes: Topochemical Ullmann Coupling of Bromohelicene on Au(111)
Published in Chemistry : a European journal (16-05-2023)“…The on‐surface dimerization into bis(hexahelicene) on a gold(111) surface has been studied by means of scanning tunneling microscopy and time‐of‐flight…”
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Switching the on‐surface orientation of oxygen‐functionalized helicene
Published in Chirality (New York, N.Y.) (01-02-2024)“…Helicenes represent an important class of chiral organic material with promising optoelectronic properties. Hence, functionalization of surfaces with helicenes…”
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Double layer crystallization of heptahelicene on noble metal surfaces
Published in Chirality (New York, N.Y.) (01-07-2020)“…Resolution of enantiomers of chiral compounds via crystallization is the dominant method in chemical industry, but chiral recognition at the molecular level…”
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Stereospecific on‐Surface Cyclodehydrogenation of Bishelicenes: Preservation of Handedness from Helical to Planar Chirality
Published in Chemistry : a European journal (24-09-2021)“…Flattening helices while keeping the handedness: On‐surface cyclodehydrogenation of bishelicene enantiomers leads stereospecifically to (M,M) and (P,P) chiral…”
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11
From Homochiral Clusters to Racemate Crystals: Viable Nuclei in 2D Chiral Crystallization
Published in Journal of the American Chemical Society (01-07-2015)“…The quest for enantiopure compounds raises the question of which factors favor conglomerate crystallization over racemate crystallization. Studying nucleation…”
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12
Chiral Autocatalysis and Mirror Symmetry Breaking
Published in Catalysis letters (01-06-2018)“…Highly enantioselective production of chiral compounds by chiral catalysis is one of the most challenging forms of catalytic selectivity. In this perspective,…”
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Stereoselective On‐Surface Cyclodehydrofluorization of a Tetraphenylporphyrin and Homochiral Self‐Assembly
Published in Angewandte Chemie International Edition (28-09-2020)“…The thermally induced cyclodehydrofluorization of iron tetrakis(pentafluorophenyl)porphyrin proceeded highly stereoselectively to give a prochiral product on a…”
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14
On‐Surface Synthesis of Helicene Oligomers
Published in Chemistry : a European journal (06-06-2024)“…We report on‐surface synthesis of heterochiral 1D heptahelicene oligomers after deposition of a racemic heptahelicene monomer on an Au(111) surface followed by…”
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15
XXII. Symposium on Atomic, Cluster and Surface Physics (SASP)
Published in Chimia (01-06-2020)“…From Sunday February 2nd, 2020 until the following Friday, 75 scientists from all over the world gathered in Hotel Laudinella in St. Moritz to discuss their…”
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Amplification of chirality in two-dimensional enantiomorphous lattices
Published in Nature (26-01-2006)“…The concept of chirality dates back to 1848, when Pasteur manually separated left-handed from right-handed sodium ammonium tartrate crystals. Crystallization…”
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Two-Dimensional Crystallization of Enantiopure and Racemic Heptahelicene on Ag(111) and Au(111)
Published in Journal of physical chemistry. C (18-12-2014)“…Insight into recognition among helical molecules is highly relevant for understanding chiral separation or biomolecular activity. The two-dimensional…”
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Controlling On‐Surface Photoactivity: The Impact of π‐Conjugation in Anhydride‐Functionalized Molecules on a Semiconductor Surface
Published in Angewandte Chemie International Edition (22-07-2024)“…On‐surface synthesis has become a prominent method for growing low‐dimensional carbon‐based nanomaterials on metal surfaces. However, the necessity of…”
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Transition from Homochiral Clusters to Racemate Monolayers during 2D Crystallization of Trioxa[11]helicene on Ag(100)
Published in Chemphyschem (03-02-2021)“…The phenomenon of chiral crystallization into homochiral crystals is known for more than 170 years, yet it is still poorly understood. Studying crystallization…”
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Fivefold Symmetry and 2D Crystallization: Self‐Assembly of the Buckybowl Pentaindenocorannulene on a Cu(100) Surface
Published in Chemistry : a European journal (02-09-2019)“…The modification of metal electrode surfaces with functional organic molecules is an important part of organic electronics. The interaction of the…”
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