Search Results - "Heim, Karsten"
-
1
Extracellular Polymeric Substances Govern the Surface Charge of Biogenic Elemental Selenium Nanoparticles
Published in Environmental science & technology (03-02-2015)“…The origin of the organic layer covering colloidal biogenic elemental selenium nanoparticles (BioSeNPs) is not known, particularly in the case when they are…”
Get full text
Journal Article -
2
Eu3+-Mediated Polymerization of Benzenetetracarboxylic Acid Studied by Spectroscopy, Temperature-Dependent Calorimetry, and Density Functional Theory
Published in Inorganic chemistry (20-06-2011)“…Thermodynamic parameters for the complexation of Eu3+ with pyromellitic acid (1,2,4,5-benzenetetracarboxylic acid, BTC) as a model system for polymerizable…”
Get full text
Journal Article -
3
Analysis of technetium immobilization and its molecular retention mechanisms by Fe(II)-Al(III)-Cl layered double hydroxide
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-03-2021)“…[Display omitted] •Fe(II)-Al(III)-Cl LDH removes > 90% of aqueous Tc at pH > 6.•Tc retention is primarily due to Tc(VII) reduction to Tc(IV).•Tc(IV) forms…”
Get full text
Journal Article -
4
Unraveling the Np(V) sorption on ZrO2: A batch, spectroscopic and modeling combined approach
Published in Journal of hazardous materials (05-01-2024)“…The interactions of the long-lived actinide neptunium with the corrosion product zirconia (ZrO2) have to be considered in the safety assessment of a repository…”
Get full text
Journal Article -
5
Selenium(IV) Sorption Onto γ‑Al2O3: A Consistent Description of the Surface Speciation by Spectroscopy and Thermodynamic Modeling
Published in Environmental science & technology (16-01-2018)“…The sorption processes of Se(IV) onto γ-Al2O3 were studied by in situ Infrared spectroscopy, batch sorption studies, zeta potential measurements and surface…”
Get full text
Journal Article -
6
Curium(III) citrate speciation in biological systems: a europium(III) assisted spectroscopic and quantum chemical study
Published in Dalton transactions : an international journal of inorganic chemistry (07-12-2012)“…Citrate complexes are the dominant binding form of trivalent actinides and lanthanides in human urine at pH < 6. Hence, an accurate prediction of the…”
Get more information
Journal Article -
7
Complexation of Np(V) with the Dicarboxylates, Malonate, and Succinate: Complex Stoichiometry, Thermodynamic Data, and Structural Information
Published in Inorganic chemistry (20-12-2021)“…The complexation of Np(V) with malonate and succinate is studied by different spectroscopic techniques, namely, attenuated total reflection Fourier transform…”
Get full text
Journal Article -
8
The complexation of uranium(VI) and atmospherically derived CO2 at the ferrihydrite–water interface probed by time-resolved vibrational spectroscopy
Published in Journal of colloid and interface science (01-07-2012)“…[Display omitted] ► Formation of ternary surface complexes probed by online monitoring. ► Surface speciation of U(VI) on ferrihydrite at liquid–solid…”
Get full text
Journal Article -
9
The Sorption Processes of U(VI) onto SiO2 in the Presence of Phosphate: from Binary Surface Species to Precipitation
Published in Environmental science & technology (01-11-2016)“…The ternary system containing aqueous U(VI), aqueous phosphate and solid SiO2 was comprehensively investigated using a batch sorption technique, in situ…”
Get full text
Journal Article -
10
Selenium(IV) Sorption Onto γ-Al^sub 2^O^sub 3^: A Consistent Description of the Surface Speciation by Spectroscopy and Thermodynamic Modeling
Published in Environmental science & technology (16-01-2018)“…The sorption processes of Se(IV) onto γ-Al2O3 were studied by in situ Infrared spectroscopy, batch sorption studies, zeta potential measurements and surface…”
Get full text
Journal Article -
11
Selenium(IV) Sorption Onto γ-Al 2 O 3 : A Consistent Description of the Surface Speciation by Spectroscopy and Thermodynamic Modeling
Published in Environmental science & technology (16-01-2018)“…The sorption processes of Se(IV) onto γ-Al O were studied by in situ Infrared spectroscopy, batch sorption studies, zeta potential measurements and surface…”
Get full text
Journal Article -
12
The complexation of uranium(VI) and atmospherically derived CO2 at the ferrihydriteawater interface probed by time-resolved vibrational spectroscopy
Published in Journal of colloid and interface science (01-07-2012)“…The sorption reactions of uranium(VI) at the ferrihydrite(Fh)awater interface were investigated in the absence and presence of atmospherically derived CO2 by…”
Get full text
Journal Article -
13
The Sorption Processes of U(VI) onto SiO sub( 2) in the Presence of Phosphate: from Binary Surface Species to Precipitation
Published in Environmental science & technology (01-11-2016)“…The ternary system containing aqueous U(VI), aqueous phosphate and solid SiO2 was comprehensively investigated using a batch sorption technique, in situ…”
Get full text
Journal Article -
14
The Sorption Processes of U(VI) onto SiO^sub 2^ in the Presence of Phosphate: from Binary Surface Species to Precipitation
Published in Environmental science & technology (01-11-2016)“…The ternary system containing aqueous U(VI), aqueous phosphate and solid SiO2 was comprehensively investigated using a batch sorption technique, in situ…”
Get full text
Journal Article -
15
The Sorption Processes of U(VI) onto SiO 2 in the Presence of Phosphate: from Binary Surface Species to Precipitation
Published in Environmental science & technology (01-11-2016)“…The ternary system containing aqueous U(VI), aqueous phosphate and solid SiO was comprehensively investigated using a batch sorption technique, in situ…”
Get full text
Journal Article -
16
Eu(3+)-mediated polymerization of benzenetetracarboxylic acid studied by spectroscopy, temperature-dependent calorimetry, and density functional theory
Published in Inorganic chemistry (20-06-2011)“…Thermodynamic parameters for the complexation of Eu(3+) with pyromellitic acid (1,2,4,5-benzenetetracarboxylic acid, BTC) as a model system for polymerizable…”
Get full text
Journal Article -
17
Complex Formation of Uranium(VI) with L-Phenylalanine and 3-Phenylpropionic Acid Studied by Attenuated Total Reflection Fourier Transform Infrared Spectroscopy
Published in Applied spectroscopy (01-07-2008)“…Uranyl complexes with phenylalanine and the analogous ligand phenylpropionate were investigated in aqueous solution by attenuated total reflection (ATR)…”
Get full text
Journal Article -
18
-
19
Identification of actinide molecule complexes: A new vibrational spectroscopic approach at the free-electron laser facility FELBE
Published in Journal of nuclear materials (30-06-2007)“…Photothermal beam deflection (PTBD) spectroscopy using a free-electron laser (FEL) as a coherent pulsed pump source was applied for recording infrared spectra…”
Get full text
Journal Article