Search Results - "Hedman, B."

Ligand K-edge X-ray absorption spectroscopy: covalency of ligand–metal bonds by Solomon, Edward I., Hedman, Britt, Hodgson, Keith O., Dey, Abhishek, Szilagyi, Robert K.

“…The ligand K-edge probes the ligand 1s → valence np transitions. These transitions acquire intensity when the ligand is bound to an open shell metal ion. This…”
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Ligand K-Edge X-ray Absorption Spectroscopy:  A Direct Probe of Ligand−Metal Covalency by Glaser, Thorsten, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…Ligand K-edge X-ray absorption spectroscopy (XAS) is a new experimental probe of the covalency of a metal−ligand bond. The intensity of the ligand pre-edge…”
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IR and EXAFS Spectroscopic Studies of Glyphosate Protonation and Copper(II) Complexes of Glyphosate in Aqueous Solution by Sheals, Julia, Persson, Per, Hedman, Britt

“…The varying degrees of protonation of N-(phosphonomethyl)glycine (PMG, glyphosate) were investigated with infrared (IR) spectroscopy and ab initio frequency…”
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Changes in intrathecal baclofen dosage during long-term treatment in patients with spasticity due to traumatic spinal cord injuries by Skoog, B, Hylliemark, L, Hedman, B, Rutberg, L, Karlsson, A.-K

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Structural Insights into a Protein-Bound Iron-Molybdenum Cofactor Precursor by Corbett, Mary C., Hu, Yilin, Fay, Aaron W., Ribbe, Markus W., Hedman, Britt, Hodgson, Keith O.

“…The iron-molybdenum cofactor (FeMoco) of the nitrogenase MoFe protein is a highly complex metallocluster that provides the catalytically essential site for…”
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Neurophysiological evaluation of segmental motor neuron function of the thoracic cord in chronic SCI by Frostell, A, Mattsson, P, Persson, J K E, Hedman, B, Nordblom, J, Lindenryd, A, Trok, K, Brundin, L, Svensson, M

“…Study design: Pilot study. Objectives: The aim of the study was to develop a neurophysiological method to diagnose the cranial as well as the caudal level of a…”
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Spectroscopic and Density Functional Studies of the Red Copper Site in Nitrosocyanin:  Role of the Protein in Determining Active Site Geometric and Electronic Structure by Basumallick, Lipika, Sarangi, Ritimukta, DeBeer George, Serena, Elmore, Brad, Hooper, Alan B, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…The electronic structure of the red copper site in nitrosocyanin is defined relative to that of the well understood blue copper site of plastocyanin by using…”
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A Palladium-Oxo Complex. Stabilization of This Proposed Catalytic Intermediate by an Encapsulating Polytungstate Ligand by Anderson, Travis M, Cao, Rui, Slonkina, Elena, Hedman, Britt, Hodgson, Keith O, Hardcastle, Kenneth I, Neiwert, Wade A, Wu, Shaoxiong, Kirk, Martin L, Knottenbelt, Sushilla, Depperman, Ezra C, Keita, Bineta, Nadjo, Louis, Musaev, Djamaladdin G, Morokuma, Keiji, Hill, Craig L

“…A terminal Pd-oxo unit is reported. The unit is encapsulated in a cavity defined by two [A-α-PW9O34]9- units fused together by one [WO(OH2)]4+ center and forms…”
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A Quantitative Description of the Ground-State Wave Function of CuA by X-ray Absorption Spectroscopy:  Comparison to Plastocyanin and Relevance to Electron Transfer by DeBeer George, Serena, Metz, Markus, Szilagyi, Robert K, Wang, Hongxin, Cramer, Stephen P, Lu, Yi, Tolman, William B, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…To evaluate the importance of the electronic structure of CuA to its electron-transfer (ET) function, a quantitative description of the ground-state wave…”
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Spectroscopic and Electronic Structural Studies of Blue Copper Model Complexes. 2. Comparison of Three- and Four-Coordinate Cu(II)−Thiolate Complexes and Fungal Laccase by Randall, David W, George, Serena DeBeer, Holland, Patrick L, Hedman, Britt, Hodgson, Keith O, Tolman, William B, Solomon, Edward I

“…To evaluate the importance of the axial ligand in blue Cu centers, the electronic structure of a three-coordinate model compound LCuSCPh3 (2, L =…”
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S K-edge X-ray Absorption Studies of Tetranuclear Iron−Sulfur Clusters:  μ-Sulfide Bonding and Its Contribution to Electron Delocalization by Glaser, Thorsten, Rose, Kendra, Shadle, Susan E, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…X-ray absorption spectroscopy (XAS) at the sulfur (∼2470 eV) and chlorine (∼2822 eV) K-edges has been applied to a series of 4Fe−4S model complexes. These are…”
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IgE‐sensitization to predatory mites and respiratory symptoms in Swedish greenhouse workers by Kronqvist, M., Johansson, E., Kolmodin‐Hedman, B., Öman, H., Svartengren, M., Hage‐Hamsten, M.

“…Background:  Predatory mites are used as biological pesticides worldwide for control of spider mites and other pests in greenhouses. The aim of this study was…”
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Spectroscopic and Electronic Structural Studies of Blue Copper Model Complexes. 1. Perturbation of the Thiolate−Cu Bond by Randall, David W, George, Serena DeBeer, Hedman, Britt, Hodgson, Keith O, Fujisawa, Kiyoshi, Solomon, Edward I

“…A tris(pyrazolyl)hydroborate triphenylmethylthiolate Cu(II) model complex (1) that reproduces structural and spectroscopic features of active sites of blue Cu…”
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X-ray Absorption Spectroscopic Investigation of the Spin-Transition Character in a Series of Single-Site Perturbed Iron(II) Complexes by Rudd, Deanne Jackson, Goldsmith, Christian R., Cole, Adam P., Stack, T. Daniel P., Hodgson, Keith O., Hedman, Britt

“…Select ferrous spin-transition complexes with the pentadentate ligand 2,6-bis(bis(2-pyridyl)methoxymethane)pyridine (PY5) were examined using…”
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Electronic Structure of the Perturbed Blue Copper Site in Nitrite Reductase:  Spectroscopic Properties, Bonding, and Implications for the Entatic/Rack State by LaCroix, Louis B, Shadle, Susan E, Wang, Yaning, Averill, Bruce A, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…Low-temperature optical absorption, circular dichroism, magnetic circular dichroism, and sulfur K-edge X-ray absorption spectra have been measured for the…”
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Sulfur K-Edge X-ray Absorption Spectroscopy of 2Fe−2S Ferredoxin:  Covalency of the Oxidized and Reduced 2Fe Forms and Comparison to Model Complexes by Anxolabéhère-Mallart, Elodie, Glaser, Thorsten, Frank, Patrick, Aliverti, Alessandro, Zanetti, Giuliana, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…Ligand K-edge X-ray absorption spectroscopy (XAS) provides a direct experimental probe of ligand−metal bonding. In previous studies, this method has been…”
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Ligand K-edge x-ray absorption spectroscopic studies: metal-ligand covalency in a series of transition metal tetrachlorides by Shadle, Susan E, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…Ligand K-edge X-ray absorption spectroscopy has been shown to be a powerful tool in the study of the electronic structure of ligand-metal interactions in open…”
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Ligand K-Edge and Metal L-Edge X-ray Absorption Spectroscopy and Density Functional Calculations of Oxomolybdenum Complexes with Thiolate and Related Ligands:  Implications for Sulfite Oxidase by Izumi, Yasuo, Glaser, Thorsten, Rose, Kendra, McMaster, Jonathan, Basu, Partha, Enemark, John H, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…X-ray absorption spectra have been measured at the S K-, Cl K-, and Mo L3- and L2-edges for the d0 dioxomolybdenum(VI) complexes LMoO2(SCH2Ph), LMoO2Cl, and…”
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X-ray absorption spectroscopic studies of the blue copper site: metal and ligand K-edge studies to probe the origin of the EPR hyperfine splitting in plastocyanin by Shadle, Susan E, Penner-Hahn, James E, Schugar, Harvey J, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…X-ray absorption spectra for the oxidized blue copper protein plastocyanin and several Cu(II) model complexes have been measured at both the Cu K-edge and the…”
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Cu K-Edge XAS Study of the [Cu2(μ-O)2] Core:  Direct Experimental Evidence for the Presence of Cu(III) by DuBois, Jennifer L., Mukherjee, Pulakesh, Collier, Andrea M., Mayer, James M., Solomon, Edward I., Hedman, Britt, Stack, T. D. P., Hodgson, Keith O.

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