Search Results - "Hérault, Damien"
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Enantio- and Substrate-Selective Recognition of Chiral Neurotransmitters with C 3‑Symmetric Switchable Receptors
Published in Organic letters (07-02-2020)“…We report on the synthesis of C 3-symmetric enantiopure cage molecules 1, which exhibit remarkable to exclusive enantioselective recognition properties toward…”
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H‑Adamantylphosphinates as Universal Precursors of P‑Stereogenic Compounds
Published in Journal of organic chemistry (17-04-2015)“…A new family of H-adamantylphosphinates as universal precursors of P-stereogenic ligands was obtained in one step from commercial chlorophosphines. Both…”
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The Chloroazaphosphatrane Motif for Halogen Bonding in Solution
Published in Inorganic chemistry (16-08-2021)“…Chloroazaphosphatranes, the corresponding halogenophosphonium cations of the Verkade superbases, were evaluated as a new motif for halogen bonding (XB). Their…”
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The Hydroxyalkyl Moiety As a Protecting Group for the Stereospecific Alkylation of Masked Secondary Phosphine-Boranes
Published in Organic letters (04-01-2016)“…The synthesis of functionalized tertiary phosphine-boranes has been developed via a chemodivergent approach from readily accessible (hydroxymethyl)…”
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Endohedral Functionalized Cage as a Tool to Create Frustrated Lewis Pairs
Published in Angewandte Chemie International Edition (22-10-2018)“…A frustrated Lewis pair (FLP) system was obtained by confinement of the Lewis base partner, a Verkade's superbase, in a molecular cavity. Whereas the model…”
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Umpolung Reactivity of in Situ Generated Phosphido-Boranes: An Entry to P‑Stereogenic Aminophosphine-Boranes
Published in Journal of organic chemistry (05-04-2019)“…The synthesis of P-stereogenic aminophosphine-boranes has been developed on the basis of umpolung reactivity of in situ generated alkylarylphosphido-boranes,…”
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Transition metal complexes bearing atropisomeric saturated NHC ligands
Published in Chirality (New York, N.Y.) (01-01-2022)“…From achiral imidazolinium salts, chiral transition metal complexes containing an N‐heterocyclic carbene (NHC) ligand were prepared (metal = palladium, copper,…”
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Indium-catalysed ring opening of 2-hydroxybutyrolactone through the cleavage of C(sp 3 )–O bond
Published in Comptes rendus. Chimie (11-09-2023)“…The ring-opening by the cleavage of the C(sp 3)-O bond of 2-hydroxybutyrolactone with (ethylthio)trimethylsilane was effectively catalysed by indium triiodide…”
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Stereospecific Synthesis of α- and β-Hydroxyalkyl P-Stereogenic Phosphine-Boranes and Functionalized Derivatives: Evidence of the PO Activation in the BH3-Mediated Reduction
Published in Chemistry : a European journal (26-10-2015)“…Access to hydroxy‐functionalized P‐chiral phosphine–boranes has become an important field in the synthesis of P‐stereogenic compounds used as ligands in…”
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Racemization mechanism of lithium tert‐butylphenylphosphido‐borane: A kinetic insight
Published in Chirality (New York, N.Y.) (01-01-2022)“…The racemization mechanism of tert‐butylphenylphosphido‐borane is investigated experimentally and theoretically. Based on this converging approach, it is…”
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Enantiopure encaged Verkade's superbases: Synthesis, chiroptical properties, and use as chiral derivatizing agent
Published in Chirality (New York, N.Y.) (01-02-2020)“…Verkade's superbases, entrapped in the cavity of enantiopure hemicryptophane cages, have been synthesized with enantiomeric excess (ee) superior to 98%. Their…”
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Introducing Chirality at Phosphorus Atoms: An Update on the Recent Synthetic Strategies for the Preparation of Optically Pure P‐Stereogenic Molecules
Published in European journal of organic chemistry (23-06-2020)“…The synthesis of phosphorus molecules presenting a chiral center on the P‐atom, also known as P‐stereogenic compounds, has long attracted the curiosity of the…”
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Reduction of secondary and tertiary phosphine oxides to phosphines
Published in Chemical Society reviews (01-01-2015)“…Achiral or chiral phosphines are widely used in two main domains: ligands in organometallic catalysis and organocatalysis. For this reason, the obtention of…”
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The population structure of Glossina palpalis gambiensis from island and continental locations in Coastal Guinea
Published in PLoS neglected tropical diseases (2009)“…We undertook a population genetics analysis of the tsetse fly Glossina palpalis gambiensis, a major vector of sleeping sickness in West Africa, using…”
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Comparison of two soft chemistry routes for the synthesis of mesoporous carbon/β-SiC nanocomposites
Published in Journal of materials science (01-06-2013)“…We compare the influence of using either molecular or colloidal precursors on the synthesis of a ceramic material containing SiC and porous carbon. Remarkably,…”
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Physical Separation of Enantiomeric Products by Compartmentalized Parallel Kinetic Resolution
Published in Journal of the American Chemical Society (20-12-2023)“…Accessing each enantiomer of a chiral molecule starting from a racemic mixture remains a daunting challenge in chemistry. Indeed, until now, only a few…”
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A New Approach to the Synthesis of 4-Hydroxyethylsulfonylstyrene
Published in Organic process research & development (15-05-2009)“…A new, more environmentally benign route to hydroxyethylsulfonylstyrene has been developed, starting from 4-bromobenzenethiol, involving a solventless…”
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Synthesis and Structure of Planar Chiral, Bifunctional Aminoboronic Acid Ferrocene Derivatives
Published in Organometallics (23-04-2007)“…N,N‘-Diisopropylferrocenecarboxamide is utilized for an asymmetric, directed metalation approach to several planar chiral bifunctional ferrocene derivatives…”
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Asymmetric Direct Amide Synthesis by Kinetic Amine Resolution: A Chiral Bifunctional Aminoboronic Acid Catalyzed Reaction between a Racemic Amine and an Achiral Carboxylic Acid
Published in Angewandte Chemie (International ed.) (25-03-2008)“…Let's resolve this: A planar chiral benzimidazole ferroceneboronic acid catalyst demonstrates low to moderate asymmetric induction in the kinetic resolution of…”
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