Search Results - "Hawker, Craig"
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Biological Utility of Fluorinated Compounds: from Materials Design to Molecular Imaging, Therapeutics and Environmental Remediation
Published in Chemical reviews (12-01-2022)“…The applications of fluorinated molecules in bioengineering and nanotechnology are expanding rapidly with the controlled introduction of fluorine being broadly…”
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A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization
Published in Journal of the American Chemical Society (01-07-2015)“…A new and general strategy for the synthesis of sequence-defined polymers is described that employs relay metathesis to promote the ring opening polymerization…”
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3
Control of a Living Radical Polymerization of Methacrylates by Light
Published in Angewandte Chemie International Edition (27-08-2012)“…On–off: A living radical polymerization procedure, which utilizes ppm levels of an iridium‐based photoredox catalyst, affords control over chain growth through…”
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Block Copolymer Nanolithography: Translation of Molecular Level Control to Nanoscale Patterns
Published in Advanced materials (Weinheim) (18-12-2009)“…The self‐asembly of block copolymers is a promising platform for the “bottom‐up” fabrication of nanostructured materials and devices. This review covers some…”
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High-Throughput Synthesis, Purification, and Application of Alkyne-Functionalized Discrete Oligomers
Published in Journal of the American Chemical Society (27-03-2024)“…The development of synthetic oligomers as discrete single molecular entities with accurate control over the number and nature of functional groups along the…”
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New methodologies in the construction of dendritic materials
Published in Chemical Society reviews (01-01-2009)“…Dendritic polymers are highly branched polymer structures, with complex, secondary architectures and well-defined spatial location of functional groups. Due to…”
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A multi-stage single photochrome system for controlled photoswitching responses
Published in Nature chemistry (01-08-2022)“…The ability of molecular photoswitches to convert on/off responses into large macroscale property change is fundamental to light-responsive materials. However,…”
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Designing with Light: Advanced 2D, 3D, and 4D Materials
Published in Advanced materials (Weinheim) (01-05-2020)“…Recent achievements and future opportunities for the design of 2D, 3D, and 4D materials using photochemical reactions are summarized. Light is an attractive…”
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Synthesis of Discrete Oligomers by Sequential PET‐RAFT Single‐Unit Monomer Insertion
Published in Angewandte Chemie International Edition (10-07-2017)“…Uniform synthetic polymers with precisely defined molar mass and monomer sequence (primary structure) have many potential high‐value applications. However, a…”
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Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization
Published in Macromolecules (09-10-2018)“…The increasing impact of atom transfer radical polymerization (ATRP) in fields beyond traditional polymer science has necessitated the development of…”
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Discrete Libraries of Amphiphilic Poly(ethylene glycol) Graft Copolymers: Synthesis, Assembly, and Bioactivity
Published in Journal of the American Chemical Society (26-10-2022)“…Poly(ethylene glycol) (PEG) is an important and widely used polymer in biological and pharmaceutical applications for minimizing nonspecific binding while…”
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Click chemistry strategies for the accelerated synthesis of functional macromolecules
Published in Journal of polymer science (2020) (01-06-2021)“…Click chemistry is one of the most powerful strategies for constructing polymeric soft materials with precise control over architecture and functionality. In…”
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Metal-Free Atom Transfer Radical Polymerization
Published in Journal of the American Chemical Society (12-11-2014)“…Overcoming the challenge of metal contamination in traditional ATRP systems, a metal-free ATRP process, mediated by light and catalyzed by an organic-based…”
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Design and Synthesis of Donor–Acceptor Stenhouse Adducts: A Visible Light Photoswitch Derived from Furfural
Published in Journal of organic chemistry (05-12-2014)“…The development of an easily synthesized, modular, and tunable organic photoswitch that responds to visible light has been a long-standing pursuit. Herein we…”
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Engineering live cell surfaces with functional polymers via cytocompatible controlled radical polymerization
Published in Nature chemistry (01-06-2017)“…The capability to graft synthetic polymers onto the surfaces of live cells offers the potential to manipulate and control their phenotype and underlying…”
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Strategies for Achieving Oxygen Tolerance in Reversible Addition–Fragmentation Chain Transfer Polymerization
Published in Macromolecular chemistry and physics (01-10-2023)“…Abstract Reversible addition–fragmentation chain transfer polymerization (RAFT) is a popular method for the synthesis of well‐defined macromolecules, but its…”
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Photoswitching Using Visible Light: A New Class of Organic Photochromic Molecules
Published in Journal of the American Chemical Society (11-06-2014)“…A versatile new class of organic photochromic molecules that offers an unprecedented combination of physical properties including tunable photoswitching using…”
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Robust, Efficient, and Orthogonal Synthesis of Dendrimers via Thiol-ene “Click” Chemistry
Published in Journal of the American Chemical Society (16-04-2008)“…Dendrimers up to the fourth generation were successfully prepared via the divergent growth strategy using a combination of thiol-ene “click” chemistry and…”
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Controlling Dark Equilibria and Enhancing Donor–Acceptor Stenhouse Adduct Photoswitching Properties through Carbon Acid Design
Published in Journal of the American Chemical Society (22-08-2018)“…A novel library of tunable negative photochromic compounds, donor–acceptor Stenhouse adducts (DASAs), is reported. Tailoring the electron deficient “acceptor”…”
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The Beauty of Branching in Polymer Science
Published in Macromolecules (12-05-2020)Get full text
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