Search Results - "Hata, Takeshi"
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Copper-Catalyzed 1,2-Double Amination of 1-Halo-1-alkynes. Concise Synthesis of Protected Tetrahydropyrazines and Related Heterocyclic Compounds
Published in Journal of the American Chemical Society (13-02-2008)“…Reaction of N,N‘-di(p-toluenesulfonyl)-1,2-diamine, 1-bromo-1-alkyne, K3PO4, and a catalytic amount of CuI in hot DMF afforded…”
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A mutation in the Cc.arp9 gene encoding a putative actin-related protein causes defects in fruiting initiation and asexual development in the agaricomycete Coprinopsis cinerea
Published in Current genetics (01-08-2016)“…Agaricomycetes exhibit a remarkable morphological differentiation from vegetative mycelia to huge fruiting bodies. To investigate the molecular mechanism…”
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Rh-catalyzed intramolecular cyclization of 1-sulfonyl-1,2,3-triazole and sulfinate. Concise preparation of sulfonylated unsaturated piperidines
Published in Tetrahedron letters (21-03-2019)“…[Display omitted] •Strictly ordered scission and formation of a few bonds are attained in one flask.•Traditional S and new Rh chemistries elegantly…”
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Rh-Catalyzed Isomerization and Intramolecular Redox Reaction of Alkynyl Ethers Affording Dihydropyrans and Ketoolefins
Published in Journal of the American Chemical Society (11-03-2009)“…When arylmethyl 4-(sulfonyl)-3-butynyl ether and a catalytic amount of Rh2(tfa)4 (tfa = CF3CO2−) were heated in toluene,…”
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Rhodium-Catalyzed Intramolecular Hydroarylation of 1-Halo-1-alkynes: Regioselective Synthesis of Semihydrogenated Aromatic Heterocycles
Published in Chemistry : a European journal (03-01-2014)“…The regioselective intramolecular hydroarylation of (3‐halo‐2‐propynyl)anilines, (3‐halo‐2‐propynyl) aryl ethers, or (4‐halo‐3‐butynyl) aryl ethers was…”
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Nucleophilic Addition of Sulfonamides to Bromoacetylenes: Facile Preparation of Pyrroles
Published in Organic letters (16-09-2011)“…Nucleophilic addition of sulfonamides to 1-bromo-1-alkynes provided (Z)-N-(1-bromo-1-alken-2-yl)-p-toluenesulfonamides in good yield and in a highly regio- and…”
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Facile Preparation of Indoles and 1,2-Benzothiazine 1,1-Dioxides: Nucleophilic Addition of Sulfonamides to Bromoacetylenes and Subsequent Palladium-Catalyzed Cyclization
Published in Angewandte Chemie International Edition (25-06-2012)“…Bromine as a double agent: The bromine atom in 1‐bromo‐1‐alkynes works as an electron‐withdrawing group to effect the nucleophilic addition of sulfonamides. It…”
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Synthesis of tert-Butyl Peroxyacetals from Benzyl, Allyl, or Propargyl Ethers via Iron-Promoted CH Bond Functionalization
Published in Advanced synthesis & catalysis (14-12-2012)“…When benzyl, allyl, and propargyl ethers were treated with tert‐butyl hydroperoxide and a catalytic amount of iron(III) acetylacetonate, tert‐butyl…”
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Additive-Free Nucleophilic Addition of Imidazolines and Imidazoles to Haloacetylenes
Published in Organic letters (06-01-2012)“…Nucleophilic addition of imidazolines to 1-halo-1-alkynes takes place by simple heating in DMF without any additives to give…”
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Iron-Catalyzed Synthesis of Allenes from 2-Alken-4-ynoates and Grignard Reagents
Published in Advanced synthesis & catalysis (09-07-2012)“…Treatment of 2‐alken‐4‐ynoates with methyl‐ or aryl‐Grignard reagents and iron(II) chloride (10 mol%) afforded 5‐methyl‐ or 5‐aryl‐3,4‐alkadienoates in good…”
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Mutation analysis of 2009 pandemic influenza A(H1N1) viruses collected in Japan during the peak phase of the pandemic
Published in PloS one (29-04-2011)“…Pandemic influenza A(H1N1) virus infection quickly circulated worldwide in 2009. In Japan, the first case was reported in May 2009, one month after its…”
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Aryl(sulfonyl)amino Group: A Convenient and Stable Yet Activated Modification of Amino Group for Its Intramolecular Displacement
Published in Organic letters (17-09-2010)“…Aryl(sulfonyl)amino groups, readily derived from sulfonyl- or arylamines by standard methods as well as the recently introduced methods of sulfonylation and…”
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Geminal Difunctionalization of Alkenylidene-Type Carbenoids by Using Interelement Compounds
Published in Angewandte Chemie International Edition (16-02-2001)“…A 1,2‐migration of a boryl or silyl group with inversion of configuration occurs in the reaction of alkylidene‐type lithium carbenoids with diboron or…”
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Facile Preparation of 1,2-Dihydroisoquinolines from N-Benzylsulfonamides and Bromoacetylenes
Published in Heterocycles (2015)Get full text
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Rh-catalyzed intramolecular debenzylative cyclization of amines. Butyrolactams from benzylamines having a chloroacetylene moiety
Published in Tetrahedron letters (11-05-2011)“…When benzylamines having a chloroacetylene moiety were heated in wet toluene with a catalytic amount of rhodium trifluoroacetate dimer, intramolecular…”
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Facile preparation of N-protected 2-alkylidene-1,3-imidazolidines
Published in Tetrahedron letters (01-03-2008)“…Stereoselective preparation of unsymmetrically protected 2-alkylidene-1,3-imidazolidines was achieved by the reaction of N,N′-protected ethylenediamine,…”
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An experimental and modeling investigation of particle production by spray pyrolysis using a laminar flow aerosol reactor
Published in Journal of materials research (01-03-2000)“…The influence of operating parameters on the morphology of particles prepared by spray pyrolysis was investigated using a temperature-graded laminar flow…”
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Asymmetric Synthesis of Axially Chiral Benzamides and Anilides by Enantiotopic Lithiation of Prochiral Arene Chromium Complexes
Published in Journal of organic chemistry (22-03-2002)“…Axially chiral benzamides and anilides were prepared by enantiotopic lithiation at the distinguished benzylic methyl of prochiral tricarbonylchromium complexes…”
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A grid-based runoff generation and flow routing model for the Upper Blue Nile basin
Published in Hydrological sciences journal (01-04-2006)“…A simple water balance model was used to generate monthly water surplus for 0.5° grid cells of the Upper Blue Nile basin. An application of a spatially…”
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