Search Results - "Harvey, Melanie J."
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Group 13 Compounds Incorporating Salen Ligands
Published in Chemical reviews (01-01-2001)“…In a previous review it was predicted that "the reactivity of five-coordinate complexes would certainly be different than that of the four-coordinate…”
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Journal Article -
2
Stability of cyclopentadienyl aryloxide complexes of calcium and barium
Published in Journal of alloys and compounds (04-12-2009)“…The synthesis of mono(cyclopentadienyl)aryloxide complexes of calcium and barium has been investigated. The reaction of ICa(ODipp)(thf) 4 (Odipp = [2,6- iPr-OC…”
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Journal Article Conference Proceeding -
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Mono(cyclopentadienyl) Complexes of Calcium, Strontium, and Barium, {[C5(SiMe3)3H2](Ca,Sr,Ba)I(thf) n } x . Influence of Alkali-Metal Cations on Ligand Exchange Reactions
Published in Organometallics (17-04-2000)“…Reaction of the alkali-metal cyclopentadienide MCp‘ with an alkaline-earth dihalide (AeX2) in ethers is usually an efficient route to group 2 cyclopentadienyl…”
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Journal Article -
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A Homologous Series of Base-Free Organo(alkaline-earth) Metallocenes: Synthesis and Molecular Structures of [1,2,4-(SiMe3)3C5H2]2(Ca, Sr, Ba)
Published in European journal of inorganic chemistry (01-09-2003)“…Bis[1,2,4‐tris(trimethylsilyl)cyclopentadienyl] complexes [1,2,4‐(SiMe3)3C5H2]2Ae [(Cp3Si)2Ae; Ae = Ca (1), Sr (2), Ba (3)] are isolated from the 2:1 reaction…”
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Journal Article -
5
Salen-Type Compounds of Calcium and Strontium
Published in Inorganic chemistry (21-10-2002)“…Salen complexes of the heavy alkaline-earth metals, calcium and strontium, were prepared by the reaction of various salen(t-Bu)H2 ligands with the metals in…”
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Journal Article -
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Synthesis and Crystal Structure of the Bis(allyl)calcium Complex [Ca{C3(SiMe3)2H3}2⋅(thf)2]
Published in Angewandte Chemie International Edition (15-01-1999)“…Two η3‐allyl ligands in an anti configuration are present in the title compound (structure depicted). Even though the Ca−C bonds are about the length expected…”
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Journal Article -
7
Formation and crystal structures of a monomer–dimer pair of mono(cyclopentadienyl)calcium complexes, [C 5( t-Bu) 3H 2] 2CaI(THF) 2 and {[C 5( t-Bu) 3H 2] 2CaI(THF)} 2
Published in Journal of organometallic chemistry (30-04-2001)“…The mono(cyclopentadienyl)calcium iodide complex [{(Cp 3T)CaI(THF) x } n ] (Cp 3T=[C 5( t-Bu) 3H 2] −) is generated from the 1:1 reaction of K[Cp 3T] and CaI 2…”
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Journal Article -
8
Binuclear Salan borate compounds with three-coordinate boron atoms
Published in Journal of organometallic chemistry (15-01-2006)“…Salan( t Bu)H 4 ligands react with B(OMe) 3 or B(OSiMe 3) 3 to form Salan( t Bu)(BOMe) 2 (shown) or Salan( t Bu)(BOSiMe 3) 2 containing three-coordinate boron…”
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Journal Article -
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Synthese und Kristallstruktur des Bis(allyl)‐Calciumkomplexes [Ca{C3(SiMe3)2H3}2(thf)2]
Published in Angewandte Chemie (15-01-1999)“…Zweiη3‐Allylliganden in anti‐Konfiguration weist die Titelverbindung auf (Struktur im Kristall siehe Bild). Zwar haben die Ca‐C‐Bindungen etwa die Länge, die…”
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Journal Article -
10
Synthese und Kristallstruktur des Bis(allyl)-Calciumkomplexes [Ca{C3(SiMe3)2H3}2(thf)2]
Published in Angewandte Chemie (15-01-1999)Get full text
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