Search Results - "Harvey, Emma C"
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Palladium-Catalyzed Anti-Markovnikov Oxidation of Allylic Amides to Protected β‑Amino Aldehydes
Published in Journal of the American Chemical Society (10-12-2014)“…A general method for the preparation of N-protected β-amino aldehydes from allylic amines or linear allylic alcohols is described. Here the Pd(II)-catalyzed…”
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2
Manganese-Catalyzed Selective Oxidation of Aliphatic CH groups and Secondary Alcohols to Ketones with Hydrogen Peroxide
Published in ChemSusChem (01-09-2013)“…An efficient and simple method for selective oxidation of secondary alcohols and oxidation of alkanes to ketones is reported. An in situ prepared catalyst is…”
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3
Incorporating Cobalt Carbonyl Moieties onto Ethynylthiophene-Based Dithienylcyclopentene Switches. 1. Photochemistry
Published in Organometallics (27-01-2014)“…The synthesis and characterization of a series of dithienyl perhydro- and perfluorocyclopentene photochromic molecular switches appended with cobalt carbonyl…”
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Incorporating Cobalt Carbonyl Moieties onto Ethynylthiophene-Based Dithienylcyclopentene Switches. 2. Electro- and Spectroelectrochemical Properties
Published in Organometallics (14-07-2014)“…The redox behavior of dithienyl perhydro- and perfluorocyclopentene photochromic molecular switches, modified with 3-ethynylthiophene and…”
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5
Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)₅CrC(NC₄H₈)CH₃]
Published in Physical chemistry chemical physics : PCCP (21-10-2014)“…Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time…”
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Photochemistry of (η6-Arene)Cr(CO)3 (Arene = Methylbenzoate, Naphthalene, or Phenanthrene) in n-Heptane Solution: Population of Two Excited States Following 400 nm Excitation As Detected by Picosecond Time-Resolved Infrared Spectroscopy
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-04-2011)“…The photochemistry of (η6-methylbenzoate)Cr(CO)3, (η6-naphthalene)Cr(CO)3, and (η6-phenanthrene)Cr(CO)3 in n-heptane solution was investigated by picosecond…”
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7
Photochemistry of (η6-Anisole)Cr(CO)3 and (η6-Thioanisole)Cr(CO)3: Evidence for a Photoinduced Haptotropic Shift of the Thioanisole Ligand, a Picosecond Time-Resolved Infrared Spectroscopy and Density Functional Theory Investigation
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (26-01-2012)“…The photochemistry of (η6-anisole)Cr(CO)3 and (η6-thioanisole)Cr(CO)3 was investigated by picosecond time-resolved infrared spectroscopy in n-heptane solution…”
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8
Excited State Dynamics and Activation Parameters of Remarkably Slow Photoinduced CO Loss from (η6-Benzene)Cr(CO)3 in n-Heptane Solution: A DFT and Picosecond-Time-Resolved Infrared Study
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (04-11-2010)“…The electronic structure of (η6-benzene)Cr(CO)3 has been calculated using density functional theory and a molecular orbital interaction diagram constructed…”
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9
Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches
Published in Coordination chemistry reviews (01-01-2015)“…In this review recent progress in combining metal carbonyl and bipyridyl transition metal complexes with dithienylethene photochromic switches is discussed…”
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10
Manganese-Catalyzed Selective Oxidation of Aliphatic CH groups and Secondary Alcohols to Ketones with Hydrogen Peroxide
Published in ChemSusChem (01-09-2013)“…An efficient and simple method for selective oxidation of secondary alcohols and oxidation of alkanes to ketones is reported. An insitu prepared catalyst is…”
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11
Photochemistry of ( eta super(6)-Anisole)Cr(CO) sub(3) and ( eta super(6)-Thioanisole)Cr(CO) sub(3 ): Evidence for a Photoinduced Haptotropic Shift of the Thioanisole Ligand, a Picosecond Time-Resolved Infrared Spectroscopy and Density Functional Theory Investigation
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (06-01-2012)“…The photochemistry of ( eta super(6)-anisole)Cr(CO) sub(3) and ( eta super(6)-thioanisole)Cr(CO) sub(3 ) was investigated by picosecond time-resolved infrared…”
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12
Photochemistry of (η(6)-arene)Cr(CO)3 (arene = methylbenzoate, naphthalene, or phenanthrene) in n-heptane solution: population of two excited states following 400 nm excitation as detected by picosecond time-resolved infrared spectroscopy
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-04-2011)“…The photochemistry of (η(6)-methylbenzoate)Cr(CO)(3), (η(6)-naphthalene)Cr(CO)(3), and (η(6)-phenanthrene)Cr(CO)(3) in n-heptane solution was investigated by…”
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