Solvent effects on the rate of oxidative addition of methyl iodide to di(4-thiocresol)(2,2′-bipyridyl) platinum(II)

Solvent effects on the rate of oxidative addition of methyl iodide to di(4-thiocresol)(2,2′-bipyridyl) platinum(II)

The reaction of methyl iodide with di(4-thiocresol)(2,2′-bipyridyl) platinum(II) to give iodo (methyl) di(4-thiocresol)(2,2′-bipyridyl) platinum(IV) follows the rate law, rate= K 2[Pt-(4-thiocresol) 2 (2,2′-bipyridyl)] [MeI]. The values of K 2 increase with increasing polarity of the solvent, sugges...

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Bibliographic Details
Published in:Journal of organometallic chemistry Vol. 599; no. 2; pp. 166 - 169
Main Authors: Jawad, Ja’afar K, Al-Obaidy, Faisal N.K, Hammud, Jasim A, Al-Azab, Fathi
Format: Journal Article
Language:English
Published: Elsevier B.V 15-04-2000
Subjects:
Oxidative addition
Platinum
Solvent effects
Platinum
Oxidative addition
Solvent effects
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Summary:The reaction of methyl iodide with di(4-thiocresol)(2,2′-bipyridyl) platinum(II) to give iodo (methyl) di(4-thiocresol)(2,2′-bipyridyl) platinum(IV) follows the rate law, rate= K 2[Pt-(4-thiocresol) 2 (2,2′-bipyridyl)] [MeI]. The values of K 2 increase with increasing polarity of the solvent, suggesting a polar transition state for the reaction.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(99)00759-7