Search Results - "Hammann, M"
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1
The sociopolitical in human genetics education
Published in Science (American Association for the Advancement of Science) (23-02-2024)“…Education must go beyond only countering essentialist and deterministic views of genetics…”
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2
A Transition-Metal-Free Synthesis of Fluorinated Naphthols
Published in Chemistry : a European journal (26-05-2014)“…Herein, we describe a transition‐metal‐free protocol for the conversion of simple 2‐allyl‐3‐(trifluoromethyl)phenols into substituted 5‐fluoronaphthalen‐1‐ols…”
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3
Stereoselective Synthesis and Reactions of Secondary Alkyllithium Reagents Functionalized at the 3-Position
Published in Angewandte Chemie International Edition (23-02-2015)“…Secondary alkyllithium reagents bearing an OTBS group (TBS=tert‐butyldimethylsilyl) at the 3‐position can be prepared stereoconvergently through an I/Li…”
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4
Recent Developments in Negishi Cross-Coupling Reactions
Published in ACS catalysis (04-03-2016)“…This Perspective describes general methods for the preparation of polyfunctional zinc organometallics and their use in Negishi cross-coupling reactions. Recent…”
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5
Cobalt-Catalyzed Negishi Cross-Coupling Reactions of (Hetero)Arylzinc Reagents with Primary and Secondary Alkyl Bromides and Iodides
Published in Angewandte Chemie International Edition (07-04-2015)“…We report a cobalt‐catalyzed cross‐coupling of di(hetero)arylzinc reagents with primary and secondary alkyl iodides or bromides using THF‐soluble CoCl2⋅2 LiCl…”
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6
A Robust and Broadly Applicable Cobalt‐Catalyzed Cross‐Coupling of Functionalized Bench‐Stable Organozinc Pivalates with Unsaturated Halides
Published in Angewandte Chemie International Edition (19-01-2017)“…We report a robust and broadly applicable CoCl2‐catalyzed cross‐coupling between functionalized aryl and heteroaryl zinc pivalates and various electron‐poor…”
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7
Cobalt‐Catalyzed Cross‐Coupling of Functionalized Alkylzinc Reagents with (Hetero)Aryl Halides
Published in Angewandte Chemie International Edition (27-03-2020)“…A combination of 10 % CoCl2 and 20 % 2,2′‐bipyridine ligands enables cross‐coupling of functionalized primary and secondary alkylzinc reagents with various…”
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8
Mild Cobalt-Catalyzed Negishi Cross-Couplings of (Hetero)arylzinc Reagents with (Hetero)aryl Halides
Published in Angewandte Chemie International Edition (07-03-2016)“…A catalytic system consisting of CoCl2⋅2 LiCl (5 mol %) and HCO2Na (50 mol %) enables the cross‐coupling of various N‐heterocyclic chlorides and bromides as…”
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9
Cobalt-Catalyzed C(sp2)–C(sp3) Cross-Coupling Reactions of Diarylmanganese Reagents with Secondary Alkyl Iodides
Published in Organic letters (16-12-2016)“…A cobalt-catalyzed cross-coupling of diarylmanganese reagents with secondary alkyl iodides using the THF-soluble salt CoCl2·2LiCl, which leads to the…”
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10
Practical Ni-Catalyzed Cross-Coupling of Unsaturated Zinc Pivalates with Unsaturated Nonaflates and Triflates
Published in Organic letters (04-01-2019)“…A practical nickel-catalyzed cross-coupling of (hetero)aryl or alkynylzinc pivalates with various unsaturated nonaflates or triflates is described. Organozinc…”
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11
Cobalt-Catalyzed Cross-Couplings of Bench-Stable Alkynylzinc Pivalates with (Hetero)Aryl and Alkenyl Halides
Published in Organic letters (21-07-2017)“…A catalytic system consisting of CoCl2·2LiCl and TMEDA enables the cross-coupling of various electron-poor aryl and heteroaryl halides with various alkynylzinc…”
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12
Cobalt-Mediated Diastereoselective Cross-Coupling Reactions between Cyclic Halohydrins and Arylmagnesium Reagents
Published in Organic letters (19-12-2014)“…Cyclic TBS-protected iodohydrins (and bromohydrins) undergo a highly diastereoselective cross-coupling with various aryl- and heteroarylmagnesium reagents in…”
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13
Diastereoselective Cobalt-Mediated Cross-Couplings of Cycloalkyl Iodides with Alkynyl or (Hetero)Aryl Grignard Reagents
Published in Organic letters (07-10-2016)“…A highly diastereoselective cross-coupling of variously substituted cycloalkyl iodides with alkynyl and (hetero)aryl Grignard reagents using cobalt(II)…”
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14
Oxidant-controlled regioselectivity in the oxidative arylation of N-acetylindoles
Published in Tetrahedron letters (16-06-2008)“…N-Acetylindoles can be oxidatively coupled with arenes such as benzene or pentafluorobenzene in dioxane. The use of Cu(OAc) 2 as the stoichiometric oxidant…”
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15
Bis(pyrazolyl)methane Copper Complexes as Robust and Efficient Catalysts for Sonogashira Couplings
Published in European journal of organic chemistry (01-12-2015)“…A series of bis(pyrazolyl)methane copper complexes were found to catalyze a fast palladium‐free Sonogashira coupling reaction of several iodoarenes with…”
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16
Cobalt‐katalysierte Kreuzkupplung funktionalisierter Alkylzinkreagenzien mit (Hetero‐)Arylhalogeniden
Published in Angewandte Chemie (27-03-2020)“…Eine Kombination aus 10 % CoCl2 und 20 % 2,2′‐Bipyridin als Liganden ermöglicht die Kreuzkupplung von funktionalisierten primären und sekundären…”
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17
A Robust and Broadly Applicable Cobalt‐Catalyzed Cross‐Coupling of Functionalized Bench‐Stable Organozinc Pivalates with Unsaturated Halides
Published in Angewandte Chemie (19-01-2017)“…We report a robust and broadly applicable CoCl2‐catalyzed cross‐coupling between functionalized aryl and heteroaryl zinc pivalates and various electron‐poor…”
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18
Invasion success of the seaweed Gracilaria vermiculophylla correlates with low palatibility
Published in Marine ecology. Progress series (Halstenbek) (12-07-2013)“…Differences with respect to anti-herbivore defense were investigated in invasive and native populations of the seaweed Gracilaria vermiculophylla. Specimens…”
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19
Age and growth of totoaba, Totoaba macdonaldi (Sciaenidae), in the upper Gulf of California
Published in Fishery bulletin (Washington, D.C.) (01-07-1997)“…The totoaba, Totoaba macdonaldi (Gilbert), also known as Mexican giant bass, is found only in the Gulf of California. This species during 1934-45 supported one…”
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20
Cobalt-katalysierte Negishi-Kreuzkupplungen von (Hetero)Arylzinkreagentien mit primären und sekundären Alkylbromiden und -iodiden
Published in Angewandte Chemie (07-04-2015)“…Abstract Wir berichten über eine Cobalt‐katalysierte Kreuzkupplung von Di(hetero)arylzinkreagentien mit primären und sekundären Alkyliodiden und ‐bromiden…”
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