Search Results - "Halbach, Robert L."

Structurally characterized terminal manganese(iv) oxo tris(alkoxide) complex by Halbach, Robert L, Gygi, David, Bloch, Eric D, Anderson, Bryce L, Nocera, Daniel G

“…A Mn(iv) complex featuring a terminal oxo ligand, [Mn (O)(ditox) ][K(15-C-5) ] ( ; ditox = Bu MeCO , 15-C-5 = 15-crown-5-ether) has been isolated and…”
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Oxygen Reduction Mechanism of Monometallic Rhodium Hydride Complexes by Halbach, Robert L, Teets, Thomas S, Nocera, Daniel G

“…The reduction of O2 to H2O mediated by a series of electronically varied rhodium hydride complexes of the form cis,trans-RhIIICl2H­(CNAd)­(P­(4-X-C6H4)3)2 (2)…”
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Modulation of Phenol Oxidation in Cofacial Dyads by Koo, Bon Jun, Huynh, Michael, Halbach, Robert L, Stubbe, JoAnne, Nocera, Daniel G

“…The presentation of two phenols on a xanthene backbone is akin to the tyrosine dyad (Y730 and Y731) of ribonucleotide reductase. X-ray crystallography reveals…”
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Photophysical Properties of β‑Substituted Free-Base Corroles by Lemon, Christopher M, Halbach, Robert L, Huynh, Michael, Nocera, Daniel G

“…Corroles are an emergent class of fluorophores that are finding an application and reaction chemistry to rival their porphyrin analogues. Despite a growing…”
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Cerium Tetrakis(tropolonate) and Cerium Tetrakis(acetylacetonate) Are Not Diamagnetic but Temperature-Independent Paramagnets by Halbach, Robert L, Nocton, Grégory, Booth, Corwin H, Maron, Laurent, Andersen, Richard A

“…A new synthesis of cerium tetrakis­(tropolonate), Ce­(trop)4, where trop is deprotonated 2-hydroxy-2,4,6-cycloheptatrienone) or Ce­(O2C7H5)4, is developed that…”
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Hydrogen Evolution Catalysis by a Sparsely Substituted Cobalt Chlorin by Maher, Andrew G, Passard, Guillaume, Dogutan, Dilek K, Halbach, Robert L, Anderson, Bryce L, Gagliardi, Christopher J, Taniguchi, Masahiko, Lindsey, Jonathan S, Nocera, Daniel G

“…A sparsely substituted chlorin macrocycle containing a Co­(II) center (1-Co) has been synthesized and structurally characterized. The Co­(II) atom resides in a…”
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Understanding the Multiconfigurational Ground and Excited States in Lanthanide Tetrakis Bipyridine Complexes from Experimental and CASSCF Computational Studies by Halbach, Robert L, Nocton, Grégory, Amaro-Estrada, Jorge I, Maron, Laurent, Booth, Corwin H, Andersen, Richard A

“…An alternative synthesis for M­(κ2-bipy)4 (M = La, Ce) and [Li­(thf)4]­[M­(κ2-bipy)4] (M = Tb, Dy) and the crystal structures for M = La, Ce, and Tb are…”
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Correction to Cerium Tetrakis(tropolonate) and Cerium Tetrakis(acethylacetonate) Are Not Diamagnetic but Temperature-Independent Paramagnets by Halbach, Robert L, Nocton, Grégory, Booth, Corwin H, Maron, Laurent, Andersen, Richard A

“…© 2018 American Chemical Society. Page 7295. In the Summary section of the article, the text should read "The energy of the closed-shell singlet that…”
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Synthesis, Structural Studies, and Application of Aluminum Aryloxides for Ring-Opening Metathesis Polymerization by Halbach, Robert L., Dupper, Torin, López-Barrón, Carlos R., Kang, Shuhui, Mattler, Sarah J., Luo, Lubin, Zabula, Alexander V.

“…A series of aluminum aryloxides of types [Al­(OAr)3] and [Al­(OAr)2Cl] (Ar = 4-CH3C6H4, 4-PhC6H4, 2-iPr-C6H4, 2-tBu-C6H4, 2,6-iPr2C6H3, and 2,6-Cl2C6H3) were…”
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Cerium Tetrakis(tropolonate) and Cerium Tetrakis(acethylacetonate) Are Not Diamagnetic but Temperature-Independent Paramagnets (vol 57, pg 7290, 2018) by Halbach, Robert L., Nocton, Grégory, Booth, Corwin H., Maron, Laurent, Andersen, Richard A.

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Structurally characterized terminal manganese(iv) oxo tris(alkoxide) complexElectronic supplementary information (ESI) available: Single crystal X-ray diffraction data; ESI-MS spectra and data: IR spectra; and magnetic data. CCDC 1829119-1829121. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01164h by Halbach, Robert L, Gygi, David, Bloch, Eric D, Anderson, Bryce L, Nocera, Daniel G

“…A Mn( iv ) complex featuring a terminal oxo ligand, [Mn IV (O)(ditox) 3 ][K(15-C-5) 2 ] ( 3 ; ditox = t Bu 2 MeCO − , 15-C-5 = 15-crown-5-ether) has been…”
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Structurally characterized terminal manganese(iv) oxo tris(alkoxide) complex† †Electronic supplementary information (ESI) available: Single crystal X-ray diffraction data; ESI-MS spectra and data: IR spectra; and magnetic data. CCDC 1829119–1829121. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01164h by Halbach, Robert L., Gygi, David, Bloch, Eric D., Anderson, Bryce L., Nocera, Daniel G.

“…First structurally characterized Mn( iv ) oxo. A Mn( iv ) complex featuring a terminal oxo ligand, [Mn IV (O)(ditox) 3 ][K(15-C-5) 2 ] ( 3 ; ditox = t Bu 2…”
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Hydrogen Evolution Catalysis by a Sparsely Substituted Cobalt Chlorin by Maher, Andrew G., Passard, Guillaume, Dogutan, Dilek K., Halbach, Robert L., Anderson, Bryce L., Gagliardi, Christopher J., Taniguchi, Masahiko, Lindsey, Jonathan S., Nocera, Daniel G.

“…Here, a sparsely substituted chlorin macrocycle containing a Co(II) center (1-Co) has been synthesized and structurally characterized. The Co(II) atom resides…”
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