Search Results - "Hadi, Jebril"
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Eighteen years of steel–bentonite interaction in the FEBEX in situ test at the Grimsel Test Site in Switzerland
Published in Clays and clay minerals (15-04-2019)“…ABSTRACT Corrosion of steel canisters containing buried high-level radioactive waste is a relevant issue for the long-term integrity of repositories. The…”
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Determination of Sulfide Consumption by Fe-bearing Components of Bentonites
Published in Clays and clay minerals (01-10-2023)“…Geologic repositories for spent nuclear fuel use bentonite as a buffer to protect the metallic containers confining the radioactive material. Sulfate-reducing…”
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Mössbauer spectrometry insights into the redox reactivity of Fe-bearing phases in the environment
Published in Journal of materials research (28-02-2023)“…Rates and mechanisms of important reactions in the cycling of electrons via the geochemical transformations of iron have been identified using Mössbauer…”
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Unravelling the corrosion processes at steel/bentonite interfaces in in situ tests
Published in Materials and corrosion (01-11-2023)“…Microscopic and spectroscopic analyses were conducted on steel/bentonite interface samples removed from four in situ experiments that were carried out in three…”
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Interaction of Corroding Iron with Eight Bentonites in the Alternative Buffer Materials Field Experiment (ABM2)
Published in Minerals (Basel) (01-08-2021)“…Bentonite, a common smectite-rich buffer material, is in direct contact with corroding steel in many high-level radioactive waste repository designs. The…”
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A novel and easy chemical-clock synthesis of nanocrystalline iron–cobalt bearing layered double hydroxides
Published in Journal of colloid and interface science (15-11-2014)“…[Display omitted] •Hexaamminecobalt trichloride reacts spontaneously with ferrous chloride in anoxic conditions.•A dramatic color change of the solution is…”
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Pitfalls in using the hexaamminecobalt method for cation exchange capacity measurements on clay minerals and clay-rocks: Redox interferences between the cationic dye and the sample
Published in Applied clay science (01-01-2016)“…Using cationic dyes, such as hexaamminecobalt trichloride (CoHex), is a popular method for measuring clay minerals' cation exchange capacity (CEC), because a…”
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Geochemistry and palaeo-hydrogeology of the weathered zone in the Opalinus Clay
Published in Applied clay science (01-02-2023)“…The effects of weathering and decompaction on the Opalinus Clay in northern Switzerland were studied on the basis of a 146 m long drillcore profile. Below 6 m…”
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Modelling CEC variations versus structural iron reduction levels in dioctahedral smectites. Existing approaches, new data and model refinements
Published in Journal of colloid and interface science (01-10-2013)“…•New measurements of nontronite negative layer charge versus structural Fe reduction.•Nontronite negative layer charge can decrease upon intense structural Fe…”
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Enhanced heterotrophic denitrification in clay media: The role of mineral electron donors
Published in Chemical geology (18-12-2014)“…Denitrification is expected to occur at and near the interface with clayey formations dedicated to radioactive waste disposal, due to the nitrate content in…”
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Geochemical characterization and modelling of the Toarcian/Domerian porewater at the Tournemire underground research laboratory
Published in Applied geochemistry (01-07-2012)“…► A suitable model missed to obtain the porewater composition of Tournemire argillite. ► Fine geochemical experimental characterization of water–clay system is…”
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