Search Results - "HOPE, Eric G"
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Bis-Cyclometalation of Fluorinated N-Aryl NHCs
Published in Organometallics (27-02-2012)“…The new imidazolium salts N,N′-bisfluoroarylimidazolium chloride (fluoroaryl = 4-fluorophenyl (1), 2,4-difluorophenyl (2), 2,4,6-trifluorophenyl (3)) have been…”
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2
Intramolecular Fluorocyclizations of Unsaturated Carboxylic Acids with a Stable Hypervalent Fluoroiodane Reagent
Published in Angewandte Chemie International Edition (01-12-2015)“…A new class of fluorinated lactones was prepared by the intramolecular fluorocyclizations of unsaturated carboxylic acids by using the stable fluoroiodane…”
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3
Effect of Electrolyte Concentration on the Viscosity and Voltammetry of Supercritical Solutions
Published in Analytical chemistry (Washington) (15-10-2005)“…The viscosity of a supercritical electrolyte solution is measured for the first time using a modified quartz crystal microbalance, and it is shown that ionic…”
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4
Complexes of molybdenum(VI) oxide tetrafluoride and molybdenum(VI) dioxide difluoride with neutral N- and O-donor ligands
Published in Journal of fluorine chemistry (01-08-2017)“…[Display omitted] •First examples of MoOF4 complexes with neutral ligands.•X-ray structure of [MoOF4(Ph3PO)].•Comparisons of [MoOF4(L)] and [MoO2F2(L)2]…”
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5
Synthesis of fluoroalkyl-derivatised BINAP ligands
Published in Tetrahedron letters (26-11-2001)“…Fluoroalkyl-derivatised R-BINAP ligands have been prepared, characterised and applied in the ruthenium-catalysed asymmetric hydrogenation of dimethyl…”
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6
Active O,Npy,N-Titanium(IV) Fluoride Precatalysts for Ethylene Polymerization: Exploring “Fluoride Effects” on Polymer Properties and Catalytic Performance
Published in Organometallics (09-05-2016)“…Three examples of discrete six-coordinate O,Npy,N-bearing titanium(IV) trifluoride complexes, [{2-(C5H4N)-6-(CMe2O)C5H3N}TiF3] (1),…”
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7
A recyclable perfluoroalkylated PCP pincer palladium complex
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2011)“…A new fluorous PCP pincer ligand has been coordinated to Ni(II), Pd(II) and Pt(II). The air stable palladium complex, which promotes Heck reactions between…”
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8
Insoluble Perfluoroalkylated Polymers: New Solid Supports for Supported Fluorous Phase Catalysis
Published in Advanced synthesis & catalysis (10-09-2010)“…New perfluoroalkylated polystyrene resins have been prepared by the suspension polymerisation of 4‐(perfluoro‐n‐octyl)styrene. The evaluation of these highly…”
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9
Fluorous biphase catalysis
Published in Journal of fluorine chemistry (01-12-1999)“…The evolution and future prospects for the fluorous biphase approach to homogeneous catalysis are discussed…”
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10
Supported Fluorous Phase Catalysis on PTFE, Fluoroalkylated Micro- and Meso-porous Silica
Published in Advanced synthesis & catalysis (01-08-2006)“…New perfluoroalkylated micro‐ and mesoporous silica, along with powdered Teflon, have been evaluated as solid supports for supported fluorous phase catalysis…”
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11
Intramolecular Fluorocyclizations of Unsaturated Carboxylic Acids with a Stable Hypervalent Fluoroiodane Reagent
Published in Angewandte Chemie (01-12-2015)“…A new class of fluorinated lactones was prepared by the intramolecular fluorocyclizations of unsaturated carboxylic acids by using the stable fluoroiodane…”
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12
Effect of Solutes on the Viscosity of Supercritical Solutions
Published in The journal of physical chemistry. B (19-07-2007)“…This study shows that solutes can impart significant structure to supercritical solutions, resulting in unexpectedly high solution viscosity at pressures close…”
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13
Probing Solute Clustering in Supercritical Solutions Using Solvatochromic Parameters
Published in The journal of physical chemistry. B (19-07-2007)“…Kamlet and Taft polarity parameters are presented for three supercritical solutions containing solutes of different polarities at two concentrations. It is…”
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14
Synthesis, properties, and multinuclear NMR (125Te{1H}, 13C{1H}, 1H) studies in di- and polytelluroether ligands
Published in Organometallics (01-01-1988)Get full text
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15
Hydroformylation in perfluorinated solvents; improved selectivity, catalyst retention and product separation
Published in Tetrahedron (13-05-2002)“…The hydroformylation of linear terminal alkenes using rhodium based catalysts under fluorous biphasic conditions in the presence and absence of toluene is…”
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16
Coordination chemistry of the noble gases and noble gas fluorides
Published in Coordination chemistry reviews (01-03-2013)“…► The first combined survey of metal-noble gas and metal-noble gas fluoride complexes. ► Recent developments in organometallic noble gas complexes in an…”
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Ruthenium-catalysed asymmetric hydrogenation with fluoroalkylated BINAP ligands in supercritical CO2
Published in Journal of molecular catalysis. A, Chemical (01-09-2004)Get full text
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18
Hydroformylation in fluorous solvents
Published in Journal of organometallic chemistry (15-04-2004)“…The hydroformylation of long chain alkenes under fluorous biphase conditions and in neat perfluorocarbon solvents is reviewed, with emphasis on the steric and…”
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19
Polymer modification using difluoromethane (HFC 32) and carbon dioxide
Published in Journal of polymer science. Part B, Polymer physics (01-04-2006)“…The infusion of difluoromethane (HFC 32) and CO2 into polystyrene and polyethylene has been characterized using a quartz crystal microbalance technique over a…”
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20
Towards the synthesis of perfluoroalkylated derivatives of Xantphos
Published in Tetrahedron (26-04-2004)“…An analogue of Xantphos incorporating four perfluoroalkyl groups has been prepared and successfully used as a ligand in the rhodium-catalysed hydroformylation…”
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