Search Results - "HICKEY, David P"
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A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms
Published in Chemical science (Cambridge) (14-07-2019)“…Monitoring reactive intermediates can provide vital information in the study of synthetic reaction mechanisms, enabling the design of new catalysts and…”
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2
Parameterization of phosphine ligands reveals mechanistic pathways and predicts reaction outcomes
Published in Nature chemistry (01-06-2016)“…The mechanistic foundation behind the identity of a phosphine ligand that best promotes a desired reaction outcome is often non-intuitive, and thus has been…”
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Scalable and safe synthetic organic electroreduction inspired by Li-ion battery chemistry
Published in Science (American Association for the Advancement of Science) (22-02-2019)“…Reductive electrosynthesis has faced long-standing challenges in applications to complex organic substrates at scale. Here, we show how decades of research in…”
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A self-powered amperometric lactate biosensor based on lactate oxidase immobilized in dimethylferrocene-modified LPEI
Published in Biosensors & bioelectronics (15-03-2016)“…Lactate is an important biomarker due to its excessive production by the body during anerobic metabolism. Existing methods for electrochemical lactate…”
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5
Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications
Published in Journal of the American Chemical Society (17-04-2019)“…C–N cross-coupling is one of the most valuable and widespread transformations in organic synthesis. Largely dominated by Pd- and Cu-based catalytic systems, it…”
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6
Rational design of quinones for high power density biofuel cells
Published in Chemical science (Cambridge) (01-08-2015)“…Enzymatic fuel cells (EFCs) are devices that can produce electrical energy by enzymatic oxidation of energy-dense fuels (such as glucose). When considering…”
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7
Hybrid Enzymatic and Organic Electrocatalytic Cascade for the Complete Oxidation of Glycerol
Published in Journal of the American Chemical Society (12-11-2014)“…We demonstrate the complete electrochemical oxidation of the biofuel glycerol to CO2 using a hybrid enzymatic and small-molecule catalytic system. Combining an…”
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8
Understanding Biophotocurrent Generation in Photosynthetic Purple Bacteria
Published in ACS catalysis (01-02-2019)“…Establishing an efficient extracellular electron transfer (EET) process between photoelectroactive microorganisms and an electrode surface is critical for the…”
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Predicting Electrocatalytic Properties: Modeling Structure–Activity Relationships of Nitroxyl Radicals
Published in Journal of the American Chemical Society (30-12-2015)“…Stable nitroxyl radical-containing compounds, such as 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) and its derivatives, are capable of electrocatalytically…”
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10
Establishing a Thermodynamic Landscape for the Active Site of Mo-Dependent Nitrogenase
Published in Journal of the American Chemical Society (30-10-2019)“…Nitrogenase enzymes are the only biological catalysts able to convert N2 to NH3. Molybdenum-dependent nitrogenase consists of two proteins and three…”
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11
Creation of a point-of-care therapeutics sensor using protein engineering, electrochemical sensing and electronic integration
Published in Nature communications (24-02-2024)“…Point-of-care sensors, which are low-cost and user-friendly, play a crucial role in precision medicine by providing quick results for individuals. Here, we…”
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Membraneless enzymatic ethanol/O2 fuel cell: Transitioning from an air-breathing Pt-based cathode to a bilirubin oxidase-based biocathode
Published in Journal of power sources (30-08-2016)“…The bioelectrooxidation of ethanol was investigated in a fully enzymatic membraneless ethanol/O2 biofuel cell assembly using hybrid bioanodes containing…”
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13
Modeling Carbon Nanotube Connectivity and Surface Activity in a Contact Lens Biofuel Cell
Published in Electrochimica acta (10-06-2016)“…[Display omitted] Biofuel cells are often limited by the current density produced by the cathode; this is especially true when such fuel cells are scaled down…”
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Bioinspired architecture of a hybrid bifunctional enzymatic/organic electrocatalyst for complete ethanol oxidation
Published in Bioelectrochemistry (Amsterdam, Netherlands) (01-12-2019)“…Electrochemical ethanol oxidation was performed at an innovative hybrid architecture electrode containing TEMPO-modified linear poly(ethylenimine) (LPEI) and…”
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Electrochemical Characterization of Glucose Bioanodes Based on Tetramethylferrocene-Modified Linear Poly(ethylenimine)
Published in Electrochimica acta (10-12-2014)“…Tetramethylferrocene-modified linear(polyethylenimine) (FcMe4-C3-LPEI) was cross-linked with ethylene glycol diglycidyl ether (EGDGE) in the presence of…”
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16
Coupling Theory to Electrode Design for Electrocatalysis
Published in ACS central science (22-05-2019)“…Predicting the thermochemistry of interfacial proton-coupled electron-transfer reactions…”
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Model-Driven Design of Redox Mediators: Quantifying the Impact of Quinone Structure on Bioelectrocatalytic Activity with Glucose Oxidase
Published in The journal of physical chemistry. B (14-09-2023)“…Successful application of emerging bioelectrocatalysis technologies depends upon an efficient electrochemical interaction between redox enzymes as biocatalysts…”
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Electrochemical ammonia production from nitrates in agricultural tile drainage: Technoeconomic and global warming analysis
Published in AIChE journal (01-02-2023)“…Nitrates from agricultural wastewater are harmful to human health and result in eutrophication. Several emerging electrochemical technologies have been…”
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Impact of sodium pyruvate on the electrochemical reduction of NAD + biomimetics
Published in Faraday discussions (31-10-2023)“…Biomimetics of nicotinamide adenine dinucleotide (mNADH) are promising cost-effective alternatives to their natural counterpart for biosynthetic applications;…”
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Creating a Low‐Potential Redox Polymer for Efficient Electroenzymatic CO2 Reduction
Published in Angewandte Chemie International Edition (28-05-2018)“…Increasing greenhouse gas emissions have resulted in greater motivation to find novel carbon dioxide (CO2) reduction technologies, where the reduction of CO2…”
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