Search Results - "HERNANDEZ, Olivier"
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Perovskite-Type CuNbO3 Exhibiting Unusual Noncollinear Ferrielectric to Collinear Ferroelectric Dipole Order Transition
Published in Chemistry of materials (23-06-2020)“…We report a perovskite oxide with a new type of polar structure, CuNbO3, thanks to the use of high-pressure and high-temperature synthesis. The perovskite-type…”
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Hybrid Improper Ferroelectricity in (Sr,Ca)3Sn2O7 and Beyond: Universal Relationship between Ferroelectric Transition Temperature and Tolerance Factor in n = 2 Ruddlesden–Popper Phases
Published in Journal of the American Chemical Society (21-11-2018)“…Hybrid improper ferroelectricity, which utilizes nonpolar but ubiquitous rotational/tilting distortions to create polarization, offers an attractive route to…”
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Ferroelectric Sr3Zr2O7: Competition between Hybrid Improper Ferroelectric and Antiferroelectric Mechanisms
Published in Advanced functional materials (25-07-2018)“…In contrast to polar cation displacements driving oxides into noncentrosymmetric and ferroelectric states, inversion‐preserving anion displacements, such as…”
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An oxyhydride of BaTiO3 exhibiting hydride exchange and electronic conductivity
Published in Nature materials (15-04-2012)“…The substitution of oxygen by hydride anions in oxide materials to form oxyhydrides has been difficult to achieve because it requires highly reducing…”
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New chemistry of transition metal oxyhydrides
Published in Science and technology of advanced materials (31-12-2017)“…In this review we describe recent advances in transition metal oxyhydride chemistry obtained by topochemical routes, such as low temperature reduction with…”
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Mechanochemical Synthesis and Study of the Local Structure of NaGaS2 Glass and Glass–Ceramics
Published in Inorganic chemistry (21-11-2022)“…NaGaS2 is a newly discovered compound that has already shown great promise for a variety of applications because of its layered structure and ion exchange…”
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Comprehensive Study of Oxygen Storage in YbFe2O4+x (x ≤ 0.5): Unprecedented Coexistence of FeOn Polyhedra in One Single Phase
Published in Journal of the American Chemical Society (29-11-2017)“…The multiferroic LuFe2.5+2O4 was recently proposed as a promising material for oxygen storage due to its easy reversible oxidation into LuFe3+2O4.5. We have…”
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In Situ Synchrotron Powder Diffraction Study of Cd Intercalation into Chevrel Phases: Crystal Structure and Kinetic Effect
Published in Inorganic chemistry (04-02-2019)“…Chevrel phases are molybdenum chalcogenides of formula M x Mo6X8 (where M is a cation and X is a chalcogen) that present a complex and captivating…”
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Site Selectivity of Hydride in Early-Transition-Metal Ruddlesden–Popper Oxyhydrides
Published in Inorganic chemistry (04-09-2018)“…Layered perovskite titanium oxyhydrides have been prepared by low-temperature topochemical CaH2 reduction from Ruddlesden–Popper Sr n+1Ti n O3n+1 phases (n =…”
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Kinemetry of SINS High-Redshift Star-Forming Galaxies: Distinguishing Rotating Disks from Major Mergers
Published in The Astrophysical journal (20-07-2008)“…We present a simple set of kinematic criteria that can distinguish between galaxies dominated by ordered rotational motion and those involved in major merger…”
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Lattice Dynamics To Trigger Low Temperature Oxygen Mobility in Solid Oxide Ion Conductors
Published in Journal of the American Chemical Society (26-11-2008)“…SrFeO2.5 and SrCoO2.5 are able to intercalate oxygen in a reversible topotactic redox reaction already at room temperature to form the cubic perovskites…”
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Gas phase contributions to topochemical hydride reduction reactions
Published in Journal of solid state chemistry (01-11-2013)“…Alkali and alkali earth hydrides have been used as solid state reductants recently to yield many interesting new oxygen-deficient transition metal oxides…”
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13
Reduction of Sr2MnO4 Investigated by High Temperature in Situ Neutron Powder Diffraction under Hydrogen Flow
Published in Inorganic chemistry (18-01-2013)“…This experiment emphasizes the first example of two-phase sequential Rietveld refinements throughout a solid/gas chemical reaction monitored by Neutron Powder…”
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Unprecedented Electron-Poor Octahedral Ta6 Clusters in a Solid-State Compound: Synthesis, Characterisations and Theoretical Investigations of Cs2BaTa6Br15O3
Published in Chemistry : a European journal (16-09-2013)“…The crystal structure of Cs2BaTa6Br15O3 has been elucidated by using synchrotron X‐ray powder diffraction and absorption experiments. It is built from…”
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Self-Assembly of Ambivalent Organic/Inorganic Building Blocks Containing Re6 Metal Atom Cluster: Formation of a Luminescent Honeycomb, Hollow, Tubular Metal-Organic Framework
Published in Inorganic chemistry (16-02-2009)“…Reactions in a sealed glass tube between melted pyrazine (pyz) and a Cs3Re6Qi 7BriBra 6·H2O inorganic rhenium cluster compound (Q = S, Se; “i” for inner and…”
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Density Functional Theory Study of Triphenyl Phosphite: Molecular Flexibility and Weak Intermolecular Hydrogen Bonding
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-08-2007)“…The high conformational flexibility of triphenyl phosphite (TPP) is investigated by density functional theory (DFT) calculations. First, through a scan of the…”
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Tetrahedral Mo4 Clusters as Building Blocks for the Design of Clathrate-Related Giant Frameworks
Published in Angewandte Chemie International Edition (01-08-2011)“…Cluster‐based clathrate: Mo4Si4Cla12 inorganic building blocks (see picture, i=inner, a=apical) containing Mo4 metal atom clusters assemble to yield an…”
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Micro-structural investigations in the glacial state of triphenyl phosphite
Published in Journal of non-crystalline solids (15-11-2006)“…A detailed structural description of the glacial state in triphenyl phosphite, based on Raman microspectroscopy investigations and a complementary structural…”
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Journal Article Conference Proceeding -
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Rotationally disordered phase of 1,3-dibromo-5-iodo-2,4,6-trimethylbenzene at 293 K
Published in Acta crystallographica. Section C, Crystal structure communications (01-10-2009)“…In the crystal state at room temperature, the molecule of dibromoiodomesitylene (1,3‐dibromo‐5‐iodo‐2,4,6‐trimethylbenzene), C9H9Br2I, is prone to strong…”
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Unusual Coexistence of Magnetic and Nonmagnetic Mo6 Octahedral Clusters in a Chalcohalide Solid Solution: Synthesis, X-ray Diffraction, EPR, and DFT Investigations of Cs3Mo6Ii6Ii2−xSeixIa6
Published in Chemistry : a European journal (26-11-2007)“…The Cs3Mo6Ii6Ii2−xSeixIa6 series has been obtained by a solid‐state route. There is evidence for a solid solution between the compositions…”
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