Search Results - "HANSMANN, M"
-
1
Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene
Published in Journal of the American Chemical Society (14-12-2016)“…(Phosphino)phosphaketenes (>PPCO) behave as (phosphino)phosphinidene-carbonyl adducts (>PP←:CO). CO scrambling was observed using 13C labeled CO, and…”
Get full text
Journal Article -
2
Singlet (Phosphino)phosphinidenes are Electrophilic
Published in Journal of the American Chemical Society (13-07-2016)“…A room-temperature stable (phosphino)-phosphinidene reacts with carbon monoxide, stable singlet carbenes, including the poor π-accepting imidazol-2-ylidene,…”
Get full text
Journal Article -
3
Gene expression profiling of isolated tumour cells from anaplastic large cell lymphomas: insights into its cellular origin, pathogenesis and relation to Hodgkin lymphoma
Published in Leukemia (01-11-2009)“…Anaplastic large cell lymphoma (ALCL) is a main type of T-cell lymphomas and comprises three distinct entities: systemic anaplastic lymphoma kinase (ALK)…”
Get full text
Journal Article -
4
Mechanistic Switch in Dual Gold Catalysis of Diynes: C(sp3)-H Activation through Bifurcation-Vinylidene versus Carbene Pathways
Published in Angewandte Chemie International Edition (25-02-2013)“…The other side of the mountain: Changing the framework of diyne systems opens up new cyclization modes for dual gold catalysis. Instead of a 5‐endo cyclization…”
Get full text
Journal Article -
5
Highly recurrent mutations of SGK1, DUSP2 and JUNB in nodular lymphocyte predominant Hodgkin lymphoma
Published in Leukemia (01-04-2016)“…Nodular lymphocyte predominant Hodgkin lymphoma (NLPHL)—a subtype of Hodgkin lymphoma (HL)—is characterized by a low content of tumor cells, the lymphocyte…”
Get full text
Journal Article -
6
Isolation and reactivity of an elusive diazoalkene
Published in Nature chemistry (01-06-2021)“…Most functional groups, especially those consisting of the abundant elements of organic matter—carbon, nitrogen and oxygen—have been extensively studied and…”
Get full text
Journal Article -
7
Singlet Fission in Carbene‐Derived Diradicaloids
Published in Angewandte Chemie International Edition (11-05-2020)“…Herein, we present a new class of singlet fission (SF) materials based on diradicaloids of carbene scaffolds, namely cyclic (alkyl)(amino)carbenes (CAACs). Our…”
Get full text
Journal Article -
8
Dysregulation of global microRNA expression in splenic marginal zone lymphoma and influence of chronic hepatitis C virus infection
Published in Leukemia (01-07-2012)“…The precise molecular pathogenesis of splenic marginal zone lymphoma (SMZL) is still unknown. Clinical and epidemiological data suggest that chronic hepatitis…”
Get full text
Journal Article -
9
Synthesis of Highly Substituted 3-Formylfurans by a Gold(I)-Catalyzed Oxidation/1,2-Alkynyl Migration/Cyclization Cascade
Published in Angewandte Chemie International Edition (01-04-2014)“…3‐Formylfuran derivatives are core structures of a variety of bioactive natural products. However, procedures for their preparation are still rare and…”
Get full text
Journal Article -
10
Gold-Catalyzed Cyclization of Diynes: Controlling the Mode of 5-endo versus 6-endo Cyclization-An Experimental and Theoretical Study by Utilizing Diethynylthiophenes
Published in Chemistry : a European journal (17-02-2014)“…Herein, a dual‐gold catalyzed cyclization of 3,4‐diethynylthiophenes generating pentaleno[c]thiophenes through gold–vinylidenes and CH bond activation is…”
Get full text
Journal Article -
11
Different biological risk factors in young poor-prognosis and elderly patients with diffuse large B-cell lymphoma
Published in Leukemia (01-07-2015)“…Prognostically relevant risk factors in patients with diffuse large B-cell lymphoma (DLBCL) have predominantly been evaluated in elderly populations. We tested…”
Get full text
Journal Article -
12
Intercepting a Transient Phosphino‐Arsinidene
Published in Chemistry : a European journal (05-07-2018)“…A phosphino‐arsinidene derived from a diazaphospholidine scaffold (Ar**NCH2)2PAs (where Ar**=2,6‐bis[(4‐tert‐butylphenyl)methyl]‐4‐methylphenyl) was generated…”
Get full text
Journal Article -
13
Role of early B-cell factor 1 (EBF1) in Hodgkin lymphoma
Published in Leukemia (01-03-2013)“…A hallmark of classical Hodgkin lymphoma (cHL) is that the B-cell-derived Hodgkin and Reed–Sternberg (HRS) tumor cells have largely lost the B-cell-typical…”
Get full text
Journal Article -
14
An oncogenic axis of STAT-mediated BATF3 upregulation causing MYC activity in classical Hodgkin lymphoma and anaplastic large cell lymphoma
Published in Leukemia (01-01-2018)“…Classical Hodgkin lymphoma (cHL) and anaplastic large cell lymphoma (ALCL) feature high expression of activator protein-1 (AP-1) transcription factors, which…”
Get full text
Journal Article -
15
New Pathways for the Dual Gold-Catalyzed Cyclization of Diynes
Published in Chemistry : a European journal (02-11-2016)“…The reaction of thiophene‐based diynes with dual‐activation gold catalysts can provide cyclobutene derivatives or different polycycles by selective C−H…”
Get full text
Journal Article -
16
Intramolecular anti‐Phosphinoauration of Alkynes: An FLP‐Motivated Approach to Stable Aurated Phosphindolium Complexes
Published in Chemistry : a European journal (21-02-2017)“…The synthesis of aurated phosphindolium complexes from easy accessible 1,5‐alkynylphosphine derivatives has been studied by using gold(I) complexes featuring…”
Get full text
Journal Article -
17
Re-activation of mitochondrial apoptosis inhibits T-cell lymphoma survival and treatment resistance
Published in Leukemia (01-07-2016)“…T lymphocyte non-Hodgkin's lymphoma (T-NHL) represents an aggressive and largely therapy-resistant subtype of lymphoid malignancies. As deregulated apoptosis…”
Get full text
Journal Article -
18
Gold-Catalyzed Formal 1,6-Acyloxy Migration Leading to 3,4-Disubstituted Pyrrolidin-2-ones
Published in Angewandte Chemie International Edition (21-01-2013)“…Mobile: The title reaction affords diastereomerically pure 3,4‐disubstituted pyrrolidin‐2‐ones, which are important structural motifs in natural products, in…”
Get full text
Journal Article -
19
Clinical, pathological and genetic features of follicular lymphoma grade 3A: a joint analysis of the German low-grade and high-grade lymphoma study groups GLSG and DSHNHL
Published in Annals of oncology (01-07-2016)“…Histologically, follicular lymphoma (FL) grades 1, 2 and 3A are composed of two distinct cell types, centroblasts and centrocytes. FL grade 3B is composed only…”
Get full text
Journal Article -
20
T-cell receptor diversity prevents T-cell lymphoma development
Published in Leukemia (01-12-2012)“…Mature T-cell lymphomas (MTCLs) have an extremely poor prognosis and are much less frequent than immature T-cell leukemias. This suggests that malignant…”
Get full text
Journal Article