Search Results - "H. Khan, M. Anwar"
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Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate
Published in Proceedings of the National Academy of Sciences - PNAS (05-05-2020)“…Isoprene has the highest emission into Earth’s atmosphere of any nonmethane hydrocarbon. Atmospheric processing of alkenes, including isoprene, via ozonolysis…”
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Emissions and Marine Boundary Layer Concentrations of Unregulated Chlorocarbons Measured at Cape Point, South Africa
Published in Environmental science & technology (01-09-2020)“…Unregulated chlorocarbons, here defined as dichloromethane (CH2Cl2), perchloroethene (C2Cl4), chloroform (CHCl3), and methyl chloride (CH3Cl), are gases not…”
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Direct gas-phase formation of formic acid through reaction of Criegee intermediates with formaldehyde
Published in Communications chemistry (22-06-2023)“…Ozonolysis of isoprene is considered to be an important source of formic acid (HCOOH), but its underlying reaction mechanisms related to HCOOH formation are…”
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Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications
Published in Angewandte Chemie (International ed.) (25-04-2014)“…Rate coefficients are directly determined for the reactions of the Criegee intermediates (CI) CH2OO and CH3CHOO with the two simplest carboxylic acids, formic…”
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Investigation of Biofuel as a Potential Renewable Energy Source
Published in Atmosphere (01-10-2021)“…An accelerating global energy demand, paired with the harmful environmental effects of fossil fuels, has triggered the search for alternative, renewable energy…”
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Experimental Evidence of Dioxole Unimolecular Decay Pathway for Isoprene-Derived Criegee Intermediates
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (07-05-2020)“…Ozonolysis of isoprene, one of the most abundant volatile organic compounds emitted into the Earth’s atmosphere, generates two four-carbon unsaturated Criegee…”
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Direct Measurements of Unimolecular and Bimolecular Reaction Kinetics of the Criegee Intermediate (CH3)2COO
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-01-2017)“…The Criegee intermediate acetone oxide, (CH3)2COO, is formed by laser photolysis of 2,2-diiodopropane in the presence of O2 and characterized by synchrotron…”
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Aerosol mass and size-resolved metal content in urban Bangkok, Thailand
Published in Environmental science and pollution research international (01-11-2022)“…Inhalable particulate matter (PM) is a health concern, and people living in large cities such as Bangkok are exposed to high concentrations. This exposure has…”
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Reaction of Perfluorooctanoic Acid with Criegee Intermediates and Implications for the Atmospheric Fate of Perfluorocarboxylic Acids
Published in Environmental science & technology (05-02-2019)“…The reaction of perfluorooctanoic acid with the smallest carbonyl oxide Criegee intermediate, CH2OO, has been measured and is very rapid, with a rate…”
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Particle Number Concentration Measurements on Public Transport in Bangkok, Thailand
Published in International journal of environmental research and public health (29-03-2023)“…Traffic is a major source of particulate pollution in large cities, and particulate matter (PM) level in Bangkok often exceeds the World Health Organisation…”
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Airborne observations over the North Atlantic Ocean reveal the importance of gas-phase urea in the atmosphere
Published in Proceedings of the National Academy of Sciences - PNAS (20-06-2023)“…Reduced nitrogen (N) is central to global biogeochemistry, yet there are large uncertainties surrounding its sources and rate of cycling. Here, we present…”
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The reaction of hydroxyl and methylperoxy radicals is not a major source of atmospheric methanol
Published in Nature communications (19-10-2018)“…Methanol is a benchmark for understanding tropospheric oxidation, but is underpredicted by up to 100% in atmospheric models. Recent work has suggested this…”
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Atmospheric HCFC-22, HFC-125, and HFC-152a at Cape Point, South Africa
Published in Environmental science & technology (06-08-2019)“…One hydrochlorofluorocarbon and two hydrofluorocarbons (HCFC-22, HFC-125, and HFC-152a) were measured in air samples at the Cape Point observatory (CPT), South…”
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Investigating the Effect of Fine Particulate Matter (PM2.5) Emission Reduction on Surface-Level Ozone (O3) during Summer across the UK
Published in Atmosphere (01-06-2024)“…UK air pollutant data collected over a 10-year period (2010–2019) from 46 sites with Urban Traffic, Urban Background, Suburban Background, Rural Background,…”
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Criegee Intermediate–Alcohol Reactions, A Potential Source of Functionalized Hydroperoxides in the Atmosphere
Published in ACS earth and space chemistry (21-12-2017)“…Ozonolysis, the mechanism by which alkenes are oxidized by ozone in the atmosphere, produces a diverse family of oxidants known as Criegee intermediates (CIs)…”
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Elucidating the Effects of COVID-19 Lockdowns in the UK on the O3-NOx-VOC Relationship
Published in Atmosphere (01-05-2024)“…The unprecedented reductions in anthropogenic emissions over the COVID-19 lockdowns were utilised to investigate the response of ozone (O3) concentrations to…”
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The Emissions of Water Vapour and NOx from Modelled Hydrogen-Fuelled Aircraft and the Impact of NOx Reduction on Climate Compared with Kerosene-Fuelled Aircraft
Published in Atmosphere (01-10-2022)“…A kerosene fuelled aircraft was modelled within a performance tool and fuel burn and the emissions of nitrogen oxides (NOx) and water vapour at different…”
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Improvements to the representation of BVOC chemistry–climate interactions in UKCA (v11.5) with the CRI-Strat 2 mechanism: incorporation and evaluation
Published in Geoscientific Model Development (20-08-2021)“…We present the first incorporation of the Common Representative Intermediates version 2.2 tropospheric chemistry mechanism, CRI v2.2, combined with…”
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An Estimation of the Levels of Stabilized Criegee Intermediates in the UK Urban and Rural Atmosphere Using the Steady‐State Approximation and the Potential Effects of These Intermediates on Tropospheric Oxidation Cycles
Published in International journal of chemical kinetics (01-08-2017)“…ABSTRACT Levels of the stabilized Criegee Intermediate (sCI), produced via the ozonolysis of unsaturated volatile organic compounds (VOCs), were estimated at…”
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Preparation and characterization of artificial skin using chitosan and gelatin composites for potential biomedical application
Published in Polymer bulletin (Berlin, Germany) (01-09-2012)“…A bioadhesive wound-dressing material based on the combination of gelatin and chitosan with a proper ratio was developed and successfully applied in biomedical…”
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