Search Results - "Gygi, David"

Taming the Chlorine Radical: Enforcing Steric Control over Chlorine-Radical-Mediated C–H Activation by Gonzalez, Miguel I, Gygi, David, Qin, Yangzhong, Zhu, Qilei, Johnson, Elizabeth J, Chen, Yu-Sheng, Nocera, Daniel G

“…Chlorine radicals readily activate C–H bonds, but the high reactivity of these intermediates precludes their use in regioselective C–H functionalization…”
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Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M₂(dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) by Queen, Wendy L., Hudson, Matthew R., Bloch, Eric D., Mason, Jarad A., Gonzalez, Miguel I., Lee, Jason S., Univ. of California, Berkeley, CA, Gygi, David, Howe, Joshua D., Lee, Kyuho, Darwish, Tamim A., James, Michael, Australian Synchrotron, Clayton, Peterson, Vanessa K., Teat, Simon J., Smit, Berend, Lawrence Berkeley National Lab, Ecole Polytechnique Federale de Lausanne, Neaton, Jeffrey B., Long, Jeffrey R., Lawrence Berkeley National Lab, Brown, Craig M., Univ. of Delaware, Newark, DE

“…Analysis of the CO₂ adsorption properties of a well-known series of metal–organic frameworks M₂(dobdc) (dobdc⁴⁻ = 2,5-dioxido-1,4-benzenedicarboxylate; M = Mg,…”
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Structurally characterized terminal manganese(iv) oxo tris(alkoxide) complex by Halbach, Robert L, Gygi, David, Bloch, Eric D, Anderson, Bryce L, Nocera, Daniel G

“…A Mn(iv) complex featuring a terminal oxo ligand, [Mn (O)(ditox) ][K(15-C-5) ] ( ; ditox = Bu MeCO , 15-C-5 = 15-crown-5-ether) has been isolated and…”
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Hydrogen Storage in the Expanded Pore Metal–Organic Frameworks M2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn) by Gygi, David, Bloch, Eric D., Mason, Jarad A., Hudson, Matthew R., Gonzalez, Miguel I., Siegelman, Rebecca L., Darwish, Tamim A., Queen, Wendy L., Brown, Craig M., Long, Jeffrey R.

“…The hydrogen storage properties of a new family of isostructural metal–organic frameworks are reported. The frameworks M2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn;…”
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Hydrogen Storage in the Expanded Pore Metal–Organic Frameworks M 2 (dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn) by Gygi, David, Bloch, Eric D., Mason, Jarad A., Hudson, Matthew R., Gonzalez, Miguel I., Siegelman, Rebecca L., Darwish, Tamim A., Queen, Wendy L., Brown, Craig M., Long, Jeffrey R.

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Mechanistic Investigations of Phenoxyimine–Cobalt(II)-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling by Mills, L. Reginald, Gygi, David, Simmons, Eric M., Wisniewski, Steven R., Kim, Junho, Chirik, Paul J.

“…The mechanism of phenoxyimine (FI)−cobalt-catalyzed C­(sp2)–C­(sp3) Suzuki–Miyaura cross-coupling was studied using a combination of kinetic measurements and…”
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Cooperative insertion of CO2 in diamine-appended metal-organic frameworks by McDonald, Thomas M., Mason, Jarad A., Kong, Xueqian, Bloch, Eric D., Gygi, David, Dani, Alessandro, Crocellà, Valentina, Giordanino, Filippo, Odoh, Samuel O., Drisdell, Walter S., Vlaisavljevich, Bess, Dzubak, Allison L., Poloni, Roberta, Schnell, Sondre K., Planas, Nora, Lee, Kyuho, Pascal, Tod, Wan, Liwen F., Prendergast, David, Neaton, Jeffrey B., Smit, Berend, Kortright, Jeffrey B., Gagliardi, Laura, Bordiga, Silvia, Reimer, Jeffrey A., Long, Jeffrey R.

“…The process of carbon capture and sequestration has been proposed as a method of mitigating the build-up of greenhouse gases in the atmosphere. If implemented,…”
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Overcoming double-step CO2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg2(dobpdc) by Milner, Phillip J, Martell, Jeffrey D, Siegelman, Rebecca L, Gygi, David, Weston, Simon C, Long, Jeffrey R

“…Alkyldiamine-functionalized variants of the metal–organic framework Mg2(dobpdc) (dobpdc4− = 4,4′-dioxidobiphenyl-3,3′-dicarboxylate) are promising for CO2…”
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Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M 2 (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) by Queen, Wendy L., Hudson, Matthew R., Bloch, Eric D., Mason, Jarad A., Gonzalez, Miguel I., Lee, Jason S., Gygi, David, Howe, Joshua D., Lee, Kyuho, Darwish, Tamim A., James, Michael, Peterson, Vanessa K., Teat, Simon J., Smit, Berend, Neaton, Jeffrey B., Long, Jeffrey R., Brown, Craig M.

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Photoredox Oxidation of Alkanes by Monometallic Copper–Oxygen Complexes Using Visible Light Including One Sun Illumination by Nascimento, Daniel L., Gygi, David, Drummer, Matthew C., Gonzalez, Miguel I., Zheng, Shao-Liang, Nocera, Daniel G.

“…Oxygenation of hydrocarbons offers versatile catalytic routes to more valuable compounds, such as alcohols, aldehydes, and ketones. Despite the importance of…”
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Scalable Syntheses of 4‑Substituted Pyridine–Diimines by Gygi, David, Hwang, Seung Jun, Nocera, Daniel G

“…A concise benchtop and scalable synthesis of pyridine–diimine (PDI) ligand frameworks is presented using inexpensive commercial starting materials as opposed…”
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Phenoxythiazoline (FTz)‐Cobalt(II) Precatalysts Enable C(sp2)–C(sp3) Bond‐Formation for Key Intermediates in the Synthesis of Toll‐like Receptor 7/8 Antagonists by Mills, L. Reginald, Di Mare, Francesca, Gygi, David, Lee, Heejun, Simmons, Eric M., Kim, Junho, Wisniewski, Steven R., Chirik, Paul J.

“…Evaluation of the relative rates of the cobalt‐catalyzed C(sp2)–C(sp3) Suzuki–Miyaura cross‐coupling between the neopentylglycol ester of 4‐fluorophenylboronic…”
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Cobalt-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling Enabled by Well-Defined Precatalysts with L,X-Type Ligands by Mills, L. Reginald, Gygi, David, Ludwig, Jacob R, Simmons, Eric M, Wisniewski, Steven R, Kim, Junho, Chirik, Paul J

“…Cobalt­(II) halides in combination with phenoxyimine (FI) ligands generated efficient precatalysts in situ for the C­(sp2)–C­(sp3) Suzuki–Miyaura…”
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Capturing the Complete Reaction Profile of a C–H Bond Activation by Gygi, David, Gonzalez, Miguel I, Hwang, Seung Jun, Xia, Kay T, Qin, Yangzhong, Johnson, Elizabeth J, Gygi, François, Chen, Yu-Sheng, Nocera, Daniel G

“…The activation of C–H bonds requires the generation of extremely reactive species, which hinders the study of this reaction and its key intermediates. To…”
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Selective Propene Oligomerization with Nickel(II)-Based Metal–Organic Frameworks by Mlinar, Anton N, Keitz, Benjamin K, Gygi, David, Bloch, Eric D, Long, Jeffrey R, Bell, Alexis T

“…Two Ni2+-containing metal–organic frameworks, Ni2(dobdc) and Ni2(dobpdc), are shown to be active for the oligomerization of propene in the gas phase. The…”
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Photohalogen elimination chemistry in low-valent binuclear nickel complexes by Jun Hwang, Seung, Hadt, Ryan G., Ruccolo, Serge, Gygi, David, Zheng, Shao-Liang, Chen, Yu-Sheng, Nocera, Daniel G.

“…The preserved dσ* character preserved across the different d-electron counts of a homologous binuclear complex series allows for M–X bond activation upon…”
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Structurally characterized terminal manganese(iv) oxo tris(alkoxide) complexElectronic supplementary information (ESI) available: Single crystal X-ray diffraction data; ESI-MS spectra and data: IR spectra; and magnetic data. CCDC 1829119-1829121. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01164h by Halbach, Robert L, Gygi, David, Bloch, Eric D, Anderson, Bryce L, Nocera, Daniel G

“…A Mn( iv ) complex featuring a terminal oxo ligand, [Mn IV (O)(ditox) 3 ][K(15-C-5) 2 ] ( 3 ; ditox = t Bu 2 MeCO − , 15-C-5 = 15-crown-5-ether) has been…”
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Structurally characterized terminal manganese(iv) oxo tris(alkoxide) complex† †Electronic supplementary information (ESI) available: Single crystal X-ray diffraction data; ESI-MS spectra and data: IR spectra; and magnetic data. CCDC 1829119–1829121. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01164h by Halbach, Robert L., Gygi, David, Bloch, Eric D., Anderson, Bryce L., Nocera, Daniel G.

“…First structurally characterized Mn( iv ) oxo. A Mn( iv ) complex featuring a terminal oxo ligand, [Mn IV (O)(ditox) 3 ][K(15-C-5) 2 ] ( 3 ; ditox = t Bu 2…”
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Phenoxythiazoline (FTz)‐Cobalt(II) Precatalysts Enable C(sp2)–C(sp3) Bond‐Formation for Key Intermediates in the Synthesis of Toll‐like Receptor 7/8 Antagonists by Mills, L. Reginald, Di Mare, Francesca, Gygi, David, Lee, Heejun, Simmons, Eric M., Kim, Junho, Wisniewski, Steven R., Chirik, Paul J.

“…Evaluation of the relative rates of the cobalt‐catalyzed C(sp2)–C(sp3) Suzuki–Miyaura cross‐coupling between the neopentylglycol ester of 4‐fluorophenylboronic…”
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Overcoming double-step CO 2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg 2 (dobpdc) by Milner, Phillip J, Martell, Jeffrey D, Siegelman, Rebecca L, Gygi, David, Weston, Simon C, Long, Jeffrey R

“…Alkyldiamine-functionalized variants of the metal-organic framework Mg (dobpdc) (dobpdc = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) are promising for CO capture…”
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