Search Results - "Gutsul, Evgenii"
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Palladium(II) Pincer Complexes of Functionalized Amides with S‑Modified Cysteine and Homocysteine Residues: Cytotoxic Activity and Different Aspects of Their Biological Effect on Living Cells
Published in Inorganic chemistry (05-07-2021)“…In the search for potential new metal-based antitumor agents, two series of nonclassical palladium(II) pincer complexes based on functionalized amides with…”
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A Family of Cagelike Mn-Silsesquioxane/Bathophenanthroline Complexes: Synthesis, Structure, and Catalytic and Antifungal Activity
Published in Inorganic chemistry (25-09-2023)“…This study reports a novel family of cage manganesesilsesquioxanes prepared via complexation with bathophenanthroline (4,7-diphenyl-1,10-phenanthroline). The…”
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Cagelike Manganesesilsesquioxane Complexes: Synthesis via an Acetone Approach, Structure, and Catalytic Activity for Toluene Oxidation
Published in Crystal growth & design (06-12-2023)Get full text
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Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of "frustrated Lewis pairs"
Published in Chemical science (Cambridge) (18-03-2021)“…The reaction between basic [(PCP)Pd(H)] (PCP = 2,6-(CH 2 P( t -C 4 H 9 ) 2 ) 2 C 6 H 4 ) and acidic [LWH(CO) 3 ] (L = Cp ( 1a ), Tp ( 1b ); Cp = η 5…”
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Unsymmetrical Pd(II) Pincer Complexes with Benzothiazole and Thiocarbamate Flanking Units: Expedient Solvent-Free Synthesis and Anticancer Potential
Published in International journal of molecular sciences (10-12-2023)“…Driven by the growing threat of cancer, many research efforts are directed at developing new chemotherapeutic agents, where the central role is played by…”
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Fluoride Additive as a Simple Tool to Qualitatively Improve Performance of Nickel-Catalyzed Asymmetric Michael Addition of Malonates to Nitroolefins
Published in Journal of organic chemistry (16-09-2022)“…Nowadays, design of the new chiral ligands for organometallic catalysts is often based on the step-by-step increase in their complexity to improve efficiency…”
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Hybrid Silsesquioxane/Benzoate Cu7-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity
Published in Molecules (Basel, Switzerland) (03-12-2022)“…A series of phenylsilsesquioxane-benzoate heptacopper complexes 1–3 were synthesized and characterized by X-ray crystallography. Two parallel routes of toluene…”
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A Family of Hexacopper Phenylsilsesquioxane/Acetate Complexes: Synthesis, Solvent‐Controlled Cage Structures, and Catalytic Activity
Published in Chemistry : a European journal (03-06-2024)“…Convenient self‐assembly synthesis of copper(II) complexes via double (phenylsilsesquioxane and acetate) ligation allows to isolate a family of impressive…”
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Acetone Factor in the Design of Cu4‑, Cu6‑, and Cu9‑Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
Published in Inorganic chemistry (19-09-2022)“…The present study describes a new feature in the self-assembly of cagelike copperphenylsilsesquioxanes: the strong influence of acetone solvates on cage…”
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Versatile Reactivity of Half-Sandwich Rhodium(III) Iminophosphonamide Complexes
Published in Inorganic chemistry (10-10-2022)Get full text
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11
Pincer–dipeptide and pseudodipeptide conjugates: Synthesis and bioactivity studies
Published in Journal of inorganic biochemistry (01-10-2022)“…Following a recent trend on the application of different pincer scaffolds for the development of new metal-based antitumor agents, in this work, dipeptides and…”
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Highly Cytotoxic Palladium(II) Pincer Complexes Based on Picolinylamides Functionalized with Amino Acids Bearing Ancillary S‑Donor Groups
Published in Inorganic chemistry (21-08-2017)“…The reactions of picolinyl and 4-chloropicolinyl chlorides with methyl esters of S-methyl-l-cysteine, l- and d-methionine, and l-histidine afforded a series of…”
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The Role of L‐Ligands in Silica‐Supported Ti Oxo/Imido Heterometathesis Catalysts
Published in Applied organometallic chemistry (01-12-2024)“…ABSTRACT We report here the preparation and characterization of new well‐defined silica‐supported Ti imido complexes that present an L‐ligand variation in a…”
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Tungsten Oxide Dispersed on Silica as Robust and Readily Available Oxo/Imido Heterometathesis Catalyst
Published in ChemPlusChem (Weinheim, Germany) (01-08-2024)“…Continuing our investigation of catalytic oxo/imido heterometathesis as novel water‐free method for C=N bond construction, we report here the application of…”
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Modulation of the Cytotoxic Properties of Pd(II) Complexes Based on Functionalized Carboxamides Featuring Labile Phosphoryl Coordination Sites
Published in Pharmaceutics (28-03-2023)“…Platinum-based drugs are commonly recognized as a keystone in modern cancer chemotherapy. However, intrinsic and acquired resistance as well as serious side…”
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High-Nuclearity (Cu8‑Based) Cage Silsesquioxanes: Synthesis and Structural Study
Published in Crystal growth & design (04-04-2018)“…We herein report a study of Cu(II)-silsesquioxanes’ self-assembly in the presence of two possible template agents (acetonitrile and acetone). This results in…”
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Dihydrogen Bonding in Complex (PP3)RuH(η1‑BH4) Featuring Two Proton-Accepting Hydride Sites: Experimental and Theoretical Studies
Published in Inorganic chemistry (21-01-2014)“…Combining variable-temperature infrared and NMR spectroscopic studies with quantum-chemical calculations (density functional theory (DFT) and natural bond…”
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Electrocatalytic Radical Degradation of 2-Aminoethanol by Nickel, Palladium and Platinum Complexes Bearing Non-Innocent Diarylamido/bis(Phosphine) Pincer Ligand
Published in Applied magnetic resonance (01-10-2024)“…The electrocatalytic activity of PNP pincer complexes with general formula (PNP)MCl (PNP is bis(2-diisopropylphosphino-4-methylphenyl)amide; M = nickel,…”
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The interplay of proton accepting and hydride donor abilities in the mechanism of step-wise boron hydrides alcoholysis
Published in Inorganica Chimica Acta (24-02-2017)“…[Display omitted] •Dihydrogen bonded complexes BH⋯HOR are the intermediates of cascade borohydride alcoholysis.•The consecutive introduction of RO groups…”
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The Role of Non-Covalent Interactions in the Reactions between Palladium Hydrido Complex with Amidoarylphosphine Pincer Ligand and Brønsted Acids
Published in Inorganics (01-05-2023)“…The interaction between (PNP)PdH (1); PNP = bis(2-diisopropylphosphino-4-methylphenyl)amide and different acids (CF3SO3H, HBF4∙Et2O, fluorinated alcohols and…”
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