Search Results - "Gutiérrez, Oliver"
-
1
Electrocatalytic Hydrogenation of Biomass-Derived Organics: A Review
Published in Chemical reviews (28-10-2020)“…Sustainable energy generation calls for a shift away from centralized, high-temperature, energy-intensive processes to decentralized, low-temperature…”
Get full text
Journal Article -
2
Genesis and Stability of Hydronium Ions in Zeolite Channels
Published in Journal of the American Chemical Society (27-02-2019)“…The catalytic sites of acidic zeolite are profoundly altered by the presence of water changing the nature of the Brønsted acid site. High-resolution…”
Get full text
Journal Article -
3
The synergistic effect between Ni sites and Ni-Fe alloy sites on hydrodeoxygenation of lignin-derived phenols
Published in Applied catalysis. B, Environmental (15-09-2019)“…[Display omitted] •The formation of Ni-Fe alloy is responsible for high activity in phenol HDO.•Cyclohexanol hydrogenolysis to cyclohexane is the…”
Get full text
Journal Article -
4
Selective Methane Oxidation to Methanol on Cu-Oxo Dimers Stabilized by Zirconia Nodes of an NU-1000 Metal–Organic Framework
Published in Journal of the American Chemical Society (12-06-2019)“…Mononuclear and dinuclear copper species were synthesized at the nodes of an NU-1000 metal–organic framework (MOF) via cation exchange and subsequent oxidation…”
Get full text
Journal Article -
5
Low-temperature upcycling of polyolefins into liquid alkanes via tandem cracking-alkylation
Published in Science (American Association for the Advancement of Science) (24-02-2023)“…Selective upcycling of polyolefin waste has been hampered by the relatively high temperatures that are required to cleave the carbon-carbon (C-C) bonds at…”
Get full text
Journal Article -
6
Integrated catalytic and electrocatalytic conversion of substituted phenols and diaryl ethers
Published in Journal of catalysis (01-12-2016)“…[Display omitted] •Electrocatalytic hydrogenation of phenolic compounds and diaryl ethers on Rh/C.•The reaction proceeds at room temperature without external…”
Get full text
Journal Article -
7
Environment of Metal–O–Fe Bonds Enabling High Activity in CO2 Reduction on Single Metal Atoms and on Supported Nanoparticles
Published in Journal of the American Chemical Society (14-04-2021)“…Single-atom catalysts are often reported to have catalytic properties that surpass those of nanoparticles, while a direct comparison of sites common and…”
Get full text
Journal Article -
8
The Critical Role of Reductive Steps in the Nickel‐Catalyzed Hydrogenolysis and Hydrolysis of Aryl Ether C−O Bonds
Published in Angewandte Chemie (International ed.) (20-01-2020)“…The hydrogenolysis of the aromatic C−O bond in aryl ethers catalyzed by Ni was studied in decalin and water. Observations of a significant kinetic isotope…”
Get full text
Journal Article -
9
Electrochemically Tunable Proton‐Coupled Electron Transfer in Pd‐Catalyzed Benzaldehyde Hydrogenation
Published in Angewandte Chemie (International ed.) (20-01-2020)“…Acid functionalization of a carbon support allows to enhance the electrocatalytic activity of Pd to hydrogenate benzaldehyde to benzyl alcohol proportional to…”
Get full text
Journal Article -
10
Simultaneous electrocatalytic hydrogenation of aldehydes and phenol over carbon-supported metals
Published in Journal of applied electrochemistry (2021)“…Electrocatalytic hydrogenation of furfural, benzaldehyde, and phenol was studied on carbon-supported Rh, Ru, Pd, and Cu catalysts. All metals were active for…”
Get full text
Journal Article -
11
Copper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol
Published in Nature communications (18-11-2020)“…Molecular interactions with both oxides and metals are essential for heterogenous catalysis, leading to remarkable synergistic impacts on activity and…”
Get full text
Journal Article -
12
Hydrogenation of benzaldehyde via electrocatalysis and thermal catalysis on carbon-supported metals
Published in Journal of catalysis (01-03-2018)“…[Display omitted] •Benzaldehyde hydrogenates to benzyl alcohol on C-supported metals in aqueous phase.•Intrinsic activity with H2 (TCH) increases as…”
Get full text
Journal Article -
13
Aqueous phase electrocatalysis and thermal catalysis for the hydrogenation of phenol at mild conditions
Published in Applied catalysis. B, Environmental (01-03-2016)“…[Display omitted] •Efficient hydrogenation of phenol at room temperature and atmospheric pressure.•Electrochemical and thermal hydrogenations on Pt/C and Rh/C…”
Get full text
Journal Article -
14
Catalytic routes and oxidation mechanisms in photoreforming of polyols
Published in Journal of catalysis (01-12-2016)“…[Display omitted] •Photoreforming and oxidation mechanisms of polyols on Rh/TiO2 for H2-generation.•Anodic reaction network for glycerol photoreforming was…”
Get full text
Journal Article -
15
Hydrogen Bonding Enhances the Electrochemical Hydrogenation of Benzaldehyde in the Aqueous Phase
Published in Angewandte Chemie (International ed.) (04-01-2021)“…The hydrogenation of benzaldehyde to benzyl alcohol on carbon‐supported metals in water, enabled by an external potential, is markedly promoted by polarization…”
Get full text
Journal Article -
16
Electrocatalytic Hydrogenation of Oxygenated Compounds in Aqueous Phase
Published in Organic process research & development (21-12-2018)“…Electrocatalytic hydrogenation is a strategy to hydrogenate biogenic compounds under ambient conditions by replacing the thermal and H2 inputs by cathodic…”
Get full text
Journal Article -
17
Confined Ionic Environments Tailoring the Reactivity of Molecules in the Micropores of BEA-Type Zeolite
Published in Journal of the American Chemical Society (03-07-2024)“…In the presence of water, hydronium ions formed within the micropores of zeolite H-BEA significantly influence the surrounding environment and the reactivity…”
Get full text
Journal Article -
18
Anodic electrocatalytic conversion of carboxylic acids on thin films of RuO2, IrO2, and Pt
Published in Applied catalysis. B, Environmental (15-11-2020)“…[Display omitted] •Pt foil and thin films (TFs) of RuO2 and IrO2 are active for electrocatalytic decarboxylation (ECDX) of valeric acid at ambient…”
Get full text
Journal Article -
19
Site Densities, Rates, and Mechanism of Stable Ni/UiO-66 Ethylene Oligomerization Catalysts
Published in Journal of the American Chemical Society (08-12-2021)“…Nickel-functionalized UiO-66 metal organic frameworks (MOFs) oligomerize ethylene in the absence of cocatalysts or initiators after undergoing…”
Get full text
Journal Article -
20
Directing the Rate‐Enhancement for Hydronium Ion Catalyzed Dehydration via Organization of Alkanols in Nanoscopic Confinements
Published in Angewandte Chemie (International ed.) (01-02-2021)“…Alkanol dehydration rates catalyzed by hydronium ions are enhanced by the dimensions of steric confinements of zeolite pores as well as by intraporous…”
Get full text
Journal Article