Search Results - "Gusarova, Nina K."
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Synthesis and Properties of Sulfur-Containing Organophosphorus Extractants Based on Red Phosphorus, Alkyl Bromides, and Elemental Sulfur
Published in Materials (26-04-2023)“…In order to obtain sulfur-containing organophosphorus compounds that are promising as extractants of heavy metals, the interaction of elemental phosphorus and…”
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Facile Non-Catalyzed Synthesis of Tertiary Phosphine Sulfides by Regioselective Addition of Secondary Phosphine Sulfides to Alkenes
Published in European journal of organic chemistry (01-04-2014)“…An atom‐economic green synthesis of tertiary phsophine sulfides has been developed based on catalyst‐ and solvent‐free addition of secondary phosphine sulfides…”
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3
One-pot synthesis of ultra-branched mixed tetradentate tripodal phosphines and phosphine chalcogenides
Published in Tetrahedron (11-11-2012)“…Ultra-branched mixed tetradentate tripodal phosphines and phosphine chalcogenides have been synthesized by the exhaustive regioselective addition of secondary…”
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4
Alkali Metal Thioselenophosphinates, M[SeSPR2]: One-Pot Multicomponent Synthesis, DFT Study, and Synthetic Application
Published in European journal of inorganic chemistry (01-01-2013)“…Diverse alkali metal thioselenophosphinates, M[SeSPR2] (M = Li, Na, K, Rb, and Cs; R = alkyl, aryl, aralkyl, and hetaralkyl), have been synthesized in 78–94 %…”
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5
Aerobic addition of secondary phosphine oxides to vinyl sulfides: a shortcut to 1-hydroxy-2-(organosulfanyl)ethyl(diorganyl)phosphine oxides
Published in Beilstein journal of organic chemistry (23-10-2015)“…Secondary phosphine oxides react with vinyl sulfides (both alkyl- and aryl-substituted sulfides) under aerobic and solvent-free conditions (80 °C, air, 7-30 h)…”
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6
Novel general halogen-free methodology for the synthesis of organophosphorus compounds
Published in Pure and applied chemistry (17-01-2012)“…The use of novel general halogen-free methodology for the synthesis of phosphines, phosphine chalcogenides, and phosphinic acids from elemental phosphorus and…”
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7
Electrophilic addition of thioselenophosphinic acids to vinyl sulfides and selenides
Published in Journal of sulfur chemistry (04-03-2015)“…The thioselenophosphinic acids, R 2 P(Se)SH (R = Ph, Cy, aralkyl), prepared by acidification of the sodium salts or generated in situ by reaction of secondary…”
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8
Towards C1 chemistry: methanol vinylation by CaC2 in water in the presence of potassium or sodium carbonates
Published in Journal of chemical technology and biotechnology (1986) (01-06-2019)“…BACKGROUND Methyl vinyl ether (MVE), which polymers and copolymers are widely used in industry and medical chemistry, is produced mainly through base‐catalysed…”
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Synthesis of Long‐Chain n‐Alkylphosphonic Acids by Phosphonylation of Alkyl Bromides with Red Phosphorus and Superbase under Micellar/Phase Transfer Catalysis
Published in European journal of organic chemistry (12-03-2021)“…Long‐chain n‐Alkylphosphonic acids, AlkP(O)(OH)2, are synthesized in up to 91 % yield (mostly 40–60 %) by straightforward phosphonylation of alkyl bromides…”
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Superbase‐Assisted Selective Synthesis of Triarylphosphines from Aryl Halides and Red Phosphorus: Three Consecutive Different SNAr Reactions in One Pot
Published in European journal of organic chemistry (30-09-2019)“…Aryl halides, ArX (Ar = Ph, 2‐, 3‐ and 4‐Tol, 1‐ and 2‐Np, 4‐C6H4CONH2; X = F, Cl, Br), rapidly and exothermically (100–180 °C, 0.5–2 h) react with red…”
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11
NaOH(KOH)-catalyzed vinylation of cellulose with acetylene gas in water
Published in Cellulose (London) (01-11-2020)“…Diverse mercerized celluloses (powder cellulose and kraft pulp) have been successfully vinylated with acetylene in an aqueous solution of alkali metal…”
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12
Efficient Synthesis of Lupininium, Anabasinium and Quininium Thioselenophosphinates via a Multi-component Reaction between Secondary Phosphines, Sulfur, Selenium and Alkaloids
Published in Organic preparations and procedures international (01-01-2012)“…Organic Preparations and Procedures International Efficient Synthesis of Lupininium, Anabasinium and Quininium Thioselenophosphinates via a Multi-component…”
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Catalyst-Free Double CH-Functionalization of Quinolines with Phosphine Oxides via Two S N H Ar Reaction Sequences
Published in Journal of organic chemistry (03-04-2020)“…Quinolines undergo catalyst-free double CH-functionalization upon treatment with secondary phosphine oxides (70-75 °C, 20-48 h) followed by oxidation of the…”
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14
Novel atom-economic synthesis of thioselenophosphinates via three-component reaction between secondary phosphine sulfides, elemental selenium, and amines
Published in Journal of sulfur chemistry (01-12-2011)“…An efficient, general, and atom-economic synthesis of organoammonium thioselenophosphinates has been developed by exploiting a three-component reaction between…”
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Acetylene-Triggered Reductive Incorporation of Phosphine Chalcogenides into a Quinoline Scaffold: Toward S N H Ar Reaction
Published in Journal of organic chemistry (17-05-2019)“…Quinolines react with acylacetylenes and secondary phosphine chalcogenides at 20-75 °C to afford N-acylvinyl-2(1)-chalcogenophosphoryldihydroquinolines in good…”
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16
Regio- and stereoselective reaction of 3-fluoropyridine, electron-deficient alkynes and bis(fluoroalkyl) phosphites: Catalyst- and solvent-free synthesis of polyfluoroalkylphosphonylated 3-fluoro-1,2-dihydropyridines
Published in Journal of fluorine chemistry (01-06-2018)“…[Display omitted] •Catalyst- and solvent-free synthesis of polyfluoroalkylphosphonylated 3-fluorodihydropyridines has been elaborated.•Three-component reaction…”
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Catalyst-Free Phosphorylation of Acridine with Secondary Phosphine Chalcogenides: Nucleophilic Addition vs S N H Ar Reaction
Published in Organic letters (07-12-2018)“…Acridine adds secondary phosphine chalcogenides HP(X)R (X = O, S, Se; R = Ar, ArAlk) under catalyst-free conditions at 70-75 °C (both in the presence and…”
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Expedient one-pot organometallics-free synthesis of tris(2-pyridyl)phosphine from 2-bromopyridine and elemental phosphorus
Published in Tetrahedron letters (09-05-2012)“…2-Bromopyridine reacts with elemental phosphorus (red or white) in a superbasic KOH/DMSO(H2O) suspension at 100°C (for red phosphorus) and 75°C (for white…”
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19
Tuneable superbase-catalyzed vinylation of α-hydroxyalkylferrocenes with alkynes
Published in Tetrahedron (02-09-2014)“…Superbase-catalyzed (KOH/DMSO suspension as a catalyst) vinylation of hydroxymethyl- and hydroxyethylferrocenes with terminal and internal alkynes (acetylene,…”
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20
Reaction of Tri(2-pyridyl)phosphine with Electron-Deficient Alkynes in Water: Stereoselective Synthesis of Functionalized Pyridylvinylphosphine Oxides
Published in European journal of organic chemistry (01-01-2014)“…The reaction of tri(2‐pyridyl)phosphine with electron‐deficient alkynes in water proceeds under mild conditions (40–45 °C, without catalyst, 4–5 h) with…”
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