Search Results - "Guiles, R. D"
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Direct Voltammetric Investigation of the Electrochemical Properties of Human Hemoglobin: Relevance to Physiological Redox Chemistry
Published in Biochemistry (Easton) (05-12-2000)“…Voltammetric measurements on solutions of human hemoglobin using gold electrodes modified with ω-hydroxyalkanethiols have yielded the first direct measure of…”
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Sulfur K-Edge X-Ray Absorption Spectroscopy: A Spectroscopic Tool to Examine the Redox State of S-Containing Metabolites in vivo
Published in Proceedings of the National Academy of Sciences - PNAS (26-05-1998)“…The sulfur K-edge x-ray absorption spectra for the amino acids cysteine and methionine and their corresponding oxidized forms cystine and methionine sulfoxide…”
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Voltammetric Probes of Cytochrome Electroreactivity: The Effect of the Protein Matrix on Outer-Sphere Reorganization Energy and Electronic Coupling Probed through Comparisons with the Behavior of Porphyrin Complexes
Published in Biochemistry (Easton) (05-12-2000)“…Using surface-modified electrodes composed of ω-hydroxyalkanethiols, an experimentally based value for the inner-sphere reorganization energy of the…”
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The S3 state of photosystem II: differences between the structure of the manganese complex in the S2 and S3 states determined by x-ray absorption spectroscopy
Published in Biochemistry (Easton) (16-01-1990)“…O2-evolving photosystem II (PSII) membranes from spinach have been cryogenically stabilized in the S3 state of the oxygen-evolving complex. The cryogenic…”
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Effect of Axial Ligand Plane Reorientation on Electronic and Electrochemical Properties Observed in the A67V Mutant of Rat Cytochrome b5
Published in Biochemistry (Easton) (13-05-1997)“…Mutational studies directed at evaluating the effect of the axial ligand plane orientation on electrochemical properties of cytochrome b5 have been performed…”
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The S0 state of photosystem II induced by hydroxylamine: differences between the structure of the manganese complex in the S0 and S1 states determined by x-ray absorption spectroscopy
Published in Biochemistry (Easton) (16-01-1990)“…Hydroxylamine at low concentrations causes a two-flash delay in the first maximum flash yield of oxygen evolved from spinach photosystem II (PSII)…”
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Characterization of a Site-Directed Mutant of Cytochrome b5 Designed To Alter Axial Imidazole Ligand Plane Orientation
Published in Biochemistry (Easton) (13-05-1997)“…Mutants of cytochrome b5 were designed to achieve reorientation of individual axial imidazole ligands. The orientation of the axial ligand planes is thought to…”
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Pseudocontact shifts used in the restraint of the solution structures of electron transfer complexes
Published in Nature structural biology (01-04-1996)“…The geometry of the ferricytochrome b5-ferricytochrome c complex has been analysed using long-range interprotein paramagnetic dipolar shifts. Heteronuclear…”
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Novel heteronuclear methods of assignment transfer from a diamagnetic to a paramagnetic protein: application to rat cytochrome b5
Published in Biochemistry (Easton) (01-08-1993)“…15N and 1H resonance assignments for backbone and side-chain resonances of both equilibrium forms of rat ferricytochrome b5 have been obtained, using a…”
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NMR studies of the structure and dynamics of peptide E, an endogenous opioid peptide that binds with high affinity to multiple opioid receptor subtypes
Published in Biopolymers (01-01-1999)“…Structural and dynamic properties of opioid peptide E have been examined in an sodium dodecyl sulfate (SDS) micelle. Structural and dynamic studies both…”
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Structural studies of cytochrome b5: complete sequence-specific resonance assignments for the trypsin-solubilized microsomal ferrocytochrome b5 obtained from pig and calf
Published in Biochemistry (Easton) (06-02-1990)“…We report complete sequence-specific proton resonance assignments for the trypsin-solubilized microsomal ferrocytochrome b5 obtained from calf liver. In…”
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Kinetic Parameters for Cytochrome c via Insulated Electrode Voltammetry
Published in Journal of the American Chemical Society (21-08-1996)Get full text
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The Origin of Differences in the Physical Properties of the Equilibrium Forms of Cytochrome b5 Revealed through High-Resolution NMR Structures and Backbone Dynamic Analyses
Published in Biochemistry (Easton) (09-06-1998)“…On the basis of a comparison of high-resolution solution structures calculated for both equilibrium forms of rat ferrocytochrome b5, differences in reduction…”
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Structure of the manganese complex of photosystem II upon removal of the 33-kilodalton extrinsic protein: an x-ray absorption spectroscopy study
Published in Biochemistry (Easton) (22-09-1987)“…The structure of the Mn complex of photosystem II (PSII) was studied by X-ray absorption spectroscopy. Oxygen-evolving spinach PSII membranes containing 4-5…”
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Low-potential iron-sulfur centers in photosystem I: an x-ray absorption spectroscopy study
Published in Biochemistry (Easton) (31-05-1988)“…We have measured the X-ray absorption spectra of Fe in photosystem I (PS I) preparations from spinach and a thermophilic cyanobacterium, Synechococcus sp., to…”
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The Origin of Differences in the Physical Properties of the Equilibrium Forms of Cytochrome b 5 Revealed through High-Resolution NMR Structures and Backbone Dynamic Analyses
Published in Biochemistry (Easton) (09-06-1998)“…On the basis of a comparison of high-resolution solution structures calculated for both equilibrium forms of rat ferrocytochrome b 5, differences in reduction…”
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Contribution of Backbone Dynamics to Entropy Changes Occurring on Oxidation of Cytochrome b 5. Can Redox Linked Changes in Hydrogen Bond Networks Modulate Reduction Potentials?
Published in The journal of physical chemistry. B (15-10-1998)“…Changes in backbone dynamics occurring upon oxidation of rat cytochrome b 5 have been examined through model free analyses of 15N-relaxation rates of both…”
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Characterization of a Site-Directed Mutant of Cytochrome b 5 Designed To Alter Axial Imidazole Ligand Plane Orientation
Published in Biochemistry (Easton) (13-05-1997)“…Mutants of cytochrome b 5 were designed to achieve reorientation of individual axial imidazole ligands. The orientation of the axial ligand planes is thought…”
Get full text
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