Search Results - "Guerriero, Antonella"

Coordination chemistry of 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. Part III. Variations on a theme: Novel architectures, materials and applications by Guerriero, Antonella, Peruzzini, Maurizio, Gonsalvi, Luca

“…[Display omitted] •Recent modifications of PTA (1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane) are reviewed.•Reactions of PTA and analogues with transition…”
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New Class of Half-Sandwich Ruthenium(II) Arene Complexes Bearing the Water-Soluble CAP Ligand as an in Vitro Anticancer Agent by Guerriero, Antonella, Oberhauser, Werner, Riedel, Tina, Peruzzini, Maurizio, Dyson, Paul J, Gonsalvi, Luca

“…Ruthenium­(II) arene complexes of 1,4,7-triaza-9-phosphatricyclo[5.3.2.1]­tridecane (CAP) were obtained. Cytotoxicity studies against cancer cell lines reveal…”
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A Ruthenium-Based Catalytic System for a Mild Borrowing-Hydrogen Process by Jumde, Varsha R., Gonsalvi, Luca, Guerriero, Antonella, Peruzzini, Maurizio, Taddei, Maurizio

“…The alkylation of arylamines using stoichiometric amounts of aliphatic and benzylic alcohols in the presence of tBuOK was carried out at 55 °C using a low…”
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Ruthenium(II)-Arene Complexes of the Water-Soluble Ligand CAP as Catalysts for Homogeneous Transfer Hydrogenations in Aqueous Phase by Antonella Guerriero, Maurizio Peruzzini, Luca Gonsalvi

“…The neutral Ru(II) complex κP-[RuCl2(η6-p-cymene)(CAP)] (1), and the two ionic complexes κP-[RuCl(η6-p-cymene)(MeCN)(CAP)]PF6 (2) and…”
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New Wind in Old Sails: Novel Applications of Triphos-based Transition Metal Complexes as Homogeneous Catalysts for Small Molecules and Renewables Activation by Mellone, Irene, Bertini, Federica, Gonsalvi, Luca, Guerriero, Antonella, Peruzzini, Maurizio

“…Recent developments in the coordination chemistry and applications of Ru-triphos [triphos = 1,1,1-tris-(diphenylphosphinomethyl)ethane] systems are reviewed,…”
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Catalytic reactions promoted by metal complexes stabilized by 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. A brief survey of recent results by Guerriero, Antonella, Gonsalvi, Luca

“…[Display omitted] •Water-soluble ligands and metal complexes are considered valuable tools for sustainable processes in water.•PTA and derivatives have shown…”
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Metal-Free Reduction of Phosphine Oxides Using Polymethylhydrosiloxane by Nicolas, Emmanuel, Guerriero, Antonella, Lyaskovskyy, Volodymyr, Peruzzini, Maurizio, Lammertsma, Koop, Gonsalvi, Luca, Slootweg, J.

“…A simple protocol is presented here for the use of inexpensive polymethylhydrosiloxane (PMHS), a waste product of the silicon industry, as stoichiometric…”
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From traditional PTA to novel CAP: A comparison between two adamantane cage-type aminophosphines by Guerriero, Antonella, Gonsalvi, Luca

“…[Display omitted] •Water-soluble organometallics are considered for sustainable processes in water.•Neutral aminophosphines such as PTA and CAP show…”
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Synthesis of New Ruthenium‐CAP Complexes and Use as Catalysts for Benzonitrile Hydration to Benzamide by Guerriero, Antonella, Peruzzini, Maurizio, Gonsalvi, Luca

“…The new bimetallic [Ru2(μ‐Cl)3(CAP)6]Cl (1) and monometallic cis,cis,trans‐[RuCl2(dmso‐S)2(CAP)2] (2) complexes, bearing the water soluble cage‐like phosphine…”
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Beyond transition block metals: exploring the reactivity of phosphine PTA and its oxide PTA(O) towards gallium(iii) by Guerriero, Antonella, Ienco, Andrea, Hicks, Thomas, Cilibrizzi, Agostino

“…The water-soluble cage-like phosphine PTA (1,3,5-triaza-7-phosphaadamantane) and its phosphine oxide derivative [PTA(O)]…”
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Beyond transition block metals: exploring the reactivity of phosphine PTA and its oxide [PTA(O)] towards gallium() by Guerriero, Antonella, Ienco, Andrea, Hicks, Thomas, Cilibrizzi, Agostino

“…The water-soluble cage-like phosphine PTA (1,3,5-triaza-7-phosphaadamantane) and its phosphine oxide derivative [PTA(O)]…”
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Diffusion NMR Studies on the Self-Aggregation of Ru-Arene CAP Complexes: Evidence for the Formation of H‑Bonded Dicationic Species in Acetonitrile by Sian, Leonardo, Guerriero, Antonella, Peruzzini, Maurizio, Zuccaccia, Cristiano, Gonsalvi, Luca, Macchioni, Alceo

“…The self-aggregation of neutral [RuCl2(η6-p-cymene)­(CAP)] (2; p-cymene = 1-methyl-4-(propan-2-yl)­benzene) and ionic [RuCl­(η6-p-cymene)­(L)­(CAP)]­(PF6) (3,…”
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Water-Soluble Silver(I) Complexes Featuring the Hemilabile 3,7-Dimethyl-1,3,5-triaza-7-phosphabicyclo[3.3.1]nonane Ligand: Synthesis, Characterization, and Antimicrobial Activity by Armstrong, Declan, Kirk, Sarah M, Murphy, Cormac, Guerriero, Antonella, Peruzzini, Maurizio, Gonsalvi, Luca, Phillips, Andrew D

“…This paper describes the preparation and comprehensive characterization of a series of water-soluble cationic silver­(I)-centered complexes featuring the…”
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Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-Biaryl Sulfonated Phosphines in Aqueous Solution by Guerriero, Antonella, Bricout, Hervé, Sordakis, Katerina, Peruzzini, Maurizio, Monflier, Eric, Hapiot, Frédéric, Laurenczy, Gábor, Gonsalvi, Luca

“…The selective dehydrogenation of aqueous solutions of HCOOH/HCOONa to H2 and CO2 gas mixtures has been investigated using RuCl3·3H2O as a homogeneous catalyst…”
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Water-Soluble, 1,3,5-Triaza-7-phosphaadamantane-Stabilized Palladium Nanoparticles and their Application in Biphasic Catalytic Hydrogenations at Room Temperature by Caporali, Maria, Guerriero, Antonella, Ienco, Andrea, Caporali, Stefano, Peruzzini, Maurizio, Gonsalvi, Luca

“…Water‐dispersible Pd nanoparticles stabilized by the hydrophilic cage‐like aminophosphine ligand 1,3,5‐triaza‐7‐phosphaadamantane and its N‐methyl derivative…”
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Cyclodextrins as first and second sphere ligands for Rh(I) complexes of lower-rim PTA derivatives for use as catalysts in aqueous phase hydrogenation by Potier, Jonathan, Guerriero, Antonella, Menuel, Stéphane, Monflier, Eric, Peruzzini, Maurizio, Hapiot, Frédéric, Gonsalvi, Luca

“…The rhodium complex [Rh(cod)Cl(N-tBuBzPTA)]PF6 (2) was obtained by reacting the appropriate Rh(I) precursor with the lower-rim PTA derivative [N-tBuBzPTA]PF6…”
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Imidazolyl-PTA Derivatives as Water-Soluble (P,N) Ligands for Ruthenium-Catalyzed Hydrogenations by Krogstad, Donald A, Guerriero, Antonella, Ienco, Andrea, Manca, Gabriele, Peruzzini, Maurizio, Reginato, Gianna, Gonsalvi, Luca

“…The first imidazolyl “upper-rim” derivatives of 1,3,5-triaza-7-phoshaadamantane (PTA), namely,…”
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Electron-Poor Rhenium Allenylidenes and Their Reactivity toward Phosphines: A Combined Experimental and Theoretical Study by Coletti, Cecilia, Gonsalvi, Luca, Guerriero, Antonella, Marvelli, Lorenza, Peruzzini, Maurizio, Reginato, Gianna, Re, Nazzareno

“…The reaction of 1-(phenyl)-1-(p-nitrophenyl)-2-propyn-1-ol with the Re­(I) precursor [(triphos)­(CO)2Re­(OTf)] in dichloromethane at 0 °C afforded the cationic…”
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Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated β-cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives by Legrand, François-Xavier, Hapiot, Frédéric, Tilloy, Sébastien, Guerriero, Antonella, Peruzzini, Maurizio, Gonsalvi, Luca, Monflier, Eric

“…Both PTA (PTA = 1,3,5-triaza-7-phosphaadamantane) and its N-benzylated derivative ( N-Bz-PTA)Cl have been shown to be non-interacting phosphines towards the…”
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Rhenium Allenylidenes and Their Reactivity toward Phosphines: A Theoretical Study by Coletti, Cecilia, Gonsalvi, Luca, Guerriero, Antonella, Marvelli, Lorenza, Peruzzini, Maurizio, Reginato, Gianna, Re, Nazzareno

“…Density functional and local MP2 calculations have been performed to study the electronic structure of the rhenium(I) allenylidene…”
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