Search Results - "Guadagnin, Rafael"
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Chemical composition and cytotoxicity evaluation of essential oil from leaves of Casearia sylvestris, its main compound α-zingiberene and derivatives
Published in Molecules (Basel, Switzerland) (08-08-2013)“…Casearia sylvestris (Salicaceae), popularly known as "guaçatonga", is a plant widely used in folk medicine to treat various diseases, including cancer. The…”
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Antileishmanial Effects of Acetylene Acetogenins from Seeds of Porcelia macrocarpa (Warm.) R.E. Fries (Annonaceae) and Semisynthetic Derivatives
Published in Molecules (Basel, Switzerland) (28-01-2022)“…As part of our continuous studies involving the prospection of natural products from Brazilian flora aiming at the discovery of prototypes for the development…”
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Differential lethal action of C17:2 and C17:0 anacardic acid derivatives in Trypanosoma cruzi – A mechanistic study
Published in Bioorganic chemistry (01-09-2020)“…[Display omitted] •A C17:2 derivative of anacardic acid (1) was isolated from Schinus terebinthifolius.•Compound 1 was subjected to hydrogenation to afford a…”
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4
Understanding the cytotoxic effects of new isovanillin derivatives through phospholipid Langmuir monolayers
Published in Bioorganic chemistry (01-03-2019)“…[Display omitted] •Hydroxymethyl and alkyl groups decrease IC50 values and increase the selectivity.•Modifications modulate the interaction with the membrane…”
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Essential oils from Schinus terebinthifolius leaves - chemical composition and in vitro cytotoxicity evaluation
Published in Pharmaceutical biology (01-10-2012)“…In folk medicine, Schinus terebinthifolius Raddi (Anacardiaceae), has been used as a remedy for ulcers, respiratory problems, wounds, rheumatism, gout,…”
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Dammarane Triterpenoids from Carnauba, Copernicia prunifera (Miller) H. E. Moore (Arecaceae), Wax
Published in Journal of the Brazilian Chemical Society (01-08-2017)“…Phytochemical investigation from carnauba (Copernicia prunifera) wax led to the identification of sixteen dammarane-type triterpenes, including thirteen new…”
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Nucleophilic addition of potassium organotrifluoroborates to chiral cyclic N-acyliminium ions: stereoselective synthesis of functionalized N-heterocycles
Published in Tetrahedron (07-04-2008)“…The stereoselective nucleophilic addition of potassium aryl- and alkynyltrifluoroborates to cyclic N-acyliminium ion derivatives from…”
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8
Preparation and Reactivity of Chalcogenyl Phosphonates and Phosphane Oxides
Published in European Journal of Organic Chemistry (01-10-2007)“…The preparation of new bis[(diphenylphosphinoyl)methyl] sulfides, selenides, and tellurides is described by the reaction of (diphenylphosphinoyl)methyl…”
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Potassium trifluoro-[(Z)-3-methoxy-prop-1-en-yl]borate
Published in Acta crystallographica. Section E, Structure reports online (13-11-2008)“…In the title salt, K(+)·C(4)H(7)BF(3)O(-), the K atom is surrounded by six anions making close contacts through seven F [K⋯F = 2.779 (1)-3.048 (1) Å] and two O…”
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Mechanistic aspects of the isomerization of Z-vinylic tellurides double bonds in the synthesis of potassium Z-vinyltrifluoroborate salts
Published in Beilstein journal of organic chemistry (05-02-2008)“…Through direct transmetalation reaction of Z-vinylic tellurides with nBuLi was observed the unexpected isomerization of double bonds leading to potassium…”
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In vitro trypanocidal evaluation of pinane derivatives from essential oils of ripe fruits from Schinus terebinthifolius Raddi (Anacardiaceae)
Published in Química Nova (2012)“…Essential oils of ripe fruits from Schinus terebinthifolius (Anacardiaceae), obtained using a pilot extractor and a Clevenger apparatus were chemically…”
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Potassium trifluoro-[(Z)-3-(oxan-2-yl-oxy)prop-1-en-1-yl]borate monohydrate
Published in Acta crystallographica. Section E, Structure reports online (24-12-2008)“…The title compound, K(+)·C(8)H(13)BF(3)O(2) (-)·H(2)O, which was obtained from the reaction of a modified form of Z-vinylic telluride via a transmetalation…”
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Cinnamomum triplinerve essential oil as an amikacin carrier agent to combat a polymyxin-resistant Klebsiella pneumoniae strain
Published in Industrial crops and products (15-12-2024)“…Essential oils (EOs) are a complex mix of chemical compounds and can have antibacterial activity. Thus, they can improve the delivery and effectiveness of…”
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1-[( Z )-2-Butyltellanyl-1-chloroethenyl]cyclohex-1-ene
Published in Acta crystallographica. Section E, Structure reports online (01-03-2012)“…The TeII atom in the title molecule, C12H19ClTe, is coordinated in a V-shaped geometry by C atoms derived from the disparate organic substituents. A short…”
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1-[( Z )-1-Bromo-2-(butyldichloro-λ 4 -tellanyl)ethenyl]cyclohex-1-ene
Published in Acta crystallographica. Section E, Structure reports online (01-07-2011)“…The TeIV atom in the title compound, [Te(C4H9)(C8H10Br)Cl2] or C12H19BrCl2Te, is in a distorted ψ-trigonal–bipyramidal geometry, with the lone pair…”
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Sesquiterpenes, diterpenes, alkenyl p-coumarates, and flavonoid from the aerial parts of Baccharis retusa (Asteraceae)
Published in Biochemical systematics and ecology (01-06-2018)“…[Display omitted] •The present work describes the phytochemical analysis from aerial parts of B. retusa.•Sesquiterpenes, diterpenes, flavonoid and alkenyl…”
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Chemoselective cross-coupling Suzuki–Miyaura reaction of ( Z)-(2-chlorovinyl)tellurides and potassium aryltrifluoroborate salts
Published in Tetrahedron letters (04-08-2008)“…An ultrasound-assisted synthesis of functionalized vinylic chlorides is described by palladium-catalyzed cross-coupling reaction of potassium…”
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Synthesis of Lapachone Derivates via Ionic Liquid‐Mediated Tandem Knoevenagel/Diels‐Alder Reaction
Published in ChemistrySelect (Weinheim) (22-08-2017)“…The use of ionic liquid (IL) in Tandem Knoevenagel/Diels‐Alder Reaction is an optimization method for one‐pot procedures, providing great results under mild…”
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Copper catalyzed cross-coupling reactions of diaryl ditellurides with potassium aryltrifluoroborate salts
Published in Journal of the Brazilian Chemical Society (2009)“…We present here results of the cross-coupling reaction of diaryl ditellurides with potassium aryltrifluoroborate salts using a catalytic amount of Cu(OAc)2 and…”
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2-chlorovinyl tellurium dihalides, (p-tol)Te[C(H)=C(Cl)Ph]X2 for X = Cl, Br and I: variable coordination environments, supramolecular structures and docking studies in cathepsin B
Published in Journal of the Brazilian Chemical Society (2010)“…Crystallography shows that the Te atom in each of (p-tol)Te[C(H)=C(Cl)Ph]X2, for X = Cl (1), Br (2) and I (3), is within a distorted Ψ-pentagonal bipyramidal…”
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